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linear 1,3-butadienes (22) 22
chemistry, multidisciplinary (13) 13
selective access (12) 12
c-h activation (9) 9
alkenes (8) 8
alkenylation (8) 8
chemistry, organic (8) 8
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oxidative olefination (8) 8
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conjugated dienes (4) 4
efficient (4) 4
efficient synthesis (4) 4
electron-deficient alkenes (4) 4
allyl acetate (3) 3
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chemical reactions (3) 3
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internal alkynes (3) 3
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4+2 annulation (2) 2
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1,3-butadien (1) 1
1,3-butadiene (1) 1
1,3-dienes (1) 1
1,3‐dienes (1) 1
2-pyridones (1) 1
[ chim.cata ] chemical sciences/catalysis (1) 1
[ chim.coor ] chemical sciences/coordination chemistry (1) 1
[ chim.inor ] chemical sciences/inorganic chemistry (1) 1
[ chim.orga ] chemical sciences/organic chemistry (1) 1
acid-catalyzed hydration (1) 1
acrylamides - chemistry (1) 1
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CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2013, Volume 42, Issue 8, pp. 3253 - 3260
Transition metal-catalyzed oxidative dehydrogenative coupling reactions of C-aryl-H bonds with C-vinyl-H bonds to generate a C-aryl-C-vinyl bonds have been... 
OXIDATIVE OLEFINATION | OLEFINATION REACTION | ALKENES | CROSS-COUPLING REACTION | MECHANISM | SELECTIVE ACCESS | HECK REACTION | LINEAR 1,3-BUTADIENES | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 9, pp. 3169 - 3172
A Ru-catalyzed direct oxidative cross-coupling reaction of acrylates was developed. It offers a straightforward and atom-economical protocol for the synthesis... 
H BOND ACTIVATION | DIRECTING GROUPS | ACID-DERIVATIVES | TRANSITION-METAL-COMPLEXES | TO-TAIL DIMERIZATION | SELECTIVE ACCESS | STEREOSELECTIVE-SYNTHESIS | LINEAR 1,3-BUTADIENES | AROMATIC ESTERS | CHEMISTRY, MULTIDISCIPLINARY | OXIDATIVE ALKENYLATION | Acrylates | Chemical properties | Catalysis | Research | Chemical synthesis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2017, Volume 53, Issue 3, pp. 533 - 536
An oxidant-free cross-coupling reaction of electron-deficient alkenes using an inexpensive ruthenium catalyst is reported. With the assistance of the oxidizing... 
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2017, Volume 53, Issue 96, pp. 12926 - 12929
Cross-coupling reactions of enol carbamates with alkynes or alkenes are reported, using an inexpensive ruthenium catalyst. With the assistance of the directing... 
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5240 - 5243
A combined mass spectrometric and computational study of the Pd/mono-N-protected amino acid (MPAA)-catalyzed vinyl–vinyl coupling reactions is reported.... 
GAS-PHASE | CHEMISTRY, ORGANIC | BOND ACTIVATION | C-H ACTIVATION | LINEAR 1,3-BUTADIENES | EFFICIENT | SIMPLE ALKENES | ALKENYLATION | ELECTROSPRAY-IONIZATION | ACRYLATES
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 18, pp. 4582 - 4585
A Ru-catalyzed direct olefination of electron-deficient alkenes with allyl acetate via C–H bond activation is disclosed. By using N,N-disubstituted... 
ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | C-H ALLYLATION | OXIDATIVE HECK REACTIONS | CHEMISTRY, ORGANIC | BOND ACTIVATION | SELECTIVE SYNTHESIS | LINEAR 1,3-BUTADIENES | ALKENYLATION | DEAROMATIZATION REACTION | ACRYLATES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 7, pp. 2146 - 2149
Pd-catalyzed α-olefinic C–H activation of simple α,β-unsaturated olefins has been developed. 4-imino-β-lactam derivatives were readily synthesized via... 
