Catalysis Today, ISSN 0920-5861, 03/2017, Volume 281, pp. 109 - 116
In this study, poly (4-vinylphenol) (denoted as PVP) was firstly used as a stable and low-cost sensitizer of titania for visible light photocatalysis. The PVP...
H2 production | Metal-free organic sensitizer | Ligand-to-metal charge transfer (LMCT) | Titania | Visible light photocatalyst | production | OXIDATION | H-2 production | MEDIATED PHOTOCATALYSIS | NANOCRYSTALS | CHEMISTRY, PHYSICAL | DRIVEN | ENGINEERING, CHEMICAL | SUSPENSION | LOW-COST | SURFACE | DEGRADATION | CHEMISTRY, APPLIED | EFFICIENT | TIO2 | Green technology | Catalysis | Polyols
H2 production | Metal-free organic sensitizer | Ligand-to-metal charge transfer (LMCT) | Titania | Visible light photocatalyst | production | OXIDATION | H-2 production | MEDIATED PHOTOCATALYSIS | NANOCRYSTALS | CHEMISTRY, PHYSICAL | DRIVEN | ENGINEERING, CHEMICAL | SUSPENSION | LOW-COST | SURFACE | DEGRADATION | CHEMISTRY, APPLIED | EFFICIENT | TIO2 | Green technology | Catalysis | Polyols
Journal Article
Applied Catalysis B: Environmental, ISSN 0926-3373, 01/2015, Volume 162, pp. 463 - 469
Glucose adsorbed-TiO nanoparticles show photoactivity under visible light ( > 420 nm) through the ligand-to-metal charge transfer (LMCT) mechanism. Although...
Surface complex | Ligand-to-metal charge transfer (LMCT) | Glucose | Visible light photocatalysis | Titanium dioxide | OXIDATION | MECHANISM | TIO2 PHOTOCATALYST | CHEMISTRY, PHYSICAL | FLUORINATION | AQUEOUS-SOLUTION | ENGINEERING, CHEMICAL | IRRADIATION | NANOPARTICLES | SUSPENSION | ENGINEERING, ENVIRONMENTAL | SURFACE | DEGRADATION
Surface complex | Ligand-to-metal charge transfer (LMCT) | Glucose | Visible light photocatalysis | Titanium dioxide | OXIDATION | MECHANISM | TIO2 PHOTOCATALYST | CHEMISTRY, PHYSICAL | FLUORINATION | AQUEOUS-SOLUTION | ENGINEERING, CHEMICAL | IRRADIATION | NANOPARTICLES | SUSPENSION | ENGINEERING, ENVIRONMENTAL | SURFACE | DEGRADATION
Journal Article
Journal of Inorganic and Organometallic Polymers and Materials, ISSN 1574-1443, 3/2010, Volume 20, Issue 1, pp. 142 - 151
Molecular and crystal structure analysis of a tetradentate ligand-to-metal charge transfer (LMCT) complex,...
Polymer Sciences | Valence tautomerism | Ligand-to-metal charge transfer (LMCT) complex | Chemistry | Metalloaromaticity | bis (tetradentate) Schiff base ligand | HOMA | Inorganic Chemistry | Organic Chemistry | bis(tetradentate) Schiff base ligand | POLYMER SCIENCE | MOLECULAR CALCULATIONS | EFFECTIVE CORE POTENTIALS | CRYSTAL-STRUCTURE | AROMATIC CHARACTER | COPPER(II) COMPLEXES | PI INTERACTIONS | COBALT(III) COMPLEXES | BOND | SCHIFF-BASE LIGANDS | ELECTRON DELOCALIZATION
Polymer Sciences | Valence tautomerism | Ligand-to-metal charge transfer (LMCT) complex | Chemistry | Metalloaromaticity | bis (tetradentate) Schiff base ligand | HOMA | Inorganic Chemistry | Organic Chemistry | bis(tetradentate) Schiff base ligand | POLYMER SCIENCE | MOLECULAR CALCULATIONS | EFFECTIVE CORE POTENTIALS | CRYSTAL-STRUCTURE | AROMATIC CHARACTER | COPPER(II) COMPLEXES | PI INTERACTIONS | COBALT(III) COMPLEXES | BOND | SCHIFF-BASE LIGANDS | ELECTRON DELOCALIZATION
Journal Article
Applied Catalysis B: Environmental, ISSN 0926-3373, 2010, Volume 100, Issue 1-2, pp. 77 - 83
We investigated the formation of surface complex between TiO and common electron donors (methanol, formic acid, acetic acid, triethanolamine and EDTA) that can...
