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mediated radical aryldifluoroacetylation (11) 11
chemistry, organic (9) 9
alkynes (5) 5
ethyl bromodifluoroacetate (5) 5
c-h functionalization (4) 4
difluoroalkylation (4) 4
substrates (4) 4
aryl boronic acids (3) 3
chemistry, multidisciplinary (3) 3
difluoroacetylation (3) 3
light photoredox catalysis (3) 3
photoredox catalysis (3) 3
radicals (3) 3
room-temperature (3) 3
alpha-arylation (2) 2
aryl diazonium salts (2) 2
arylation (2) 2
arylboronic acids (2) 2
bromides (2) 2
catalysis (2) 2
chemistry, applied (2) 2
coordination compounds (2) 2
fluoroalkylation reactions (2) 2
functionalisation (2) 2
funktionalisierung (2) 2
hydrotrifluoromethylation (2) 2
isocyanide insertion (2) 2
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light (2) 2
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organic chemistry (2) 2
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phenanthridine derivatives (2) 2
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usage (2) 2
visible light (2) 2
3-component reaction (1) 1
[ chim ] chemical sciences (1) 1
acetylation (1) 1
acetylieren (1) 1
acids (1) 1
agrochemical (1) 1
agrochemikalie (1) 1
aldehydes (1) 1
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alpha,beta-unsaturated carboxylic-acids (1) 1
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alzheimers-disease (1) 1
amination (1) 1
amines (1) 1
aminierung (1) 1
amino-acids (1) 1
aniline (1) 1
aryldifluoroacetylation (1) 1
arylierung (1) 1
aryltrifluoromethylation (1) 1
bearing (1) 1
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benzylation (1) 1
benzylierung (1) 1
biological evaluation (1) 1
bond formation (1) 1
bond-formation (1) 1
c(sp (1) 1
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chemische energie (1) 1
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copper-catalyzed trifluoromethylation (1) 1
c−h bond functionalization (1) 1
c−h functionalization (1) 1
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derivatives (1) 1
difluoromethylation (1) 1
difunctionalization (1) 1
direct arylation (1) 1
direct difluoromethylation (1) 1
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Organic Letters, ISSN 1523-7060, 11/2015, Volume 17, Issue 21, pp. 5188 - 5191
A palladium-catalyzed aryldifluoroalkylation of alkynes with ethyl difluoroiodoacetate and arylboronic acids as reaction partners is described. The alkyne... 
ETHYL BROMODIFLUOROACETATE | DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | HYDROTRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | DIFLUOROACETYLATION | OXIDATIVE TRIFLUOROMETHYLATION | DIFLUOROALKYLATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | UNACTIVATED ALKENES | BOND-FORMATION
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2018, Volume 118, Issue 16, pp. 7532 - 7585
Transition metal-catalyzed C–H bond functionalizations have been the focus of intensive research over the last decades for the formation of C–C bonds from... 
H FUNCTIONALIZATION | ROOM-TEMPERATURE | DIRECT ARYLATION | ARYL DIAZONIUM SALTS | VISIBLE-LIGHT PHOTOREDOX | PYRIDINE N-OXIDES | SINGLE-ELECTRON TRANSMETALATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | CARBOXYLIC-ACIDS | Chemical Sciences
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2015, Volume 80, Issue 24, pp. 12599 - 12605
A novel visible-light-induced carboperfluoroalkylation of alkenes using perfluoroalkyl iodides and bromides as Rf sources, leading to isoquinoline-1,3-diones,... 
DIFUNCTIONALIZATION | ROOM-TEMPERATURE | IODIDES | ALLYLIC ALCOHOLS | HYDROTRIFLUOROMETHYLATION | OXINDOLES | CHEMISTRY, ORGANIC | ALKYNES | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | PHOTOREDOX CATALYSIS | TRIFLUOROMETHYLATION | Usage | Research | Ring formation (Chemistry) | Chemical synthesis | Light
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 68, pp. 10396 - 10399
A novel copper-catalyzed difluoromethylation of 2- or 3-propargylamide-substituted indoles with ICF2CO2Et via a radical cascade cyclization process is... 
