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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 42, pp. 15162 - 15162
The spin state (singlet or triplet) of a magnetically bistable carbene is controlled by a remote methoxy group as a conformational switch. In their... 
carbenes | conformation | spin crossover | matrix isolation | hydrogenation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2019, Volume 58, Issue 37, pp. 12720 - 12720
Surprisingly stable organic trinitrenes were synthesized in almost quantitative yields from their triazide precursors. In their Communication on page 12994 ff.... 
septet | matrix isolation | photochemistry | IR spectroscopy | nitrenes
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 2016, Volume 22, Issue 35, pp. 12479 - 12486
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 2017, Volume 23, Issue 9, pp. 2035 - 2039
Short interatomic distances below standard values for a single bond are usually identified with double or triple bonds. The synthesis and spectroscopic... 
quantum chemical calculations | bonding analysis | matrix isolation | noble gas complexes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 35, pp. 12567 - 12567
Four of the five possible isomers of azulenylcarbenes were synthesized, isolated in low temperature matrices, and spectroscopically characterized. While... 
carbenes | matrix isolation | photochemistry | IR spectroscopy | photolysis
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 7, pp. 1795 - 1805
Uranium and thorium hydrides are known as functional groups for ligand stabilized complexes and as isolated molecules under matrix isolation conditions. Here,... 
density functional calculations | infrared | uranium | matrix isolation | thorium
Journal Article
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, 06/2017, Volume 181, pp. 116 - 121
Matrix isolation infrared spectra of 1:1 complexes of two fluorophenols, 2-fluorophenol (2-FPh) and 2,6-difluorophenol (2,6-DFPh), with water and benzene have... 
Matrix isolation | Cooperativity | Fluorophenol-water | Charge transfer
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 2017, Volume 56, Issue 36, pp. 10746 - 10749
As an experimental test of the theoretical prediction that heavy-atom tunneling is involved in the degenerate Cope rearrangement of semibullvalenes at... 
solid-state reactions | matrix isolation | IR spectroscopy | isotopes | rearrangement
Journal Article
Journal of Physical Chemistry A, ISSN 1089-5639, 12/2017, Volume 121, Issue 50, p. 9663
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 05/2019, Volume 1183, pp. 367 - 372
High overtone excitation induced conformational isomerization of glycolic acid – nitrogen complex in an argon matrix was investigated by Raman spectroscopy.... 
Matrix isolation | High overtone excitation | Molecular complex | Raman spectroscopy | Isomerization
Journal Article
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 01/2009, Volume 42, Issue 1, pp. 33 - 44
Unlike normal chemical bonds, hydrogen bonds (H-bonds) characteristically feature binding energies and contact distances that do not simply depend on the donor... 
BETA-DIKETONE ENOLS | CRYSTAL-STRUCTURE | ENZYMATIC CATALYSIS | COMPLEXES | TAUTOMERIC COMPETITION | GAS-PHASE | SYSTEMS | MODEL | PROTON-TRANSFER | MATRIX-ISOLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
2008, ISBN 9780470031971, xiv, 258
There has been significant expansion in the application of atomic spectrographic techniques in recent years, which has brought with it the need to provide more... 
Chemistry, Organic | Atomic emission spectroscopy | Metals | Analysis | Metals - Analysis
Book
Angewandte Chemie - International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 1, pp. 124 - 128
Journal Article
Analytical Chemistry, ISSN 0003-2700, 02/2012, Volume 84, Issue 3, pp. 1474 - 1482
In this study, the relationship between matrix concentration and suppression of electrospray ionization (matrix effects) was investigated. Ion suppression of... 
INTERNAL STANDARD | LC-MS/MS | CHEMISTRY, ANALYTICAL | HUMAN PLASMA | PERFORMANCE | PESTICIDE-RESIDUES | POSTCOLUMN INFUSION | MULTIRESIDUE METHOD | SIGNAL SUPPRESSION | SOLID-PHASE EXTRACTION | Matrix isolation | Liquid chromatography | Research | Ionization | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 8, pp. 2217 - 2217
A fleeting exotic heterocumulene radical , OCNSO, is generated in the gas phase at ca. 1200 K, and its conformational ( syn and anti ) interconversion occurs... 
cumulenes | matrix isolation | IR spectroscopy | pseudohalogens | sulfur–nitrogen compounds | Irradiation
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 2016, Volume 55, Issue 36, pp. 10863 - 10867
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2015, Volume 2015, Issue 11, pp. 1946 - 1949
Frozen‐matrix photolysis studies of M(CO) 2 (N 2 Ph)(PPh 3 ) 2 cations (M = Fe and Ru) have revealed end‐on/side‐on photochemical linkage isomerism of the... 
Matrix isolation | Iron | Ruthenium | Isomerization | Photochemistry | Ligands
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 10/2017, Volume 1146, pp. 692 - 702
Reactions of laser-ablated cerium atoms with silane were investigated by matrix isolation infrared spectroscopy and theoretical calculations. The reaction... 
Hydrogen bridge bond | Matrix isolation | DFT calculation | Transition metal
Journal Article
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