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metallaboratranes (51) 51
chemistry, inorganic & nuclear (42) 42
reactivity (32) 32
ligands (24) 24
chemistry, multidisciplinary (23) 23
coordination (22) 22
metallaboratrane (21) 21
structural-characterization (20) 20
boron (19) 19
chemistry, organic (19) 19
rhodium (19) 19
transition-metal-complexes (18) 18
dative sigma-bond (15) 15
methimazolyl (15) 15
polyazolyl chelate chemistry (15) 15
trisborane complexes (14) 14
activation (13) 13
borane (13) 13
ligand (12) 12
bu-t (11) 11
oxidative addition (10) 10
complexes (9) 9
bond (8) 8
chemistry (8) 8
platinum (8) 8
rhodaboratrane (8) 8
ruthenium (8) 8
hydride migration (7) 7
synthesis (7) 7
bisborane (6) 6
catalysis (6) 6
transition metals (6) 6
ambiphilic ligands (5) 5
boranes (5) 5
coordination chemistry (5) 5
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crystal-structure (5) 5
iron (5) 5
platinaboratranes (5) 5
zinc (5) 5
bonding (4) 4
borylene complexes (4) 4
coordination modes (4) 4
crystallography, x-ray (4) 4
h activation (4) 4
hydrogenation (4) 4
hydrotrisborate (4) 4
palladium (4) 4
palladium complexes (4) 4
transition-metal (4) 4
transition-metals (4) 4
übergangsmetalle (4) 4
agostic interactions (3) 3
alternative ligands (3) 3
block metals (3) 3
bor (3) 3
borataallyl (3) 3
cat=1,2-o2c6h4 (3) 3
chelate chemistry (3) 3
chemical properties (3) 3
chemical sciences (3) 3
cobalt (3) 3
cp-asterisk (3) 3
crystal-structures (3) 3
derivatives (3) 3
gold (3) 3
iridium (3) 3
lewis acids (3) 3
metal-borane complexes (3) 3
metal-complexes (3) 3
models, molecular (3) 3
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mt (3) 3
organometallic chemistry (3) 3
organometallic compounds - chemistry (3) 3
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silicon (3) 3
vinylborane (3) 3
[ chim ] chemical sciences (2) 2
[chim.cata]chemical sciences/catalysis (2) 2
[chim.coor]chemical sciences/coordination chemistry (2) 2
[chim.orga]chemical sciences/organic chemistry (2) 2
[chim.poly]chemical sciences/polymers (2) 2
[chim.theo]chemical sciences/theoretical and/or physical chemistry (2) 2
ambiphilic ligand (2) 2
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borate (2) 2
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chemisches reaktionsvermögen (2) 2
chemistry, physical (2) 2
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copper (2) 2
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Chemical Society reviews, ISSN 1460-4744, 2012, Volume 41, Issue 9, pp. 3535 - 3546
Ligand cooperation has become an important strategy in the development of new transition metal based transformations. By using this approach some remarkable... 
ACTIVATION | BORON | TRANSITION-METAL-COMPLEXES | HYDRIDE MIGRATION | DATIVE SIGMA-BOND | REACTIVITY | TRIS(METHIMAZOLYL)BORANE COMPLEXES | METALLABORATRANES | CHEMISTRY, MULTIDISCIPLINARY | CHELATE CHEMISTRY
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9234, 2011, Volume 40, Issue 3, pp. 549 - 558
While the vast majority of inorganic chemistry involves electron donation from main-group atoms to metals, an intriguing yet flip-side exists: where... 
SIGMA-BOND | BLOCK METALS | BU-T | REACTIVITY | TRIS(METHIMAZOLYL)BORANE COMPLEXES | METALLABORATRANES | OXIDATIVE ADDITION | BORANE | BORYLENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Spectroscopy | Boron | Correlation | Transition metals | Ligands | Electron density | Lewis base | Bonding
Journal Article
Chemistry, an Asian journal, ISSN 1861-4728, 08/2013, Volume 8, Issue 8, pp. 1720 - 1734
Synergistic effects between a transition metal and an appropriate ligand are required to promote a desired catalytic reaction. Ancillary ligands, provided by... 
boranes | chelates | multidentate ligands | coordination chemistry | transition metals | CATALYSIS | PALLADIUM | RHODIUM | IRIDIUM | BU-T | DATIVE SIGMA-BOND | PLATINUM | CHEMISTRY, MULTIDISCIPLINARY | METAL-BORANE COMPLEXES | PINCER COMPLEXES | METALLABORATRANES
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 72, pp. 18264 - 18275
Journal Article
Organometallics, ISSN 0276-7333, 05/2013, Volume 32, Issue 10, pp. 3053 - 3062
Reversible, heterolytic addition of H2 across an iron–boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride... 
Metallaboratrane | non-noble metal hydrogenation catalysis | heterolytic dihydrogen activation
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2013, Volume 135, Issue 23, pp. 8508 - 8511
The PBP ligand (Ph2PC6H4)(2)BPh was used to prepare ((Ph2PC6H4)(2)B(Cl)(eta(6)-Ph)RuCI (1) and subsequently [((Ph2PC6H4)(2)B(eta(6)-Ph))RuCl][B(C6F5)(4)] (2).... 
CARBENE | RHODIUM | AMBIPHILIC LIGANDS | METALLABORATRANES | COORDINATION | H2 ACTIVATION | METAL | BORANE | CHEMISTRY, MULTIDISCIPLINARY | PAIRS
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 27, pp. 8797 - 8805
We herein report detailed investigations into the interaction of Lewis acidic fluoroboranes, for example BF2Pf (Pf=perfluorophenyl) and BF2ArF... 
Lewis acids | density functional calculations | fluoroboranes | transition metals | SIGMA-BOND | ACTIVATION | BORON-TRIFLUORIDE | TRANSITION-METAL-COMPLEXES | BU-T | METALLABORATRANE | OXIDATIVE ADDITION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | BORYL COMPLEXES | PAIRS | Platinum | Lewis acid | Ethene | Boranes | Mathematical models | Lewis base | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 9, pp. 2063 - 2067
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2006, Volume 128, Issue 37, pp. 12056 - 12057
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2014, Volume 136, Issue 29, pp. 10262 - 10265
The synthesis of a three-coordinate Pt-borane complex featuring a bidentate "LZ" (boryl)iminomethane (BIM) ligand is reported. Unlike other LZ-type borane... 
CATALYSIS | HYDROGENATION | BORON | REDUCTION | METALLABORATRANE | CO2 | REACTIVITY | PLATINUM | AMBIPHILIC LIGANDS | H-2 | CHEMISTRY, MULTIDISCIPLINARY | Transition metals | Chemical properties | Research
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 09/2015, Volume 21, Issue 39, pp. 13732 - 13738
A high‐yielding synthetic route for the preparation of group 9 metallaboratrane complexes [Cp*MBH(L)2], 1 and 2 (1, M=Rh, 2, M=Ir; L=C7H4NS2) has been... 
coordination modes | N,S‐heterocyclic ligands | borataallyl | metallaboratrane | vinylborane | rhodium
Journal Article