OXIDATIVE OLEFINATION | C(SP)-H BONDS | CROSS-COUPLING REACTION | PALLADIUM(II)-CATALYZED DIRECT ARYLATION | CYCLIC ENAMINONES | ELECTRON-DEFICIENT ALKENES | CARBON-HYDROGEN BONDS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | BETA-LACTAMS | ARYLBORONIC ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2012, Volume 48, Issue 91, pp. 11232 - 11234
Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route... 
H BOND ACTIVATION | OXIDATIVE OLEFINATION | FUNCTIONALIZATIONS | MECHANISM | 2-PYRIDONES | CYTOTOXIC MACROLIDE | SELECTIVE SYNTHESIS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | ACRYLATES | Alkenes - chemistry | Oxidation-Reduction | Stereoisomerism | Amides - chemistry | Catalysis | Ruthenium - chemistry | Rhodium - chemistry | Acrylamides - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2498 - 2501
A ruthenium-catalyzed direct cross-coupling between alkenes and alkynes via directed C–H bond activation is described. By using N,N-disubstituted aminocarbonyl... 
OXIDATIVE OLEFINATION | ORGANIC-SYNTHESIS | ATOM ECONOMY | ALLYL ACETATE | CHEMISTRY, ORGANIC | BOND ACTIVATION | SELECTIVE SYNTHESIS | ELECTRON-DEFICIENT ALKENES | INTERNAL ALKYNES | C-H FUNCTIONALIZATION | LINEAR 1,3-BUTADIENES
Journal Article
by Liang, QJ and Yang, C and Meng, FF and Jiang, B and Xu, YH and Loh, TP
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 04/2017, Volume 56, Issue 18, pp. 5091 - 5095
A hydroxy group chelation-assisted stereospecific oxidative cross-coupling reaction between alkenes was developed under mild reaction conditions. In the... 
DIRECTING GROUP | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | ATOM ECONOMY | AMINO-ACID LIGANDS | WITTIG OLEFINATION | SELECTIVE ACCESS | CHEMISTRY, MULTIDISCIPLINARY | alkenylation | C-H activation | cross-coupling | palladium | OLEFIN-METATHESIS | LINEAR 1,3-BUTADIENES | METAL-COMPLEXES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2018, Volume 140, Issue 17, pp. 5805 - 5813
A catalytic method to prepare highly substituted 1,3-dienes from two different alkenes is described using a directed, palladium­(II)-mediated C­(alkenyl)–H... 
ALKENYL CARBONYL-COMPOUNDS | CROSS-COUPLING REACTIONS | OLEFINATION | ISOMERIZATION | EFFICIENT SYNTHESIS | SELECTIVE ACCESS | H BOND FUNCTIONALIZATION | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL ALKENES | UNACTIVATED ALKENES | Chemical bonds | Usage | Chemical properties | Chemical synthesis | Analysis | Olefins
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 5, pp. 1236 - 1244
A rhodium-catalyzed Weinreb amide directed cross-coupling reaction between electron-deficient alkenes is reported, which provides an efficient route for the... 
OLEFINATION REACTION | AMINO-ACIDS | OXIDATIVE HECK REACTIONS | CHEMISTRY, ORGANIC | BOND ACTIVATION | AMPHOTERICIN-B | FUJIWARA-MORITANI REACTION | C-H ACTIVATION | SELECTIVE FUNCTIONALIZATION | LINEAR 1,3-BUTADIENES | ALKENYLATION
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 02/2017, Volume 15, Issue 5, pp. 1236 - 1244
A rhodium-catalyzed Weinreb amide directed cross-coupling reaction between electron-deficient alkenes is reported, which provides an efficient route for the... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 3, pp. 533 - 536
An oxidant-free cross-coupling reaction of electron-deficient alkenes using an inexpensive ruthenium catalyst is reported. With the assistance of the oxidizing... 
