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1. Full Text Arylboronic Acid Chemistry under Electrospray Conditions
by Wang, Lifang and Dai, Chaofeng and Burroughs, Sarah Kathryn and Wang, Siming Liu and Wang, Binghe
Chemistry – A European Journal, ISSN 0947-6539, 06/2013, Volume 19, Issue 23, pp. 7587 - 7594
Boronic acids are important in the organic and biological arenas. Thus, their identification and characterization are important. ESI‐MS is a well‐known tool... 
reaction mechanisms | mass spectrometry | electrospray ionization | gas‐phase reactions | boronic acids | gas-phase reactions | SACCHARIDES | BORONIC ACID | DESIGN | RECOGNITION | SENSOR | SIALYL-LEWIS-X | CHEMISTRY, MULTIDISCIPLINARY | DIOLS | BOMBARDMENT MASS-SPECTROMETRY | REPORTER COMPOUNDS | COMPLEXATION | Boronic Acids - chemistry | Molecular Structure | Macromolecular Substances - chemistry | Spectrometry, Mass, Electrospray Ionization - methods | Ionization | Mass spectrometry | Analysis | Acids | Conjugates | Mass spectrometers | Ion sources | Tools | Biological | Arenas | Chambers
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2. Full Text Tandem catalysis with a bifunctional site-isolated Lewis acid-Bronsted base metal-organic framework, NH2-MIL-101(Al)
by Srirambalaji, Renganathan and Hong, Soonsang and Natarajan, Ramalingam and Yoon, Minyoung and Hota, Raghunandan and Kim, Yonghwi and Ho Ko, Young and Kim, Kimoon
Chemical Communications, ISSN 1359-7345, 12/2012, Volume 48, Issue 95, pp. 11650 - 11652
A metal-organic framework (MOF), NH2-MIL-101(Al), which acts as a bifunctional, site-isolated Lewis acid-Bronsted base heterogeneous catalyst, catalyzes a... 
EPOXIDES | MEINWALD REARRANGEMENT REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | STRATEGY | Lewis Acids - chemistry | Metals - chemistry | Epoxy Compounds - chemistry | Organometallic Compounds - chemistry | Catalysis | Lewis Bases - chemistry | Aldehydes - chemistry
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3. Full Text Lewis Acid Promoted Ruthenium(II)‐Catalyzed Etherifications by Selective Hydrogenation of Carboxylic Acids/Esters
by Li, Yuehui and Topf, Christoph and Cui, Xinjiang and Junge, Kathrin and Beller, Matthias
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 17, pp. 5196 - 5200
Ethers are of fundamental importance in organic chemistry and they are an integral part of valuable flavors, fragrances, and numerous bioactive compounds. In... 
Lewis acids | ethers | ruthenium | homogeneous catalysis | hydrogenation | HYDROGENOLYSIS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | TRIFLATE | LACTONES | LIGANDS | ESTERS | HOMOGENEOUS CATALYTIC-HYDROGENATION | REDUCTIVE ETHERIFICATION | UNSYMMETRICAL ETHERS | Lewis Acids - chemistry | Ethers - chemical synthesis | Phosphines - chemistry | Carboxylic Acids - chemistry | Esters | Ethers - chemistry | Catalysis | Mesylates - chemistry | Coordination Complexes - chemistry | Hydrogenation | Ruthenium - chemistry | Ruthenium | Organic acids | Lactones | Acids | Reduction | Catalysts | Aluminum | Carboxylic acids | Ethers | Phosphines
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4. Full Text Exploiting the Reversible Covalent Bonding of Boronic Acids: Recognition, Sensing, and Assembly
by Bull, Steven D and Davidson, Matthew G and van den Elsen, Jean M. H and Fossey, John S and Jenkins, A. Toby A and Jiang, Yun-Bao and Kubo, Yuji and Marken, Frank and Sakurai, Kazuo and Zhao, Jianzhang and James, Tony D
Accounts of Chemical Research, ISSN 0001-4842, 02/2013, Volume 46, Issue 2, pp. 312 - 326
Boronic acids can interact with Lewis bases to generate boronate anions, and they can also bind with diol units to form cyclic boronate esters. Boronic acid... 
