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Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2016, Volume 55, Issue 8, pp. 2907 - 2910
The characteristic features of bulk silicon surfaces are echoed in the related partially substituted—and thus unsaturated—neutral silicon clusters... 
cluster compounds | main-group elements | subvalent compounds | anions | synthesis design | Silicon | Synthesis | Surface active agents | Organic compounds | Clusters | Lithium | Salts | Anions | Communications | Communication
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 05/2019, Volume 25, Issue 39, pp. 9133 - 9152
Amine-boranes have gained a lot of attention due to their potential as hydrogen storage materials and their capacity to act as precursors for transfer... 
dehydrogenation | ammonia–borane | main-group catalysis | hydrogen transfer | amine–boranes | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Dehydrogenation | Hydrogen storage materials | Hydrogen storage | Catalysts | Polymerization | Boranes | Catalysis | Hydrogen ion concentration | Reviews | Review
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 54, pp. 14290 - 14290
A low coordinate germanium complex (denoted as [L‐Ge‐OSiMe3]+; L=ligand) was used to induce the catalytic reduction of ketones to value added products. More... 
hydrides | hydroborylation | main-group catalysis | germanium | oxidative addition
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2019, Volume 58, Issue 22, pp. 7459 - 7463
The preparation of the first stable diylide‐substituted stannylene and germylene (Y2E, with E=Ge, Sn and Y=[PPh3‐C‐SO2Tol]−) is reported. The synthesis is... 
ylides | subvalent compounds | main group elements | germylenes | stannylenes | Substitutes | Alignment | Metals | Congeners | Tin | Molecular orbitals | Germanium | Ligands | Carbenes | Communications | Communication
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 13, p. n/a
The systematic building of large macromolecular arrangements based on non‐carbon elements is a significant challenge. Our aim in the past two decades has been... 
main group | synthesis | p-block | macrocycles | methodology | Macromolecules
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 08/2017, Volume 23, Issue 47, pp. 11450 - 11450
Mechanochemistry is emerging as a powerful solvent‐free approach to chemical synthesis. Examples of mechanochemical methodologies in the synthesis of... 
solvent free | main-group elements | cyclophosphazanes | mechanochemistry | macrocycles | Chemical synthesis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2014, Volume 53, Issue 48, pp. 13159 - 13163
A one‐electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)–bis(trimethylsilyl)aminodichloroborane adduct leads to a stable aminoboryl radical. A second... 
carbon monoxide | carbine | dihydrogen activation | main‐group adducts | boron | Boron | Dihydrogen activation | Carbon monoxide | Main-group adducts | Carbine | Reduction | Synthesis | Boron compounds | Carbenes | Flexibility | Radicals | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2013, Volume 52, Issue 28, pp. 7147 - 7150
King of donor: The chelating bis(carbene) 1 enabled the synthesis of the new silyliumylidene salt 2. This salt can be dechlorinated with sodium naphthalenide... 
silyliumylidenes | silicon | main‐group chemistry | siladicarbenes | silylenes | main-group chemistry | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Silicon | Dechlorination | Chelating | Synthesis | Sodium | Mathematical analysis | Basicity
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 09/2018, Volume 24, Issue 50, pp. 13060 - 13060
Positive phosphine: A Tf2O/DMAP‐promoted formal [3+2] cycloaddition of secondary diarylphosphine oxides and internal alkynes under metal‐free conditions that... 
phosphenium cations | main-group elements | metal-free processes | synthetic methods | benzophospholes
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 07/2018, Volume 24, Issue 38, p. n/a
Tetrylones represent a class of zero‐valent group 14 compounds with the general formula EL2 (E=C, Si, Ge, Sn, or Pb; L=neutral σ‐donating ligand). This... 
tetrylones | main-group elements | group 14 elements | zero-valent | Tin | Lead | Germanium | Silicon | Computer applications
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 43, pp. 13810 - 13820
Various low oxidation state (+2) group 14 element amidohydride adducts, IPr⋅EH(BH3)NHDipp (E=Si or Ge; IPr=[(HCNDipp)2C:], Dipp=2,6‐iPr2C6H3), were... 
hydrides | carbenes | amides | main‐group elements | ring expansion | main-group elements | Pyrolysis | Toluene | Chemical properties
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 09/2017, Volume 23, Issue 49, pp. 11738 - 11746
Research on chlorine-free conversions of P4 into organophosphorus compounds (OPCs) has a long track record, but methods that allow desirable, direct P-C bond... 
organophosphorus compounds | nucleophilic addition | phosphorus anions | main group chemistry | phosphorus | Organophosphorus compounds | Chlorine compounds | Chlorine | Carbenes | Minireview | Minireviews
Journal Article
Canadian journal of chemistry, ISSN 1480-3291, 01/2009, Volume 87, Issue 1, pp. 8 - 29
The substitution of isoelectronic B–N units for C–C units in aromatic hydrocarbons produces novel heterocycles with structural similarities to the all-carbon... 
Aromaticity | Organic materials | Boron-nitrogen heterocycles | Main-group chemistry | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Chemical bonds | Research | Molecular structure | Properties | Benzene | Hydrocarbons | Biochemistry | Organic chemicals | Electric properties
Journal Article