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chemistry, organic (40) 40
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copper-catalyzed trifluoromethylation (6) 6
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Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2015, Volume 13, Issue 46, pp. 11153 - 11183
Photocatalytic methods for fluoroalkyl-radical generation provide more convenient alternatives to the classical perfluoroalkyl-radical (R f ) production... 
MEDICINAL CHEMISTRY | COORDINATION-COMPOUNDS | VISIBLE-LIGHT PHOTOCATALYSIS | C-H PERFLUOROALKYLATION | COPPER-MEDIATED TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | RADICAL TRIFLUOROMETHYLATION | OXIDATIVE TRIFLUOROMETHYLATION | REDUCTIVE ELIMINATION | PHOTOREDOX CATALYSIS | BOND-FORMATION
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 12/2015, Volume 13, Issue 46, pp. 11153 - 11183
Photocatalytic methods for fluoroalkyl-radical generation provide more convenient alternatives to the classical perfluoroalkyl-radical (Rf) production through... 
Transition Elements - chemistry | Oxidation-Reduction | Free Radicals - chemistry | Light | Halogenation | Catalysis | Coordination Complexes - chemistry | Iridium - chemistry | Ruthenium - chemistry | Alkylation | Alkylating Agents - chemistry | Photochemical Processes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 8, pp. 2743 - 2747
The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible‐light photoredox catalysis. A wide range of readily available... 
radical reactions | isocyanides | photoredox catalysis | sulfones | fluorine | COMPLEXES | TRIFLUOROMETHYLATION REACTIONS | MEDIATED CLEAVAGE | ALKYNES | PERFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | HETEROARENES | BLOCKS | DERIVATIVES | CYCLIZATION | Organosulfur compounds | Fluorides | Catalysis | Fluorination | Light effects | Radicals | Sulfones | Reagents
Journal Article
Synlett, ISSN 0936-5214, 12/2016, Volume 27, Issue 20, pp. 2747 - 2755
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2015, Volume 51, Issue 7, pp. 1214 - 1217
A novel strategy has been developed for the highly chemo- and stereo-selective synthesis of (Z)-beta-perfluoroalkyl enaminones from readily available starting... 
TANDEM RADICAL REACTIONS | ACID DERIVATIVES | ALKENES | BETA-POLYFLUOROALKYLVINYL KETONES | COPPER-MEDIATED TRIFLUOROMETHYLATION | CATALYZED SYNTHESIS | DIPHENYL DISELENIDE | TERTIARY-AMINES | COUPLING REACTION | PERFLUOROALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | Synthesis (chemistry) | Methodology | Chemical bonds | Strategy | Cleavage | Formations | Radicals
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2015, Volume 51, Issue 7, pp. 1214 - 1217
A novel strategy has been developed for the highly chemo- and stereo-selective synthesis of (Z)-β-perfluoroalkyl enaminones from readily available starting... 
Alkenes - chemistry | Stereoisomerism | Alkylation | Halogenation
Journal Article
Synlett, ISSN 0936-5214, 09/2013, Volume 24, Issue 15, pp. 1887 - 1898
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2018, Volume 59, Issue 3, pp. 180 - 187
Journal Article
Synthesis, ISSN 0039-7881, 08/2017, Volume 49, Issue 15, pp. 3394 - 3406
Journal Article
Topics in Organometallic Chemistry, ISSN 1436-6002, 2014, Volume 52, pp. 113 - 142
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 3, pp. 880 - 883
We report the first iron-catalyzed difluoromethylation of arylzincs with difluoromethyl 2-pyridyl sulfone via selective C–S bond cleavage. This method employs... 
ACTIVATION | FLUORINATED SULFONES | COUPLING REACTIONS | GEM-DIFLUOROOLEFINATION | COPPER-MEDIATED DIFLUOROMETHYLATION | ARYL HALIDES | RADICAL FLUOROALKYLATION | BASE-METAL | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | ALKYL-HALIDES | Difluoromethylornithine | Chemical properties | Structure | Sulfones
Journal Article
Organic Letters, ISSN 1523-7060, 01/2014, Volume 16, Issue 1, pp. 54 - 57
Direct N-difluoromethylation of imidazoles and benzimidazoles has been achieved using TMS-CF3 (the Ruppert–Prakash reagent) under neutral conditions.... 
FUNCTIONALIZATION | IODIDES | HETEROCYCLES | COPPER-MEDIATED DIFLUOROMETHYLATION | FLUOROALKYLATION | CHEMISTRY, ORGANIC | FLUORINE | ARYL | CHLORODIFLUOROMETHANE
Journal Article
Synfacts, ISSN 1861-1958, 07/2012, Volume 8, Issue 7, pp. 0778 - 0778
Journal Article
Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 12, pp. 3086 - 3089
The first palladium-catalyzed direct monofluoromethylation of arylboronic esters to produce monofluoromethyl arenes is reported. The reaction is typically... 
ARYL BROMIDES | ACTIVATION | FACILE ACCESS | LIGANDS | ACIDS | COPPER-MEDIATED DIFLUOROMETHYLATION | FLUOROALKYLATION | CHEMISTRY, ORGANIC | FLUORINE | TRIFLUOROMETHYLATION
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 11, pp. 3181 - 3185
An electrochemical difluoromethylation triggered lactonization of alkenes was developed for the first time. This protocol employs readily prepared CF2HSO2Na as... 
DIFUNCTIONALIZATION | HETEROARENES | ACTIVATION | COPPER-MEDIATED DIFLUOROMETHYLATION | FLUOROALKYLATION | RADICAL TRIFLUOROMETHYLATION | ARYL | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS | STRATEGIES
Journal Article
by Li, G and Wang, T and Fei, F and Su, YM and Li, Y and Lan, Q and Wang, XS
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2016, Volume 55, Issue 10, pp. 3491 - 3495
The first example of nickel-catalyzed decarboxylative fluoroalkylation of ,-unsaturated carboxylic acids has been developed with commonly available fluoroalkyl... 
nickel | fluoroalkylation | radicals | COPPER-MEDIATED TRIFLUOROMETHYLATION | FLUORINATION | CHEMISTRY, MULTIDISCIPLINARY | olefins | ARYLBORONIC ACIDS | ALKENES | CROSS-COUPLING REACTIONS | ALKYL FLUORIDES | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | FACILE ACCESS | synthetic methods | Acrylic acid | Nickel | Organic acids | Acids | Stereoselectivity | Transformation | Carboxylic acids | Catalysis | Halides
Journal Article