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Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11559 - 11563
Uranium(IV)–carbene–imido complexes [U(BIPMTMS)(NCPh3)(κ2‐N,N′‐BIPY)] (2; BIPMTMS=C(PPh2NSiMe3)2; BIPY=2,2‐bipyridine) and [U(BIPMTMS)(NCPh3)(DMAP)2] (3;... 
carbenes | density functional calculations | imido compounds | metalla-allenes | uranium | Ligands | Uranium | Pyridines | Chemistry | Stability | Isomerization | Feasibility | Clear cutting
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10530 - 10534
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 12/2017, Volume 36, Issue 23, pp. 4519 - 4524
Reaction of the Th(IV) metallacycle [Th(CH2SiMe2NSiMe3)(NR2)(2)] (1; R = SiMe3), with Ph3P=CH2 affords the Th(IV) carbene [Th(CHPPh3)(NR2)(3)] (2) in good... 
URANIUM | INFRARED-SPECTRA | METHYLIDENE COMPLEXES | U-IV=C | MOLECULAR-STRUCTURE | REACTIVITY | CHEMISTRY, ORGANIC | CARBON MULTIPLE BOND | METALLA-ALLENES | LIGAND | TRANS-INFLUENCE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10495 - 10500
Reaction of [U(Tren(TIPS))(PH2)] (1, Tren(TIPS)=N(CH(2)CH(2)NSiPri(3))(3)) with C6H5CH2K and [U(Tren(TIPS))(THF)][BPh4] (2) afforded a rare diuranium parent... 
U-IV=C | URANIUM COMPLEXES | phosphinidiide | metal-ligand multiple bonding | CHEMISTRY, MULTIDISCIPLINARY | TRIAMIDOAMINE COMPLEXES | TERMINAL PHOSPHIDE | phosphido | density functional theory | uranium | METALLA-ALLENES | MULTIPLE BONDS | URANYL-ION | PHOSPHORUS TRIPLE BOND | OXO COMPLEX | TRANS-INFLUENCE
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11559 - 11563
Uranium(IV)-carbene-imido complexes [U(BIPMTMS)(NCPh3)(kappa(2)-N,N'-BIPY)] (2; BIPMTMS=C(PPh2NSiMe3)(2); BIPY=2,2-bipyridine) and [U(BIPMTMS)(NCPh3)(DMAP)(2)]... 
imido compounds | INVERSE TRANSINFLUENCE | CARBON BONDS | carbenes | CHEMISTRY, MULTIDISCIPLINARY | ACTINYL IONS | density functional calculations | metalla-allenes | REDUCTIVE SILYLATION | FUNCTIONAL-GROUPS | uranium | VALENT ORGANOURANIUM COMPLEXES | URANYL-ION | MULTIPLE BONDS | OXO COMPLEX | ELECTRONIC-STRUCTURE
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 10/2017, Volume 56, Issue 42, pp. 12925 - 12929
The reaction of (C5Me5)(2)Th(CH3)(2) with the phosphonium salts [CH3PPh3]X (X=Cl, Br, I) was investigated. When X=Br and I, two equivalents of methane are... 
PH2PNSIME3 | ylides | U-IV=C | MOLECULAR-STRUCTURE | multiple bonding | carbenes | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | organometallics | thorium | URANIUM COMPLEX | CHEMISTRY | CARBON MULTIPLE BOND | METALLA-ALLENES | LIGAND | TRANS-INFLUENCE | Physics | Chemical Sciences
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11554 - 11558
We report uranium(IV)‐carbene‐imido‐amide metalla‐allene complexes [U(BIPMTMS)(NCPh3)(NHCPh3)(M)] (BIPMTMS=C(PPh2NSiMe3)2; M=Li or K) that can be described as... 
push–pull effect | amido | imido | metalla-allene | uranium | carbene | Reproduction | Uranium | Allene | Alkali metals | Computer applications | Lithium | Attenuation | Cations | Potassium | Heavy metals
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11554 - 11558
We report uranium(IV)-carbene-imido-amide metalla-allene complexes [U(BIPMTMS)(NCPh3)(NHCPh3)(M)] (BIPMTMS=C(PPh2NSiMe3)(2); M = Li or K) that can be described... 
push-pull effect | amido | U-IV=C | COMPLEXES | REACTIVITY | U(IV) | imido | carbene | CHEMISTRY, MULTIDISCIPLINARY | metalla-allene | uranium | MULTIPLE BONDS | V=C
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 06/1988, Volume 43, Issue 6, pp. 722 - 726
Square-planar vinylidene rhodium complexes trans-[RhCl( = C=CHR)(PPr ] (X-XII) are prepared either by isomerization of trans-[RhCl(RC≡CH)(PPr ] in hexane at 50... 
X-Ray | Metalla-allene Type Structure | Vinylidene Rhodium Complexes | NMR Spectra | Synthesis from Alkyne and Alkynyl(hydrido) Precursors
Journal Article
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