Surface complex | Ligand-to-metal charge transfer (LMCT) | Visible light activity | Photocatalyst | Titanium dioxide | REACTIVITY | CHEMISTRY, PHYSICAL | FLUORINATION | ENGINEERING, CHEMICAL | IRRADIATION | EVOLUTION | ENGINEERING, ENVIRONMENTAL | SENSITIZED TIO2 NANOPARTICLES | ONE-ELECTRON OXIDATION | HYDROGEN-PRODUCTION | DEGRADATION | BEHAVIORS | TITANIA
Surface complex | Ligand-to-metal charge transfer (LMCT) | Visible light activity | Photocatalyst | Titanium dioxide | REACTIVITY | CHEMISTRY, PHYSICAL | FLUORINATION | ENGINEERING, CHEMICAL | IRRADIATION | EVOLUTION | ENGINEERING, ENVIRONMENTAL | SENSITIZED TIO2 NANOPARTICLES | ONE-ELECTRON OXIDATION | HYDROGEN-PRODUCTION | DEGRADATION | BEHAVIORS | TITANIA
Journal Article
Chemical Engineering Journal, ISSN 1385-8947, 08/2018, Volume 346, pp. 249 - 257
Photo-induced activation of peroxymonosulfate (PMS) has been enabled by either the direct photolysis of the peroxide bond or the semiconductor bandgap-excited...
Surface complex | Visible light | Sulfate radical | Ligand-to-metal charge transfer (LMCT) | Peroxymonosulfate activation | Advanced oxidation process (AOP)
Surface complex | Visible light | Sulfate radical | Ligand-to-metal charge transfer (LMCT) | Peroxymonosulfate activation | Advanced oxidation process (AOP)
Journal Article
Sensors & Actuators: B. Chemical, ISSN 0925-4005, 11/2018, Volume 273, pp. 35 - 40
A novel colorimetric immunoassay strategy based on metal ion chelation-induced color generation and alkaline phosphatase(ALP)-catalyzed signal amplification....
Bicinchoninic acid (BCA) | Ligand-to-metal charge-transfer (LMCT) | Alkaline phosphatase (ALP) | Colorimetric immunoassay | GOLD NANOPARTICLES | OXIDATION | ELECTROCHEMISTRY | CHEMISTRY, ANALYTICAL | STRATEGY | HORSERADISH-PEROXIDASE | CANCER | BIOMARKERS | INSTRUMENTS & INSTRUMENTATION | GLUCOSE | IMMUNOSENSOR | ULTRASENSITIVE COLORIMETRIC IMMUNOASSAY | ELISA
Bicinchoninic acid (BCA) | Ligand-to-metal charge-transfer (LMCT) | Alkaline phosphatase (ALP) | Colorimetric immunoassay | GOLD NANOPARTICLES | OXIDATION | ELECTROCHEMISTRY | CHEMISTRY, ANALYTICAL | STRATEGY | HORSERADISH-PEROXIDASE | CANCER | BIOMARKERS | INSTRUMENTS & INSTRUMENTATION | GLUCOSE | IMMUNOSENSOR | ULTRASENSITIVE COLORIMETRIC IMMUNOASSAY | ELISA
Journal Article
ChemistrySelect, ISSN 2365-6549, 01/2019, Volume 4, Issue 2, pp. 458 - 464
Many reports on metal ion sensing applications are available in literature but the mechanism of selectivity is not clear. Here the synthesis and...
reversibility | LMCT | DFT | fluorescence microscopic imaging | logic gate | COPPER(II) | SENSOR | CU2+ IONS | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION | PROBES | PLATFORM | HG2 | SELECTIVE DETECTION | FLUORESCENT CHEMOSENSOR | WATER
reversibility | LMCT | DFT | fluorescence microscopic imaging | logic gate | COPPER(II) | SENSOR | CU2+ IONS | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION | PROBES | PLATFORM | HG2 | SELECTIVE DETECTION | FLUORESCENT CHEMOSENSOR | WATER
Journal Article
Applied Catalysis B, Environmental, ISSN 0926-3373, 2010, Volume 100, Issue 1, pp. 77 - 83
▶ EDTA forms the charge-transfer complex on the surface of TiO that absorbs visible light. ▶ The EDTA-TiO complex has activities for the reduction of Cr(VI)...
