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Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10581 - 10584
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 25, pp. 8466 - 8470
...‐coupling involving carboranes. Here, we report our efforts in isolating metal‐boryl complexes to further our understanding of one of these elementary steps, oxidative addition... 
cross-coupling | palladium | platinum | boron | carboranes | O-CARBORANES | REACTIVITY | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | B-H ACTIVATION | PINCER IRIDIUM COMPLEXES | CROSS-COUPLING REACTIONS | CLUSTERS | BORON-CARBON BONDS | CATALYZED AMINATION | LIGAND | Bonds | Palladium | Cross coupling | Precursors | Platinum | Reagents | Carborane | Three dimensional | Icosahedral phase
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 33, pp. 9586 - 9590
Cobalt boryl complexes, which have only been sporadically reported, can be accessed systematically with remarkable (but controllable... 
insertion reactions | cobalt | carbonyl ligands | boron | boryl ligands | ANION | REACTIVITY | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | B BONDS | CROSS-COUPLING REACTIONS | CARBON-MONOXIDE | CHEMISTRY | PLATINUM-CATALYZED DIBORATION | Precious metals | Cobalt | Ligands | Platinum | Olefins | Insertion | Noble metals | Bonding | Elongation
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 10, pp. 2403 - 2409
... mono‐boryl‐substituted derivatives, have been determined by single‐crystal X‐ray diffraction. In addition, the optical and electrochemical properties of the mixed sandwich complexes are reported... 
sandwich complexes | scandium | metalation | cyclooctatetraenyl | metallocenes | CRYSTAL-STRUCTURE | REACTIVITY | POLYMERIZATION | CYCLOPENTADIENYL | F-ELEMENT | CHEMISTRY, MULTIDISCIPLINARY | METAL COMPLEXES | CYCLOOCTATETRAENYL COMPLEXES | LIGANDS | STRUCTURAL CHEMISTRY | DERIVATIVES | Rare earth metals | Metallocenes | Electrochemical analysis | Crystals | X-ray diffraction | Derivatives | Substitutes | Single crystals | Synthesis | Optical properties | Scandium | Tetrahydrofuran | Electrochemistry | Scandium compounds | Ligands
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 40, pp. 13402 - 13407
The synthesis of base‐stabilized boryl and borylene complexes is reported. An N‐heterocyclic carbene (NHC)‐stabilized iron... 
carbenes | borylene complexes | iron | boryl complexes | boron | SUBSTITUTION | COORDINATION SPHERE | REACTIVITY | PLATINUM | STRUCTURAL-CHARACTERIZATION | REACTION CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | BOND ACTIVATION | LIGAND | TRANSITION-METAL-BORYL | Methane | Iron | Anions | Synthesis | Cationic | Halides | Lewis base | Carbenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2007, Volume 46, Issue 12, pp. 1946 - 1948
...‐workers have obtained the first three‐coordinate boryl anion (see formula), which provides an unprecedented and synthetically highly useful source for a nucleophilic... 
organoboranes | boryl compounds | boron | Boron | Boryl compounds | Organoboranes | SUBSTITUTION | TRANSITION-METAL-COMPLEXES | HYDROBORATIONS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALUMINUM | CARBENE ANALOGS | CHEMISTRY | LIGAND | GALLIUM
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16363 - 16366
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
boranes | diborane | magnesium | main-group chemistry | boryl groups | METAL-PROMOTED REACTIONS | NUCLEOPHILIC BORON | HYDRIDE ABSTRACTION | ORGANIC-SYNTHESIS | SINGLE | CARBORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | HYDROBORANE | CHEMISTRY | Chemical tests and reagents | Isomerization | Organoboranes | Diborane | Magnesium | Bonding | Thermal stability | Communications | Communication
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2016, Volume 7, Issue 1, pp. 803 - 809
A well-defined scandium boryl oxycarbene complex undergoes coupling with CO, C–H activation of lutidine, and cyclopropanation with ethylene... 
INSERTION CHEMISTRY | C-H BOND | MOLECULAR-STRUCTURE | X-RAY-STRUCTURE | MIGRATORY-INSERTION | CARBENE-PYRIDINE YLIDE | SPECTROSCOPIC OBSERVATION | ETA-2-ACYL COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL-BORYL | CARBON-MONOXIDE ACTIVATION | Pyridines | Scandium | Ethylene | Insertion | Chemical bonds | Ligands | Carbenes | Bonding
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2008, Volume 130, Issue 16, pp. 5586 - 5594
The detailed mechanism for the diboration of aldehydes catalyzed by (NHC)Cu(boryl) complexes (NHC = N-heterocyclic carbene... 
2-SUBSTITUTED INDOLES | HYDROBORATION | BORON | TRANSITION-METAL-COMPLEXES | IRIDIUM COMPLEXES | COUPLING REACTION | ARENES | REGIOSPECIFIC FUNCTIONALIZATION | BASIS-SET | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 25, Issue 16, pp. 4031 - 4035
Two novel boron‐centered diradicals based on dimesitylpyridine borane (1) were synthesized by the self‐assembling of the corresponding radical sodium and... 
diradicals | self-assembly | SQUID measurements | boron-based diradicals | boron | EPR spectroscopy | PERSISTENT | COMPLEXES | IONS | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | MOLECULES | REDUCTION | BIRADICALS | CHEMISTRY | Toluene | Spectroscopy | Salts | Metals | Crystals | Ground state | Potassium salts | Boron | Anions | Energy gap | Sodium | Potassium | Electrons
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 5/2014, Volume 4, Issue 6, pp. 1699 - 179
Journal Article
Inorganic chemistry, ISSN 0020-1669, 02/2019, Volume 58, Issue 4, pp. 2346 - 2353
...], 1, and 1-thioformyl-2,6-tetrahydro-1,3,5-trithia-2,6-diborinane complex, [(Cp*Ru)­{(η2-SCHS)­CH2S2(BH2)2}], 2. To investigate the reaction pathway for the formation of 2, we carried out the reaction... 
CLUSTERS SYNTHESIS | ELECTRONIC-STRUCTURES | CP-ASTERISK | BORON | POLYCYCLIC AROMATICS | CHEMISTRY | B-H ACTIVATION | DIRHODIUM ANALOGS | METAL-COMPLEXES | BORYLENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Catalysis science & technology, ISSN 2044-4761, 2018, Volume 8, Issue 13, pp. 3395 - 3405
Journal Article
Organometallics, ISSN 0276-7333, 11/2019, Volume 38, Issue 21, pp. 4183 - 4192
Reactions of complexes RhH­{κ3-P,O,P-[xant­(PiPr2)2]} (1) and Rh­(Bpin)­{κ3-P,O,P-[xant­(PiPr2)2]} (2; Bpin = pinacolboryl, xant­(PiPr2)2... 
RHODIUM | IRIDIUM COMPLEXES | POP-PINCER OSMIUM | TRANSITION-METAL | DEHYDROPOLYMERIZATION | CHEMISTRY, ORGANIC | RUTHENIUM | S-SUBSTITUTED ALDEHYDES | C-H BONDS | ACTIVATION REACTIONS | CONJUGATE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article