SACCHARIDE DETECTION | CHEMOSENSORS | ELECTROPHORESIS | STRATEGY | FLUORESCENCE TRANSDUCTION | ENANTIOMERIC PURITY | ESTERIFICATION | SENSORS | NMR ANALYSIS | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE PROTOCOLS | Dopamine - chemistry | Fluorescent Dyes - chemistry | Cyclization | Oxidation-Reduction | Esters - chemistry | Electrophoresis | Boronic Acids - chemistry | Molecular Structure | Chemical bonds | Boric acid | Lewis structures | Research | Chemical properties | Anions | Receptors | Separation | Constants | Esters | Lewis base | Recognition | Diols
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5. Full Text Synthesis of terephthalic acid via Diels-Alder reactions with ethylene and oxidized variants of 5-hydroxymethylfurfural
by Joshua J. Pacheco and Mark E. Davis
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 6/2014, Volume 111, Issue 23, pp. 8363 - 8367
Terephthalic acid (PTA), a monomer in the synthesis of polyethylene terephthalate (PET), is obtained by the oxidation of petroleum-derived p-xylene. There is... 
Catalysts | Biomass production | Diels Alder reactions | Lewis acids | Dioxanes | Furans | Oxidation | Dehydration | Dienes | Zeolites | Dehydrative aromatization | Heterogeneous catalysis | Cycloaddition | 2,5-DIMETHYLFURAN | heterogeneous catalysis | P-XYLENE | CONVERSION | MULTIDISCIPLINARY SCIENCES | ISOMERIZATION | dehydrative aromatization | cycloaddition | BIOMASS | GLUCOSE | AROMATICS | CATALYSTS | ZEOLITE | WATER | Phthalic Acids - chemistry | Furaldehyde - analogs & derivatives | Models, Chemical | Oxidation-Reduction | Silicon Dioxide - chemistry | Zeolites - chemistry | Cycloaddition Reaction - methods | Lewis Acids - chemistry | Furaldehyde - chemistry | Tin - chemistry | Furans - chemistry | Water - chemistry | Benzoic Acid - chemistry | Molecular Structure | Catalysis | Ethylenes - chemistry | Phthalic Acids - chemical synthesis | Chemical engineering | Terephthalic acid | Chemical properties | Diels-Alder reaction | Research | Chemical engineering research | Chemical synthesis | Production processes | Methods | Physical Sciences
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6. Full Text Phosphorus As a Simultaneous Electron-Pair Acceptor in Intermolecular P···N Pnicogen Bonds and Electron-Pair Donor to Lewis Acids
by Del Bene, Janet E and Alkorta, Ibon and Sánchez-Sanz, Goar and Elguero, José
The Journal of Physical Chemistry A, ISSN 1089-5639, 04/2013, Volume 117, Issue 14, pp. 3133 - 3141
Ab initio MP2/aug’-cc-pVTZ calculations have been performed to investigate the structures and energies of binary complexes LA:PH2F and LA:PH3 and of ternary... 
Lewis Acids - chemistry | Hydrogen Bonding | Nitrogen - chemistry | Phosphorus - chemistry | Models, Molecular | Fluorine - chemistry | Electrons
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7. Full Text Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis
by Jiang, Xingyu and Beiger, Jason J and Hartwig, John F
Journal of the American Chemical Society, ISSN 0002-7863, 01/2017, Volume 139, Issue 1, pp. 87 - 90
The preparation of all possible stereoisomers of a given chiral molecule bearing multiple stereocenters by a simple and unified method is a significant... 
ENANTIO | ENANTIOSELECTIVITY | ALKYLATION | DIASTEREOSELECTIVITY | CONSTRUCTION | QUATERNARY STEREOCENTERS | ALPHA-ALLYLATION | DUAL CATALYSIS | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | DIASTEREO | Amides - chemical synthesis | Stereoisomerism | Carboxylic Acids - chemical synthesis | Allyl Compounds - chemistry | Acetates - chemistry | Esters - chemical synthesis | Lewis Bases - chemistry | Esters - chemistry | Carboxylic Acids - chemistry | Amides - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Iridium - chemistry | Allylic compounds | Chirality | Analysis | Amides | Chemical properties | Carboxylic acids | Acetic acid
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8. Full Text Asymmetric Synthesis of Highly Substituted β‐Lactones through Oxidative Carbene Catalysis with LiCl as Cooperative Lewis Acid
by Bera, Srikrishna and Samanta, Ramesh C and Daniliuc, Constantin G and Studer, Armido
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2014, Volume 53, Issue 36, pp. 9622 - 9626
The reaction of enals with β‐diketones, β‐ketoesters, and malonates bearing a β‐oxyalkyl substituent at the α‐position by oxidative NHC catalysis to provide... 