Surface complex | Ligand-to-metal charge transfer (LMCT) | Visible light activity | Photocatalyst | Titanium dioxide
Surface complex | Ligand-to-metal charge transfer (LMCT) | Visible light activity | Photocatalyst | Titanium dioxide
Journal Article
Catalysts, ISSN 2073-4344, 02/2019, Volume 9, Issue 2, p. 201
Titanium dioxide (TiO2) is one of the most practical and prevalent photo-functional materials. Many researchers have endeavored to design several types of...
Carbon nitride (C | Selective oxidation | Plasmonic Au NPs | N-doped TiO | Decomposition of VOC | Alkoxide | Interfacial surface complex (ISC) | Visible-light-sensitive photocatalyst | Titanium dioxide (TiO | Ligand to metal charge transfer (LMCT) | GOLD NANOPARTICLES | interfacial surface complex (ISC) | selective oxidation | Titanium dioxide (TiO2) | CHEMISTRY, PHYSICAL | OXIDE PHOTOCATALYSTS | N-doped TiO2 | CORRESPONDING ALDEHYDES | PHOTOINDUCED HYDROGEN FORMATION | visible-light-sensitive photocatalyst | BENZYL ALCOHOL | ligand to metal charge transfer (LMCT) | NITROGEN-DOPED TIO2 | PLASMONIC AU/TIO2 PHOTOCATALYST | decomposition of VOC | plasmonic Au NPs | SURFACE COMPLEXES | carbon nitride (C3N4) | alkoxide | AQUEOUS SUSPENSIONS
Carbon nitride (C | Selective oxidation | Plasmonic Au NPs | N-doped TiO | Decomposition of VOC | Alkoxide | Interfacial surface complex (ISC) | Visible-light-sensitive photocatalyst | Titanium dioxide (TiO | Ligand to metal charge transfer (LMCT) | GOLD NANOPARTICLES | interfacial surface complex (ISC) | selective oxidation | Titanium dioxide (TiO2) | CHEMISTRY, PHYSICAL | OXIDE PHOTOCATALYSTS | N-doped TiO2 | CORRESPONDING ALDEHYDES | PHOTOINDUCED HYDROGEN FORMATION | visible-light-sensitive photocatalyst | BENZYL ALCOHOL | ligand to metal charge transfer (LMCT) | NITROGEN-DOPED TIO2 | PLASMONIC AU/TIO2 PHOTOCATALYST | decomposition of VOC | plasmonic Au NPs | SURFACE COMPLEXES | carbon nitride (C3N4) | alkoxide | AQUEOUS SUSPENSIONS
Journal Article
Biochemical Journal, ISSN 0264-6021, 01/2006, Volume 393, Issue 1, pp. 285 - 293
Hpn is a small cytoplasmic protein found in Helicobacter pylori, which binds Ni2+ ions with moderate affinity. Consisting of 60 amino acids, the protein is...
