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Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2010, Volume 49, Issue 24, pp. 4125 - 4128
Take it to the limit: Parent acenes larger than heptacene have eluded synthesis for decades. When 1,2‐diketone bridges in suitably designed tetraketone... 
organic materials | acenes | matrix isolation | UV/Vis spectroscopy | Matrix isolation | Acenes | Organic materials | Uv/vis spectroscopy
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2019, Volume 58, Issue 42, pp. 15162 - 15162
The spin state (singlet or triplet) of a magnetically bistable carbene is controlled by a remote methoxy group as a conformational switch. In their... 
carbenes | conformation | spin crossover | matrix isolation | hydrogenation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2019, Volume 58, Issue 37, pp. 12720 - 12720
Surprisingly stable organic trinitrenes were synthesized in almost quantitative yields from their triazide precursors. In their Communication on page 12994 ff.... 
septet | matrix isolation | photochemistry | IR spectroscopy | nitrenes
Journal Article
Structural chemistry, ISSN 1040-0400, 2/2016, Volume 27, Issue 1, pp. 243 - 248
Matrix isolation method allows investigating individual molecules and clusters. Basing on the registered spectra, one can obtain the information on cluster... 
Matrix isolation | Theoretical and Computational Chemistry | Chemistry | Cluster structure | Physical Chemistry | Hexanol | Alcohol | Computer Applications in Chemistry
Journal Article
Analytical chemistry (Washington), ISSN 0003-2700, 02/2012, Volume 84, Issue 3, pp. 1474 - 1482
In this study, the relationship between matrix concentration and suppression of electrospray ionization (matrix effects) was investigated. Ion suppression of... 
Physical Sciences | Chemistry | Chemistry, Analytical | Science & Technology | Matrix isolation | Liquid chromatography | Research | Ionization | Analysis | Analytical chemistry | Electrocatalysis | Matrix | Mass spectrometry | Pesticides
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 9, pp. 2035 - 2039
Short interatomic distances below standard values for a single bond are usually identified with double or triple bonds. The synthesis and spectroscopic... 
quantum chemical calculations | bonding analysis | matrix isolation | noble gas complexes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2016, Volume 55, Issue 50, pp. 15589 - 15593
The design and preparation of metal‐free organic materials that exhibit room‐temperature phosphorescence (RTP) is a very attractive topic owing to potential... 
intersystem crossing | materials science | matrix isolation | room-temperature phosphorescence | white-light emission | Matrix isolation | Materials science | White-light emission | Intersystem crossing | Room-temperature phosphorescence | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Bisphenol-A | Temperature
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 08/2020, Volume 26, Issue 46, pp. 10362 - 10362
The heavy‐atom tunneling in the Cope rearrangement of selectively deuterated semibullvalenes was extensively studied. The experimental results from matrix... 
solvent effects | heavy-atom tunneling | confinement | matrix isolation | SCT calculations
Journal Article
Chemical physics letters, ISSN 0009-2614, 04/2020, Volume 745, p. 137263
[Display omitted] •Dihydroxy and oxo-hydroxy tautomeric forms of 4,6-dihydroxypyrimidine and its 2-methylated analog are the most stable structures in the gas... 
Matrix isolation | Hydrogen transfer | IR spectra | Tautomerism | QCISD
Journal Article
Structural chemistry, ISSN 1572-9001, 11/2018, Volume 30, Issue 2, pp. 559 - 566
The structural and spectroscopic features of the CHF3…H2O complex have been investigated using high-level ab initio calculations and IR matrix isolation... 
Matrix isolation | Theoretical and Computational Chemistry | Chemistry | Physical Chemistry | Intermolecular complexes | Ab initio calculations | IR spectroscopy | Computer Applications in Chemistry | Infrared spectroscopy | Hydrogen bonds | Fluoroform | Mathematical analysis | Critical point | Error correction | Superposition (mathematics)
Journal Article
Chemical physics letters, ISSN 0009-2614, 01/2020, Volume 739, p. 136987
[Display omitted] •The HXeCl···H2O complex is thermally decomposed in solid Xe above 42 K.•Thermal decomposition product from HNgY molecules is identified for... 
Noble-gas hydride | Infrared spectroscopy | Molecular complex | Matrix-isolation
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2017, Volume 56, Issue 36, pp. 10746 - 10749
As an experimental test of the theoretical prediction that heavy-atom tunneling is involved in the degenerate Cope rearrangement of semibullvalenes at... 
solid-state reactions | matrix isolation | IR spectroscopy | isotopes | rearrangement
Journal Article
Journal of Chemical Physics, ISSN 0021-9606, 02/2012, Volume 136, Issue 5, pp. 054506 - 054506-8
We investigate the vibrational shift of beryllium oxide (BeO) in Xe matrix as well as in Ar matrix environments by mixed quantum-classical simulation and... 
Physical Sciences | Chemistry | Physics, Atomic, Molecular & Chemical | Chemistry, Physical | Physics | Science & Technology
Journal Article
Angewandte Chemie (International ed.), ISSN 1521-3773, 05/2004, Volume 43, Issue 20, pp. 2622 - 2648
Herein, recent experiments on the spectroscopy and chemical reactions of molecules and complexes embedded in helium droplets are reviewed. In the droplets, a... 
cryochemistry | helium | matrix isolation | IR spectroscopy | van der Waals complexes | Matrix isolation | Van der Waals complexes | Cryochemistry | Helium | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
Journal Article
Journal of molecular structure, ISSN 0022-2860, 01/2021, Volume 1224, p. 129288
•Influence of Cl…π halogen bonding in determining the geometry of POCl3-PhAc dimers was studied.•The non-trivial role played by P…π phosphorus bonding in... 
Matrix isolation | NBO | EDA | Infrared | NCI analyses | Phosphorous bonding
Journal Article