asymmetric synthesis | N‐heterocyclic carbenes | β‐lactones | organo catalysis | cooperative catalysis | β-lactones | N-heterocyclic carbenes | NHC CATALYSIS | DOMINO REACTIONS | ORGANOCATALYSIS | ALDEHYDES | beta-lactones | ACYL AZOLIUMS | CHEMISTRY, MULTIDISCIPLINARY | ENALS | DESYMMETRIZATION | STEREOSELECTIVE-SYNTHESIS | INHIBITOR | Lewis Acids - chemistry | Lactones - chemical synthesis | Oxidants - chemistry | Oxidation-Reduction | Methane - analogs & derivatives | Stereoisomerism | Cyclohexanes - chemistry | Methane - chemistry | Catalysis | Lithium Chloride - chemistry | Lewis acid | Synthesis | Asymmetry | Cascades | Carbenes | Bonding | Bearing
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9. Full Text Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes
by Goldberg, Alexander F. G and O’Connor, Nicholas R and Craig, Robert A and Stoltz, Brian M
Organic Letters, ISSN 1523-7060, 10/2012, Volume 14, Issue 20, pp. 5314 - 5317
Isocyanates, isothiocyanates, and carbodiimides are effective substrates in (3 + 2) cycloadditions with donor–acceptor cyclopropanes for the synthesis of... 
CHEMISTRY, ORGANIC | ALDEHYDES | ENANTIOSELECTIVE SYNTHESIS | MECHANISM | NITRONES | RING-OPENING REACTIONS | Cyclopropanes - chemistry | Lewis Acids - chemistry | Polyenes - chemistry | Models, Molecular | Molecular Structure | Cycloaddition Reaction | Isocyanates - chemistry
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10. Full Text Lewis Acid Promoted Highly Diastereoselective Petasis Borono-Mannich Reaction: Efficient Synthesis of Optically Active β,γ-Unsaturated α-Amino Acids
by Li, Yi and Xu, Ming-Hua
Organic Letters, ISSN 1523-7060, 04/2012, Volume 14, Issue 8, pp. 2062 - 2065
An efficient and straightforward method for the preparation of highly enantiomerically enriched β,γ-unsaturated α-amino acid derivatives by a Lewis acid... 
ENANTIOPURE | PAUSON-KHAND REACTION | TERT-BUTANESULFINYL IMINES | MEDIATED ALLYLATION | ENANTIOSELECTIVE SYNTHESIS | BIS(SULFINYL)IMIDOAMIDINE LIGANDS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | VICINAL DIAMINES | CATALYTIC ASYMMETRIC-SYNTHESIS | CHIRAL AMINES | Lewis Acids - chemistry | Vinyl Compounds - chemistry | Combinatorial Chemistry Techniques | Sulfonamides - chemistry | Glyoxylates - chemistry | Stereoisomerism | Amino Acids - chemistry | Boronic Acids - chemistry | Molecular Structure | Amino Acids - chemical synthesis | Butanes - chemistry | Catalysis
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11. Full Text Lewis Acid Catalyzed Benzylic C−H Bond Functionalization of Azaarenes: Addition to Enones
by Komai, Hirotomo and Yoshino, Tatsuhiko and Matsunaga, Shigeki and Kanai, Motomu
Organic Letters, ISSN 1523-7060, 04/2011, Volume 13, Issue 7, pp. 1706 - 1709
A Lewis acid catalyzed benzylic C−H bond functionalization of alkyl-substituted azaarenes is described. Sc(OTf)3 and Y(OTf)3 promoted the direct addition of... 
HALIDES | ACTIVATION | ALKYLATION | PYRIDINE | ARYLATION | CHEMISTRY, ORGANIC | SELECTIVE ALKENYLATION | DERIVATIVES | Lewis Acids - chemistry | Aza Compounds - chemistry | Benzene - chemistry | Molecular Structure | Catalysis | Hydrogen - chemistry | Carbon - chemistry
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12. Full Text Fluorescence and Colorimetric Chemosensors for Fluoride-Ion Detection
by Zhou, Ying and Zhang, Jun Feng and Yoon, Juyoung
Chemical Reviews, ISSN 0009-2665, 05/2014, Volume 114, Issue 10, pp. 5511 - 5571
BORONIC ACID | NAKED-EYE DETECTION | SELECTIVE FLUORESCENT | PHOTOPHYSICAL CHARACTERIZATION | CHEMICAL WARFARE AGENTS | RECENT PROGRESS | CHROMOGENIC SENSOR | ANION RECOGNITION | ON FLUORESCENT | PROTON-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | Lewis Acids - chemistry | Fluorescent Dyes - chemistry | Fluorides - chemistry | Fluorides - analysis | Quantum Dots - chemistry | Hydrogen Bonding | Nanoparticles - chemistry | Silicon Dioxide - chemistry | Polymers - chemistry | Colorimetry | Fluorescence | Research | Fluorides | Chemical properties | Analysis | Chemical senses
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13. Full Text Asymmetric Cooperative Catalysis of Strong Brønsted Acid-Promoted Reactions Using Chiral Ureas
by Hao Xu and Stephan J. Zuend and Matthew G. Woll and Ye Tao and Eric N. Jacobsen
Science, ISSN 0036-8075, 2/2010, Volume 327, Issue 5968, pp. 986 - 990
Cationic organic intermediates participate in a wide variety of useful synthetic transformations, but their high reactivity can render selectivity in competing... 