Nickel | Storage | Helicobacter pylori | Histidine-rich protein | Hpn | nickel | UREASE ACTIVITY | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | storage | histidine-rich protein | NICKEL-BINDING PROTEIN | MICROORGANISMS | TRANSPORT | PURIFICATION | INFECTION | UREE | ALLELIC EXCHANGE MUTAGENESIS | HELICOBACTER-PYLORI | Amino Acid Sequence | Proteins - metabolism | Helicobacter pylori - metabolism | Cloning, Molecular | Molecular Sequence Data | Protein Binding | Bacterial Proteins - metabolism | Gene Expression Regulation, Bacterial | Nickel - metabolism | vis, UV | Amp, ampicillin | TTBS, Tris-buffered saline with Tween 20 | visible | MALDI, matrix-assisted laser-desorption ionization | LB, Luria–Bertani | ABC, ATP-binding cassette | DTT, dithiothreitol | ICP-MS, inductively coupled plasma MS | MT, metallothionein | IPTG, isopropyl β-D-thiogalactoside | LMCT, ligand-to-metal charge transfer
Nickel | Storage | Helicobacter pylori | Histidine-rich protein | Hpn | nickel | UREASE ACTIVITY | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | storage | histidine-rich protein | NICKEL-BINDING PROTEIN | MICROORGANISMS | TRANSPORT | PURIFICATION | INFECTION | UREE | ALLELIC EXCHANGE MUTAGENESIS | HELICOBACTER-PYLORI | Amino Acid Sequence | Proteins - metabolism | Helicobacter pylori - metabolism | Cloning, Molecular | Molecular Sequence Data | Protein Binding | Bacterial Proteins - metabolism | Gene Expression Regulation, Bacterial | Nickel - metabolism | vis, UV | Amp, ampicillin | TTBS, Tris-buffered saline with Tween 20 | visible | MALDI, matrix-assisted laser-desorption ionization | LB, Luria–Bertani | ABC, ATP-binding cassette | DTT, dithiothreitol | ICP-MS, inductively coupled plasma MS | MT, metallothionein | IPTG, isopropyl β-D-thiogalactoside | LMCT, ligand-to-metal charge transfer
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 2009, Volume 362, Issue 11, pp. 3975 - 3981
A macrocyclic ligand synthesised Cs -templation forms a complex with Cu(II) with a loosely bound solvent molecule as its sixth coordinated ligand. This solvent...
Cu(II) complexes | Ligand-to-metal charge transfer (LMCT) | Cs +-templated synthesis | Macrocyclic ligand | templated synthesis | COORDINATION POLYMER | DINUCLEAR | COBALT(II) | ION | Cs+-templated synthesis | NICKEL(II) | CHEMISTRY, INORGANIC & NUCLEAR | COPPER(II) COMPLEXES | CHEMISTRY | BEARING | CLUSTER | BINDING
Cu(II) complexes | Ligand-to-metal charge transfer (LMCT) | Cs +-templated synthesis | Macrocyclic ligand | templated synthesis | COORDINATION POLYMER | DINUCLEAR | COBALT(II) | ION | Cs+-templated synthesis | NICKEL(II) | CHEMISTRY, INORGANIC & NUCLEAR | COPPER(II) COMPLEXES | CHEMISTRY | BEARING | CLUSTER | BINDING
Journal Article
Progress in Chemistry, ISSN 1005-281X, 03/2012, Volume 24, Issue 2, pp. 423 - 432
Journal Article
Journal of Environmental Chemical Engineering, ISSN 2213-3437, 02/2019, Volume 7, Issue 1, p. 102906
The effect of chelating agents (citrate and EDTA) on the visible light photocatalytic activity of natural pyrite for the inactivation of 25922 was...
