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Journal of Controlled Release, ISSN 0168-3659, 2007, Volume 123, Issue 2, pp. 109 - 115
Journal Article
2. Full Text A cationic tetrahedral Zn(ii) cluster based on a new salicylamide imine multidentate ligand: synthesis, structure and fluorescence sensing studyElectronic supplementary information (ESI) available: Crystallographic data and details of refinements for Zn4L3 (Table S1), the selected bond lengths and angles for Zn4L3 (Table S2). 1H NMR spectra and the assignment of H2L in d6-DMSO (Fig. S1). Optimized molecular geometry of H2L and its contour plots of the frontier orbitals (Fig. S2). The high resolution ESI mass spectrum of Zn4L3 in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S3). The high resolution ESI mass spectrum of Zn4L3 in HEPES buffer (pH = 7.4) solution (Fig. S4). 1H NMR spectra of Zn4L3 in d6-DMSO + D2O (V : V = 9 : 1) (Fig. S5). Comparing the simulated PXRD (black line) and experimental patterns of Zn4L3 in bulk samples and that soaked in solution (Fig. S6). Fluorescence emission changes of H2L (50 μM) upon the addition of different cations in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S7a). Fluorescence emission changes of H2L (50 μM) in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution upon the addition of Zn2+ (inset: the visual fluorescence response of H2L upon the addition of Zn2+ in mixed HEPES buffer (pH = 7) + DMSO (V : V = 1 : 9) solution under a UV light at 365 nm) (Fig. S7b). The Job curves of Zn4L3 in HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S7c). Fluorescence emission intensity of Zn4L3 at 472 nm in the absence/presence of different cations in HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution ((Fig. S7d). Contour plots of the frontier orbitals of Zn4L3 (Fig. S8). The simulated fluorescence spectrum of H2L and Zn4L3 based on TD-DFT calculations (Fig. S9). The linear concentration range of Zn4L3 (50.0 μM) with H2PO-4 in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (λem = 472 nm) (Fig. S10), relative emission intensity at 472 nm upon adding Zn2+/H2PO4- in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S11), emission spectra of Zn4L3 upon the addition of 1 equiv. NaH2PO4/Na2HPO4/Na3PO4 in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S12), UV-Vis spectra of Zn4L3 upon the addition of H2PO4- in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S13). CCDC 1881297. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9dt01376h
ISSN 1477-9226, 8/2019, Volume 48, Issue 32, pp. 12326 - 12335
A monocationic Zn II tetrahedral cluster, [Zn 4 L 3 (μ 3 -OH)]·NO 3 ·1.25H 2 O ( Zn 4 L 3 ) based on a new salicylamide imine ligand H 2 L, H 2 L =... 
Journal Article
3. Full Text A cationic tetrahedral Zn(ii) cluster based on a new salicylamide imine multidentate ligand: synthesis, structure and fluorescence sensing study (Electronic supplementary information (ESI) available: Crystallographic data and details of refinements for Zn4L3 (Table S1), the selected bond lengths and angles for Zn4L3 (Table S2). 1H NMR spectra and the assignment of H2L in d6-DMSO (Fig. S1). Optimized molecular geometry of H2L and its contour plots of the frontier orbitals (Fig. S2). The high resolution ESI mass spectrum of Zn4L3 in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S3). The high resolution ESI mass spectrum of Zn4L3 in HEPES buffer (pH = 7.4) solution (Fig. S4). 1H NMR spectra of Zn4L3 in d6-DMSO + D2O (V : V = 9 : 1) (Fig. S5). Comparing the simulated PXRD (black line) and experimental patterns of Zn4L3 in bulk samples and that soaked in solution (Fig. S6). Fluorescence emission changes of H2L (50 μM) upon the addition of different cations in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S7a). Fluorescence emission changes of H2L (50 μM) in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution upon the addition of Zn2+ (inset: the visual fluorescence response of H2L upon the addition of Zn2+ in mixed HEPES buffer (pH = 7) + DMSO (V : V = 1 : 9) solution under a UV light at 365 nm) (Fig. S7b). The Job curves of Zn4L3 in HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S7c). Fluorescence emission intensity of Zn4L3 at 472 nm in the absence/presence of different cations in HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution ((Fig. S7d). Contour plots of the frontier orbitals of Zn4L3 (Fig. S8). The simulated fluorescence spectrum of H2L and Zn4L3 based on TD-DFT calculations (Fig. S9). The linear concentration range of Zn4L3 (50.0 μM) with H2PO4– in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (λem = 472 nm) (Fig. S10), relative emission intensity at 472 nm upon adding Zn2+/H2PO4– in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S11), emission spectra of Zn4L3 upon the addition of 1 equiv. NaH2PO4/Na2HPO4/Na3PO4 in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S12), UV-Vis spectra of Zn4L3 upon the addition of H2PO4– in mixed HEPES buffer (pH = 7.4) + DMSO (V : V = 1 : 9) solution (Fig. S13). CCDC 1881297. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9dt01376h)
Dalton Transactions, ISSN 1477-9226, 01/2019, Volume 48, Issue 32, pp. 12326 - 12335
A monocationic ZnII tetrahedral cluster, [Zn4L3(μ3-OH)]·NO3·1.25H2O (Zn4L3) based on a new salicylamide imine ligand H2L, H2L =... 
Angles (geometry) | Phosphates | High resolution | Orbitals | Shape | Nuclear magnetic resonance--NMR | Fluorescence | Spectra | X ray analysis | Crystallography | Sodium hydrogen phosphate | Single crystals | Ultraviolet radiation | Anions | Sodium phosphate | Buffer solutions | Emission spectra | Contours | Clusters | Ligands | Cations | Detection | Chelates
Journal Article
European Journal of Operational Research, ISSN 0377-2217, 01/2015, Volume 240, Issue 1, pp. 109 - 126
Journal Article
Flora, ISSN 0367-2530, 08/2016, Volume 223, pp. 74 - 82
Substrate pH has been shown to be important for bryophyte distribution, although bryophytes are believed to obtain more or less all of their nutrients from... 
Species turnover | pH tolerance | Aluminium | Phosphate | Species richness | Mosses | PH tolerance | BEHAVIOR | RETENTION | CALCIFUGE | PLANT DIVERSITY | PLANT SCIENCES | CALCICOLE | BRITISH | GRASSLANDS | ECOLOGY | BASE-RICHNESS | Hydrogen-ion concentration | Phosphates | Analysis | Biological Sciences | Naturvetenskap | Botanik | Botany | Biologi | Natural Sciences
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