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | O BOND | INTERNAL OXIDANT | EFFICIENT SYNTHESIS | SELECTIVE ACCESS | N BOND FORMATION | C-H ACTIVATION | ISOQUINOLONE SYNTHESIS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | Chemical reactions | Oxidation | Selectivity | Ruthenium | Alkenes | Catalysts
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 96, pp. 12926 - 12929
Cross-coupling reactions of enol carbamates with alkynes or alkenes are reported, using an inexpensive ruthenium catalyst. With the assistance of the directing... 
4+2 ANNULATION | OLEFINATION | CROSS-COUPLING REACTION | BOND FUNCTIONALIZATIONS | CONJUGATED DIENES | ALLYL ACETATE | SELECTIVE ACCESS | ELECTRON-DEFICIENT ALKENES | INTERNAL ALKYNES | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | Cross coupling | Carbamates (tradename) | Ruthenium | Alkenes | Chemical reactions | Chemical synthesis | Butadiene | Alkynes
Journal Article
Chemical Science, ISSN 2041-6520, 10/2013, Volume 4, Issue 12, pp. 4520 - 4524
The results from a direct palladium-catalyzed cross-coupling reaction between a variety of olefins with acrylate through vinylic C-H activation that give the... 
ORGANIC-SYNTHESIS | PALLADIUM | NATURAL-PRODUCTS | HECK REACTIONS | SELECTIVE SYNTHESIS | CARBON-HYDROGEN BONDS | AMPHOTERICIN-B | HETEROAROMATIC-COMPOUNDS | LINEAR 1,3-BUTADIENES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | Carbon-carbon composites | Acrylates | Alkenes | Styrenes | Olefins | Forges | Activation | Aliphatic compounds
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 08/2013, Volume 19, Issue 33, pp. 10799 - 10803
  A time to dienes: A highly efficient and general method has been developed to prepare conjugated dienes through a biomimetic approach. This aerobic oxidative... 
conjugated dienes | DEHYDROGENATIVE ALKENYLATION | ACTIVATION | NATURAL-PRODUCTS | ARYLATION | SELECTIVE ACCESS | aerobic oxidation | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | CH activation | OLEFINATION | cross-coupling | AROMATIC SUBSTITUTION | biomimetic synthesis | LINEAR 1,3-BUTADIENES | EFFICIENT | Naturvetenskap | Kemi | Natural Sciences | Chemical Sciences
Journal Article
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, ISSN 1434-1948, 07/2018, Issue 25, pp. 2984 - 2986
Reactions of [Ru-5(mu(5)-C)(CO)(15)] with methylacrylate and vinyl acetate have yielded the products [Ru-5(mu(5)-C)(CO)(14)[CH=CHC(=O)OMe](mu-H)] (2) and... 
Ruthenium | CROSS-COUPLING REACTION | CRYSTAL-STRUCTURE | COMPLEXES | Substituent effects | CHEMISTRY, INORGANIC & NUCLEAR | OXIDATIVE OLEFINATION | C-H activation | Cluster compounds | SELECTIVE SYNTHESIS | H BONDS | LINEAR 1,3-BUTADIENES | SIMPLE ALKENES | ACRYLATES
Journal Article
Organic Letters, ISSN 1523-7060, 07/2015, Volume 17, Issue 14, pp. 3462 - 3465
Palladium-catalyzed intermolecular oxyarylation reaction of vinylacetates with retention of the double bond in the final product is developed. Under the... 
H BOND ACTIVATION | ACID-DERIVATIVES | ASYMMETRIC-SYNTHESIS | DEHYDROGENATIVE BORYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | SELECTIVE ACCESS | HECK REACTION | AROMATIC-SUBSTITUTION | LINEAR 1,3-BUTADIENES | METAL-FREE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2015, Volume 21, Issue 40, pp. 14085 - 14094
Journal Article
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