Photo-Fenton | Kinetic model | Photocatalytic inactivation | Pyrite | Chelating agents | E. coli | Hydrogen peroxide | Observed Inactivation Rate Constant (min | SEM Scanning Electron Microscope | Superoxide Radical | Conduction band electron | RSs Reactive Species | W Weibull model | LED light-emitting diode | MAE Mean Absolute Error | LMCT Ligand to Metal Charge Transfer | PBS Phosphate Buffered Saline | EDTA Ethylenediaminetetraaceticacid | hydroxyl radicals in the bulk solution | L log linear model | OH | TSB Trypticase Soy Broth | VL Visible-Light | DBPs Disinfectants Byproducts | Sl Duration of Shoulder Effect | LS log linear with shoulder model | VL/NP Visible-Light/ Natural Pyrite | Abbreviations AAD Absolute Average Deviation | CFU Colony Forming Unit | ANNs Artificial Neural Networks | time to first log-reduction of first subpopulation | NSM Natural Semi-conductor Mineral | NP Natural Pyrite | XRD X-ray powder diffraction | RMSE Root Mean Square Error | ATCC American Type Culture Collection | hydroxyl radicals on the catalyst surface | VL/Cit-NP Visible-Light/Citrate - Natural Pyrite | VL/EDTA-NP Visible-Light/EDTA - Natural Pyrite | 4D time needed for a 4log reduction | MSE Mean Squared Error | Positive hole | FTIR Fourier transform infrared spectrophotometer
Photo-Fenton | Kinetic model | Photocatalytic inactivation | Pyrite | Chelating agents | E. coli | Hydrogen peroxide | Observed Inactivation Rate Constant (min | SEM Scanning Electron Microscope | Superoxide Radical | Conduction band electron | RSs Reactive Species | W Weibull model | LED light-emitting diode | MAE Mean Absolute Error | LMCT Ligand to Metal Charge Transfer | PBS Phosphate Buffered Saline | EDTA Ethylenediaminetetraaceticacid | hydroxyl radicals in the bulk solution | L log linear model | OH | TSB Trypticase Soy Broth | VL Visible-Light | DBPs Disinfectants Byproducts | Sl Duration of Shoulder Effect | LS log linear with shoulder model | VL/NP Visible-Light/ Natural Pyrite | Abbreviations AAD Absolute Average Deviation | CFU Colony Forming Unit | ANNs Artificial Neural Networks | time to first log-reduction of first subpopulation | NSM Natural Semi-conductor Mineral | NP Natural Pyrite | XRD X-ray powder diffraction | RMSE Root Mean Square Error | ATCC American Type Culture Collection | hydroxyl radicals on the catalyst surface | VL/Cit-NP Visible-Light/Citrate - Natural Pyrite | VL/EDTA-NP Visible-Light/EDTA - Natural Pyrite | 4D time needed for a 4log reduction | MSE Mean Squared Error | Positive hole | FTIR Fourier transform infrared spectrophotometer
Journal Article
Materials Science Forum, ISSN 0255-5476, 09/2011, Volume 699, pp. 205 - 229
This paper documents the detailed investigation of the relationship between molecular structure and biological activity of few tetraaza macrocyclic metal (II)...
DNA-Deoxy ribo Nucleic Acid | LMCT-Ligand to Metal charge Transfer | Salbenz-Salicylidenebenzoylacetone | DMSO-Dimethyl sulphoxide
DNA-Deoxy ribo Nucleic Acid | LMCT-Ligand to Metal charge Transfer | Salbenz-Salicylidenebenzoylacetone | DMSO-Dimethyl sulphoxide
Journal Article
Comments on Inorganic Chemistry, ISSN 0260-3594, 12/2008, Volume 29, Issue 5-6, pp. 134 - 168
Iron and manganese superoxide dismutases (Fe- and MnSODs, respectively) are metalloenzymes that catalyze the disproportionation of superoxide to dioxygen and...
Abs, electronic absorption | NHE, normal hydrogen electrode | Glu, glutamic acid | WT, wild-type | INDO/S-CI, intermediate neglect of differential overlap/spectroscopic parameterization-configuration interaction | superoxide dismutases | EPR, electron paramagnetic resonance | quantum mechanics/molecularmechanics calculations | QM, quantum mechanics | Gln, glutamine | Asp, aspartic acid | magnetic circular dichroism spectroscopy | ZPE, zero-point energy | NMR, nuclear magnetic resonance | PA, proton affinity | metal ion redox tuning | LMCT, ligand-to-metal charge transfer | PDB, protein databank | Tyr, tyrosine | COSMO, conductor-like screening model | Trp, tryptophan | DFT, density functional theory | CT, charge transfer | MCD, magnetic circular dichroism | MM, molecular mechanics | SOD, superoxide dismutase | LF, ligand field | MO, molecular orbital | density functional theory | His, histidine | ZFS, zero-field splitting | QM/MM, quantum mechanics/molecular mechanics | CD, circular dichroism | IP, ionization potential | Density functional theory | Metal ion redox tuning | Magnetic circular dichroism spectroscopy | Quantum mechanics/molecularmechanics calculations | Superoxide dismutases | ACTIVE-SITE | CRYSTAL-STRUCTURE | PORPHYROMONAS-GINGIVALIS | POTENTIOMETRIC TITRATIONS | X-RAY-STRUCTURE | ESCHERICHIA-COLI | CHEMISTRY, INORGANIC & NUCLEAR | ELECTRONIC-STRUCTURES | quantum mechanics | LOW-TEMPERATURE THERMOCHROMISM | molecularmechanics calculations | ELECTROSTATIC CALCULATIONS | THERMUS-THERMOPHILUS
Abs, electronic absorption | NHE, normal hydrogen electrode | Glu, glutamic acid | WT, wild-type | INDO/S-CI, intermediate neglect of differential overlap/spectroscopic parameterization-configuration interaction | superoxide dismutases | EPR, electron paramagnetic resonance | quantum mechanics/molecularmechanics calculations | QM, quantum mechanics | Gln, glutamine | Asp, aspartic acid | magnetic circular dichroism spectroscopy | ZPE, zero-point energy | NMR, nuclear magnetic resonance | PA, proton affinity | metal ion redox tuning | LMCT, ligand-to-metal charge transfer | PDB, protein databank | Tyr, tyrosine | COSMO, conductor-like screening model | Trp, tryptophan | DFT, density functional theory | CT, charge transfer | MCD, magnetic circular dichroism | MM, molecular mechanics | SOD, superoxide dismutase | LF, ligand field | MO, molecular orbital | density functional theory | His, histidine | ZFS, zero-field splitting | QM/MM, quantum mechanics/molecular mechanics | CD, circular dichroism | IP, ionization potential | Density functional theory | Metal ion redox tuning | Magnetic circular dichroism spectroscopy | Quantum mechanics/molecularmechanics calculations | Superoxide dismutases | ACTIVE-SITE | CRYSTAL-STRUCTURE | PORPHYROMONAS-GINGIVALIS | POTENTIOMETRIC TITRATIONS | X-RAY-STRUCTURE | ESCHERICHIA-COLI | CHEMISTRY, INORGANIC & NUCLEAR | ELECTRONIC-STRUCTURES | quantum mechanics | LOW-TEMPERATURE THERMOCHROMISM | molecularmechanics calculations | ELECTROSTATIC CALCULATIONS | THERMUS-THERMOPHILUS
Journal Article
PROGRESS IN CHEMISTRY, ISSN 1005-281X, 03/2012, Volume 24, Issue 2-3, pp. 423 - 432
Iron is one of the most abundant metals in the continental crust, while most of dissolved iron is complexes with organic ligands. The irradiated iron complexes...
environmental photochemistry | FE(II) OXIDATION | PHOTO-FENTON REACTION | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION | REDUCTIVE DECHLORINATION | IRON(III) PHOTOINDUCED DEGRADATION | ATMOSPHERIC LIQUID-PHASES | ligand-to-metal charge transfer(LMCT) | BEARING SOIL MINERALS | reactive oxygen species | iron | DISSOLVED ORGANIC-MATTER | HYDROGEN-PEROXIDE | FULVIC ACID INTERACTIONS | organic complexes
environmental photochemistry | FE(II) OXIDATION | PHOTO-FENTON REACTION | CHEMISTRY, MULTIDISCIPLINARY | AQUEOUS-SOLUTION | REDUCTIVE DECHLORINATION | IRON(III) PHOTOINDUCED DEGRADATION | ATMOSPHERIC LIQUID-PHASES | ligand-to-metal charge transfer(LMCT) | BEARING SOIL MINERALS | reactive oxygen species | iron | DISSOLVED ORGANIC-MATTER | HYDROGEN-PEROXIDE | FULVIC ACID INTERACTIONS | organic complexes
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 1997, Volume 160, pp. 161 - 189
In this paper, the photochemical properties of ferric complexes are reviewed. The complexes are classified according to the bonding properties of their ligands...