PALLADIUM | ETHYL BROMODIFLUOROACETATE | ARYL BORONIC ACIDS | ALPHA-ARYLATION | LIGHT PHOTOREDOX CATALYSIS | C-H FUNCTIONALIZATION | ALKYNES | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS
Journal Article
by Wang, XL and Wan, W and Chen, YR and Li, JL and Jiang, HZ and Wang, Y and Deng, HM and Hao, J
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 08/2016, Issue 22, pp. 3773 - 3779
A simple AgI-mediated direct difluoromethylation reaction of activated alkenes by using TMSCF2COOEt (TMS = trimethylsilyl) under mild reaction conditions has... 
ROOM-TEMPERATURE | Fluorine | ACIDS | N-ARYLACRYLAMIDES | CHEMISTRY, ORGANIC | BOND FORMATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | Radicals | Silver | EFFICIENT ACCESS | ARYLTRIFLUOROMETHYLATION | COPPER-CATALYZED TRIFLUOROMETHYLATION | Nitrogen heterocycles | Domino reactions | BEARING | GEM-DIFLUOROMETHYLENATION
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 08/2016, Volume 52, Issue 68, pp. 10396 - 10399
A novel copper-catalyzed difluoromethylation of 2- or 3-propargylamide-substituted indoles with ICF2CO2Et via a radical cascade cyclization process is... 
Synthesis | Cascades | Indoles | Derivatives | Compatibility | Substrates | Radicals
Journal Article
by Yin, GJ and Zhu, M and Fu, WJ
JOURNAL OF FLUORINE CHEMISTRY, ISSN 0022-1139, 07/2017, Volume 199, pp. 14 - 19
A visible-light-mediated direct and regioselective difluoroacetylation reaction of imidazoheterocycles by using BrCF2CO2Et under mild reaction conditions has... 
CATALYSIS | ETHYL BROMODIFLUOROACETATE | Imidazoheterocycles | Regioselectivity | CHEMISTRY, ORGANIC | THIOCYANATION | C-H functionalization | DIFLUOROALKYLATION | Difluoroacetylation | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | DISCOVERY | CHEMISTRY, INORGANIC & NUCLEAR | INHIBITORS | FLUOROALKYLATION REACTIONS | Photoredox
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 01/2018, Volume 5, Issue 1, pp. 19 - 23
3-Difluoroacetylated quinolines and 3-fluoroacetylated quinolines were synthesized via a visible-light-induced cascade addition/cyclization of N-propargyl... 
ELECTROPHILIC CYCLIZATION | PHENANTHRIDINE DERIVATIVES | 3-COMPONENT REACTION | ARYLATION | CHEMISTRY, ORGANIC | ISOCYANIDE INSERTION | ALKYNES | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | TERT-BUTYL HYDROPEROXIDE | N-(2-ALKYNYL)ANILINES | SUBSTITUTED QUINOLINES | Quinolines | Amines | Aniline | Benzene | Light effects | Substrates | Organic compounds
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 04/2017, Volume 6, Issue 4, pp. 453 - 457
A mild and efficient photocatalytic protocol for the synthesis of 3‐aryl‐2‐difluoroacetyl indenones has been established. The reaction sequence involves... 
indenones | difluoroacetylation | photoredox | visible light catalysis | photocatalysis | PHENANTHRIDINE DERIVATIVES | ALZHEIMERS-DISEASE | CHEMISTRY, ORGANIC | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | ESTROGEN-RECEPTOR | PHOTOREDOX CATALYSIS | MEDICINAL CHEMISTRY | AMINO-ACIDS | BIOLOGICAL EVALUATION | ISOCYANIDE INSERTION | FLUOROALKYLATION REACTIONS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2017, Volume 82, Issue 13, pp. 6811 - 6818
A novel copper-catalyzed cascade difluoromethylation/cyclization of 2-(3-arylpropioloyl)­benzaldehydes has been developed. This method affords an efficient and... 
VISIBLE-LIGHT | ALKENES | MEDIATED DIFLUOROMETHYLATION | ETHYL BROMODIFLUOROACETATE | PHOSPHONATES | ARYLDIFLUOROACETYLATION | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | ALDEHYDES | ALKYNES | DIFLUOROALKYLATION | Usage | Ring formation (Chemistry) | Chemical properties | Aldehydes | Quinone
Journal Article
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