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Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 10, pp. 2376 - 2376
Non‐redox‐metal alkylperoxides have been recognized as a missing piece in the oxygenation chemistry puzzle since the first reference of their formation in... 
magnesium | oxygenation | dioxygen | peroxides | main group elements
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3342 - 3346
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3480 - 3483
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 02/2015, Volume 48, Issue 2, pp. 256 - 266
Conspectus Carbenes are compounds that feature a divalent carbon atom with only six electrons in its valence shell. In the singlet state, they possess a lone... 
CRYSTALLINE CARBENE | TRANSITION-METAL-COMPLEXES | INTRAMOLECULAR HYDROIMINIUMATION | RADICAL-CATION | ALKYL AMINO CARBENES | N-HETEROCYCLIC CARBENES | SINGLET CARBENES | CATALYTIC-ACTIVITY | LIGAND PROPERTIES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3028 - 3031
This study details the first use of well-defined low-valent p-block metal hydrides as catalysts in organic synthesis. That is, the bulky, two-coordinate... 
KETONES | HYDROGEN | ACTIVATION | AMMONIA | ASYMMETRIC REDUCTION | ENANTIOSELECTIVE REDUCTION | CATECHOLBORANE | MAIN-GROUP COMPOUNDS | H-2 | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES
Journal Article
Chinese Journal of Organic Chemistry, ISSN 0253-2786, 11/2018, Volume 38, Issue 11, pp. 2888 - 2895
Journal Article
Chemical Reviews, ISSN 0009-2665, 05/2016, Volume 116, Issue 9, pp. 5105 - 5154
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 69, pp. 10304 - 10307
Herein, the synthesis of metal-organic tetrahedral cages featuring flexible thio- and selenophosphate-based ligands is described. The cages were prepared by... 
CHEMISTRY, MULTIDISCIPLINARY | CAVITY | MAIN-GROUP | ENCAPSULATION | ANION-BINDING | MOLECULES
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 03/2019, Volume 55, Issue 24, pp. 3513 - 3516
The new phosphoranylideneketene, (cyclohexyl)(3)PCCO, was synthesized and structurally as well as spectroscopically characterized. Ph3PCCO and... 
MAIN-GROUP | DIVALENT CARBON CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2011, Volume 133, Issue 46, pp. 18622 - 18625
The reduction of the bulky amido-germanium(II) chloride complex, LGeCl (L = N(SiMe3)(Ar*); Ar* = C6H2Me{C(H)Ph2}2-4,2,6), with the magnesium(I) dimer,... 
ALKYNE ANALOGS | HYDROGEN | HYDRIDES | COMPOUND | CHEMISTRY | REACTIVITY | METAL | DIMERS | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | HEAVIER
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 8, pp. 1918 - 1922
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 6, pp. 1521 - 1521
White phosphorus (P4) is both highly toxic and pyrophoric but its synthetic utility is well appreciated. In their Communication on page 1779 ff., J. S.... 
white phosphorus | main-group chemistry | photochemistry | molybdenum | photoelimination
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2013, Volume 52, Issue 38, pp. 9940 - 9943
The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing pi -acidity of the catalyst is observed; thus, anion- pi... 
organocatalysis | TRANSPORT | ENZYME | transition states | RING | molecular recognition | kinetics | noncovalent interactions | MAIN-GROUP THERMOCHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | Catalysts | Stabilization | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 54, pp. 14290 - 14290
A low coordinate germanium complex (denoted as [L‐Ge‐OSiMe3]+; L=ligand) was used to induce the catalytic reduction of ketones to value added products. More... 
hydrides | hydroborylation | main-group catalysis | germanium | oxidative addition
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 28, pp. 8781 - 8781
Monovalent boron compounds can mimic the chemical behavior of transition‐metal complexes. In their Communication on page 8708 ff., Z. Xie and co‐workers... 
borylenes | main-group elements | boron | carboranes | CO activation
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 48, pp. 12449 - 12457
Journal Article
06/2013
While hundreds of papers have been published on frustrated Lewis pairs (FLPs) – the combination of bulky Lewis acids and bases which cannot form adducts – few... 
main group | 0488 | Aluminum | Frustrated Lewis pairs | CO2 | N2O | phosphine | small molecule activation
Dissertation
Journal of the American Chemical Society, ISSN 0002-7863, 04/2012, Volume 134, Issue 15, pp. 6500 - 6503
Simple two-coordinate acyclic silylenes, SiR2, have hitherto been identified only as transient intermediates or thermally labile species. By making use of the... 
HYDROGEN | ACTIVATION | AMMONIA | COMPOUND | CHEMISTRY | REACTIVITY | BOND | SILICON(II) | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | BORYL | Oxidation-reduction reaction | Chemical properties | Hydrogen bonding | Analysis | Aliphatic compounds
Journal Article
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