pyz, pyrazine | DMG, anion of dimethylglyoxirne | GS, ground state | DMSO, dimethylsulphoxide | pydicneN 5, 2,13-dimethyl-3,6,9,12,18-pentaaza-bicyclo[12.3.1]octadcca-1,2,12,14,16-pentaene | ES, excited state | dib, 1,4-diisocyanobenzene | DMF, N′,N′-dimethylformamide | NADH, nicotinamide adenine dinucleotide | Iron (III ) complexes | benacen, dianion of N,N′-ethylenebis(benzoylacetoneimine) | CFC, chlorofluorocarbon | edta, tetraanion of ethylenediaminetetraacetic acid | HGl, glucose | Pc, dianion of phthalocyanine | PPh 3, triphenylphosphine | TPPC, hexaanion of tetrakis(4-carboxyphenyl)porphyrin | LMCT, ligand-to-metal charge transfer | OEP, dianion of octaethvlporphyrin | TPPS, hexaanion of tetrakis(4-sulphonatophenyl)porphyrin | phen, 1,10-phenanthroline | Photochemistry | Mb, myoglobin | RK, anion of kojic acid derivatives | TDCPP, meso-tetra(2,6-dichloro-phenyl)porphyrin | acacen, dianion of N,N′-ethylenebis(acetyla-cetoncimine) | SDS, sodium dodecylsulphate | py, pyridine | ox, oxalate dianion | pyaneN 52,13-dimethyl-3,6,9,12,18-pentaazabicyclo-1 , 14,16-triene | bpy, 2,2′-bipyridine | IL, intraligand | TdPc, dianion of tetrakis(dodecylsulphonamido)phthalocyanine | MMCT, metal-to-metal charge transfer | tz, tetrazine | UroP, decaanion of uroporphyrin | IPCT, ion pair charge transfer | TIM, 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradcca-1,3,8,10-tetraene | HAOX, 2-hydroxyacetophenonoximate anion | cyt, cytochrome | TPP, dianion of tetraphenylporphyrin | debpy, 4,4′-dicarboxy-2,2′bipyridine | 3-Clpy, 3-chloropyridine | TMPyP, hexacation of tetrakis( N-methyl-4-pyridinio)porphyrin | Benacen, dianion of N,N′-ethylenebis(benzoylacetoneimine) | Acacen, dianion of N,N′-ethylenebis(acetylacetoneimine) | Iron(III ) complexes | TRANSITION-METAL COMPLEXES | DMG, anion of dimethylglyoxime | CHEMISTRY, INORGANIC & NUCLEAR | CHARGE-TRANSFER EXCITATION | TLM, 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene | TPPS, hexaanion of tetrakis(4-carboxyphenyl)porphyrin | photochemistry | TMPyP, hexacation of tetrakis(N-methyl-4-pyridion)porphyrin | MOLECULAR-OXYGEN | RESONANCE RAMAN-SPECTROSCOPY | PHOTOINDUCED ELECTRON-TRANSFER | PHOTOREDOX PROPERTIES | EQUATORIAL-AXIAL INTERACTIONS | PPh3, triphenylphosphine | iron(III) complexes | benacen, dianion of N,N'-ethylenebis(benzoylacetoneimine) | bpy, 2,2'-bipyridine | DMF, N,N-dimethylformamide | REDOX REACTIONS | acacen, dianion of N,N'-ethylenebis(acetylacetoneimine) | pyaneN, 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-1,14,16-triene | dcbpy, 4,4'-dicarboxy-2,2'-bipyridine | IRON-PORPHYRIN COMPLEXES | CYTOCHROME-C | OEP, dianion of octaethylporphyrin | pydieneN, 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1,2,12,14,16-pentaene | TDCPP, meso-tetra(2,6-dichlorophenyl)porphyrin | Myoglobin | Niacinamide | Chlorofluorocarbons | Dimethylformamide | Phthalocyanins | Iron | Glucose | Dextrose | Proteins | Iron compounds | Pyridine | Oxalic acid | Oxalates | Porphyrins
pyz, pyrazine | DMG, anion of dimethylglyoxirne | GS, ground state | DMSO, dimethylsulphoxide | pydicneN 5, 2,13-dimethyl-3,6,9,12,18-pentaaza-bicyclo[12.3.1]octadcca-1,2,12,14,16-pentaene | ES, excited state | dib, 1,4-diisocyanobenzene | DMF, N′,N′-dimethylformamide | NADH, nicotinamide adenine dinucleotide | Iron (III ) complexes | benacen, dianion of N,N′-ethylenebis(benzoylacetoneimine) | CFC, chlorofluorocarbon | edta, tetraanion of ethylenediaminetetraacetic acid | HGl, glucose | Pc, dianion of phthalocyanine | PPh 3, triphenylphosphine | TPPC, hexaanion of tetrakis(4-carboxyphenyl)porphyrin | LMCT, ligand-to-metal charge transfer | OEP, dianion of octaethvlporphyrin | TPPS, hexaanion of tetrakis(4-sulphonatophenyl)porphyrin | phen, 1,10-phenanthroline | Photochemistry | Mb, myoglobin | RK, anion of kojic acid derivatives | TDCPP, meso-tetra(2,6-dichloro-phenyl)porphyrin | acacen, dianion of N,N′-ethylenebis(acetyla-cetoncimine) | SDS, sodium dodecylsulphate | py, pyridine | ox, oxalate dianion | pyaneN 52,13-dimethyl-3,6,9,12,18-pentaazabicyclo-1 , 14,16-triene | bpy, 2,2′-bipyridine | IL, intraligand | TdPc, dianion of tetrakis(dodecylsulphonamido)phthalocyanine | MMCT, metal-to-metal charge transfer | tz, tetrazine | UroP, decaanion of uroporphyrin | IPCT, ion pair charge transfer | TIM, 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradcca-1,3,8,10-tetraene | HAOX, 2-hydroxyacetophenonoximate anion | cyt, cytochrome | TPP, dianion of tetraphenylporphyrin | debpy, 4,4′-dicarboxy-2,2′bipyridine | 3-Clpy, 3-chloropyridine | TMPyP, hexacation of tetrakis( N-methyl-4-pyridinio)porphyrin | Benacen, dianion of N,N′-ethylenebis(benzoylacetoneimine) | Acacen, dianion of N,N′-ethylenebis(acetylacetoneimine) | Iron(III ) complexes | TRANSITION-METAL COMPLEXES | DMG, anion of dimethylglyoxime | CHEMISTRY, INORGANIC & NUCLEAR | CHARGE-TRANSFER EXCITATION | TLM, 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene | TPPS, hexaanion of tetrakis(4-carboxyphenyl)porphyrin | photochemistry | TMPyP, hexacation of tetrakis(N-methyl-4-pyridion)porphyrin | MOLECULAR-OXYGEN | RESONANCE RAMAN-SPECTROSCOPY | PHOTOINDUCED ELECTRON-TRANSFER | PHOTOREDOX PROPERTIES | EQUATORIAL-AXIAL INTERACTIONS | PPh3, triphenylphosphine | iron(III) complexes | benacen, dianion of N,N'-ethylenebis(benzoylacetoneimine) | bpy, 2,2'-bipyridine | DMF, N,N-dimethylformamide | REDOX REACTIONS | acacen, dianion of N,N'-ethylenebis(acetylacetoneimine) | pyaneN, 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-1,14,16-triene | dcbpy, 4,4'-dicarboxy-2,2'-bipyridine | IRON-PORPHYRIN COMPLEXES | CYTOCHROME-C | OEP, dianion of octaethylporphyrin | pydieneN, 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1,2,12,14,16-pentaene | TDCPP, meso-tetra(2,6-dichlorophenyl)porphyrin | Myoglobin | Niacinamide | Chlorofluorocarbons | Dimethylformamide | Phthalocyanins | Iron | Glucose | Dextrose | Proteins | Iron compounds | Pyridine | Oxalic acid | Oxalates | Porphyrins
Journal Article
FEBS Letters, ISSN 0014-5793, 02/2000, Volume 467, Issue 2-3, pp. 221 - 225
Two metal ion binding sites are conserved in metallo‐β‐lactamase from Aeromonas hydrophila. The ligands of a first zinc ion bound with picomolar dissociation...
Metallo-β-lactamase | UV-vis spectroscopy | Kinetics | Metal exchange | EXAFS | EXAFS, extended X-ray absorption fine structure | LMCT, ligand-to-metal charge transfer | SITE | PROTEIN | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | RESOLUTION | ZINC(II) | CELL BIOLOGY | BACTEROIDES-FRAGILIS | BIOPHYSICS | metallo-beta-lactamase | metal exchange | RESISTANCE | kinetics | BACILLUS-CEREUS | BINDING | beta-Lactamases - chemistry | Copper - chemistry | Aeromonas hydrophila - genetics | Aeromonas hydrophila - enzymology | Imipenem - chemistry | Spectrum Analysis | Zinc - chemistry | Binding Sites | Cobalt - chemistry
Metallo-β-lactamase | UV-vis spectroscopy | Kinetics | Metal exchange | EXAFS | EXAFS, extended X-ray absorption fine structure | LMCT, ligand-to-metal charge transfer | SITE | PROTEIN | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | RESOLUTION | ZINC(II) | CELL BIOLOGY | BACTEROIDES-FRAGILIS | BIOPHYSICS | metallo-beta-lactamase | metal exchange | RESISTANCE | kinetics | BACILLUS-CEREUS | BINDING | beta-Lactamases - chemistry | Copper - chemistry | Aeromonas hydrophila - genetics | Aeromonas hydrophila - enzymology | Imipenem - chemistry | Spectrum Analysis | Zinc - chemistry | Binding Sites | Cobalt - chemistry
Journal Article