Protons | Cycloaddition | Anions | Catalysts | Imines | Sulfonic acids | Computer analysis | Ions | Reports | Catalysis | Kinetics | DIELS-ALDER REACTIONS | LEWIS-ACID | MULTIDISCIPLINARY SCIENCES | Magnetic Resonance Spectroscopy | Acids - chemistry | Stereoisomerism | Thiourea - chemistry | Urea - chemistry | Alkenes - chemistry | Benzenesulfonates - chemistry | Urea - analogs & derivatives | Chemical Phenomena | Imines - chemistry | Thiourea - analogs & derivatives | Urea | Chemical properties | Research | Chirality | Chemical reactions | Organic chemicals
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14. Full Text Oxidative γ-Addition of Enals to Trifluoromethyl Ketones: Enantioselectivity Control via Lewis Acid/N-Heterocyclic Carbene Cooperative Catalysis
by Mo, Junming and Chen, Xingkuan and Chi, Yonggui Robin
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 21, pp. 8810 - 8813
An oxidative γ-functionalization of enals under N-heterocyclic carbene (NHC) catalysis to give unsaturated δ-lactones is disclosed. Enantioselectivity control... 
ALPHA-FUNCTIONALIZED ALDEHYDES | NUCLEOPHILIC CARBENES | DIELS-ALDER REACTIONS | ALPHA,BETA-UNSATURATED ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ACTIVATED DOUBLE-BONDS | ASYMMETRIC FORMATION | DIENAMINE CATALYSIS | MICHAEL ADDITION | DELTA-LACTONES | Lewis Acids - chemistry | Alkenes - chemistry | Heterocyclic Compounds - chemistry | Oxidation-Reduction | Methane - analogs & derivatives | Stereoisomerism | Ketones - chemistry | Substrate Specificity | Methane - chemistry | Catalysis
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15. Full Text An N‐Heterocyclic Carbene/Lewis Acid Strategy for the Stereoselective Synthesis of Spirooxindole Lactones
by Dugal‐Tessier, Julien and O'Bryan, Elizabeth A and Schroeder, Thomas B. H and Cohen, Daniel T and Scheidt, Karl A
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2012, Volume 51, Issue 20, pp. 4963 - 4967
A cooperative catalysis approach for the enantioselective formal [3+2] addition of α,β‐unsaturated aldehydes to isatins has been developed. Homoenolate... 
Lewis acids | asymmetric synthesis | homoenolates | total synthesis | homogeneous catalysis | NHC CATALYSIS | ALPHA,BETA-UNSATURATED ALDEHYDES | CATALYZED REACTION | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-BUTYROLACTONES | STREPTOMYCES SP | COOPERATIVE CATALYSIS | MAREMYCIN-A | CONJUGATE UMPOLUNG | LEWIS-ACIDS | ANNULATION REACTIONS | Lewis acid | Organic chemistry | Synthesis | Chemical reactions | Strategy | Lithium chlorides | Catalysis | Carbenes | Lactones | N-heterocyclic carbene | catalysis | homoenolate
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16. Full Text Dual-Responsive Surfaces Modified with Phenylboronic Acid-Containing Polymer Brush To Reversibly Capture and Release Cancer Cells
by Liu, Hongliang and Li, Yingying and Sun, Kang and Fan, Junbing and Zhang, Pengchao and Meng, Jingxin and Wang, Shutao and Jiang, Lei
Journal of the American Chemical Society, ISSN 0002-7863, 05/2013, Volume 135, Issue 20, pp. 7603 - 7609
Artificial stimuli-responsive surfaces that can mimic the dynamic function of living systems have attracted much attention. However, there exist few artificial... 
EFFICIENT CAPTURE | CIRCULATING TUMOR-CELLS | GLUCOSE-SENSING MOIETY | INTERFACE | DRUG-DELIVERY | NANOSTRUCTURED SURFACES | QUARTZ-CRYSTAL MICROBALANCE | SEPARATION | SIALYL-LEWIS-X | CHEMISTRY, MULTIDISCIPLINARY | Particle Size | Nanowires - chemistry | Glucose - chemical synthesis | MCF-7 Cells | Humans | Surface Properties | Glucose - chemistry | Boronic Acids - chemistry | Molecular Structure | Silicon - chemistry | Acrylamides - chemistry | Hydrogen-Ion Concentration | Measurement | Diffraction gratings | Research | Methods | Surface energy | Cancer cells
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