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metallocorroles (107) 107
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Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2017, Volume 53, Issue 96, pp. 12942 - 12945
Four β-pyrrole-substituted cobalt(iii) corroles were studied as electrocatalysts for the oxygen reduction reaction. The results disclose high dependence of the... 
Journal Article
Chemical Reviews, ISSN 0009-2665, 02/2017, Volume 117, Issue 4, pp. 3377 - 3419
This review describes the known electrochemistry of corroles in nonaqueous media from 1980 until the present. The outline of the review is grouped according to... 
ARYL-SUBSTITUTED CORROLES | PI-CATION RADICALS | RAY STRUCTURAL-CHARACTERIZATION | TRANSITION-METAL-COMPLEXES | FREE-BASE CORROLES | PHOTOINDUCED CHARGE SEPARATION | TRIPLE-DECKER COMPLEXES | GROUP 9 METALLOCORROLES | OXIDATION-STATES | OXYGEN REDUCTION REACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2019, Volume 2019, Issue 44, pp. 4760 - 4765
In this work, we report the investigation of Fe and Co triphenylcorrole complexes supported on two different carbon supports as eletrocatalysts for the ORR in... 
Porphyrinoids | Oxygen Reduction Reaction | PGM‐Free Catalyst | Metallocorroles | Microbial Fuel Cell
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 96, pp. 12942 - 12945
Four beta-pyrrole-substituted cobalt(III) corroles were studied as electro-catalysts for the oxygen reduction reaction. The results disclose high dependence of... 
METALLOCORROLES | COORDINATION CHEMISTRY | DIOXYGEN | EVOLUTION | COBALT CORROLE | COMPLEXES | PORPHYRIN | CHEMISTRY, MULTIDISCIPLINARY | ELECTROCATALYSTS | Reduction | Catalysis | Electrochemical activation | Electrocatalysts
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 29, pp. 9481 - 9490
Corroles have been previously demonstrated to be a new and promising photosensitizer (PS) in photodynamic therapy (PDT) for cancer cells. This research... 
NUCLEASE ACTIVITY | CANCER-CELLS | METALLOCORROLES | APOPTOSIS | DNA-BINDING | REACTIVE OXYGEN | CORROLES | PHOTOCYTOTOXICITY | COMPLEXES | BIOLOGICAL EVALUATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 07/2017, Volume 46, Issue 29, pp. 9481 - 9490
Corroles have been previously demonstrated to be a new and promising photosensitizer (PS) in photodynamic therapy (PDT) for cancer cells. This research... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 2, pp. 681 - 689
The first FeNO octabromocorroles have been synthesized including four beta-octabromo-meso-tris(p-X-phenyl)corrole derivatives Fe[Br(8)TpXPC](NO) (X = CF3, H,... 
METALLOCORROLES | ROUTE | APPROXIMATION | METAL CENTERS | REACTIVITY | CHEMISTRY | IRON | STRAIGHT | REDUCTIVE DEMETALATION | SPECTRA | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry Communications, ISSN 1387-7003, 12/2017, Volume 86, pp. 168 - 171
A new general and green synthetic protocol for the synthesis of manganese(III) metallocorroles has been developed from substituted aryl aldehydes and... 
One-pot method | Corroles | Green chemistry | Metallocorroles | Dipyrromethane
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2019, Volume 141, Issue 36, pp. 14443 - 14450
The corrole unit from the porphyrinoid family represents one of the most important ligands in the field of coordination chemistry, which creates a unique... 
OXYGEN | METALLOCORROLES | MOF | MANGANESE | STABILITY | DIELS-ALDER REACTION | CO2 | CHEMISTRY | CATALYZED 4+2 CYCLOADDITION | ADSORPTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 08/2019, Volume 48, Issue 32, pp. 12279 - 12286
Tris- and tetrakis-beta-trifluoromethylated gallium (3CF(3)-Ga, 4CF(3)-Ga) and aluminum (3CF(3)-Al, 4CF(3)-Al) corrole systems were synthesized by a facile... 
METALLOCORROLES | HALIDES | SUBSTITUTION | DIOXYGEN | BENZENE | OXYGENATION | EXPANDED PORPHYRINS | ARYL | SELECTIVE HALOGENATION | TRIFLUOROMETHYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2015, Volume 54, Issue 46, pp. 13769 - 13774
The most common oxidation states of copper in stable complexes are +I and +II. Cu-III complexes are often considered as intermediates in biological and... 
METALLOCORROLES | CATALYSIS | ACTIVATION | higher oxidation states | WATER-OXIDATION | spectroelectrochemistry | copper corroles | STATE | XANES measurements | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | CU(III) | EPR spectroscopy
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2006, Volume 128, Issue 38, pp. 12380 - 12381
Directly linked corrole dimer 1, which has a planar cyclooctatetraene in its core, has been synthesized from 2-borylcorrole in excellent yield.... 
METALLOCORROLES | SUBSTITUTED CORROLES | CHEMISTRY, MULTIDISCIPLINARY | HYDROCARBON | COMPLEXES | Chemical synthesis | Analysis | Absorption spectra
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 5, pp. 877 - 880
Two cobalt-dioxygen adducts, [CoH8]-O-2 and [CoCl8]-O-2, chelated by electron-rich and electron-poor corroles, respectively, were isolated in solution.... 
METALLOCORROLES | ELECTROCHEMISTRY | COMPOUND-I | OXYGEN REDUCTION | APPROXIMATION | ANALOGS | WATER OXIDATION | CATALYST | PORPHYRIN | RESONANCE RAMAN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 05/2016, Volume 45, Issue 18, pp. 7815 - 7822
We report the stabilization of the hexa-coordination environment for P(v) corroles by using alkyl/aryl substituted silyloxy groups as axial ligands. The P(v)... 
Journal Article
Organic Letters, ISSN 1523-7060, 07/2015, Volume 17, Issue 13, pp. 3214 - 3217
Corroles and porphyrins With 2,6-pyrimidyl substituents are reported for the first time, together with the spectroscopic data and:the crystal structures of the... 
METALLOCORROLES | MNTNHEX-2-PYP5 | SENSING COMPONENTS | PEROXYNITRITE | CHEMISTRY | CHEMISTRY, ORGANIC | COBALT(III) CORROLES
Journal Article
Dalton Transactions, ISSN 1477-9226, 06/2015, Volume 44, Issue 22, pp. 10146 - 10151
Multiple lines of evidence, including electronic absorption spectroscopy, infrared spectroscopy, and broken-symmetry DFT calculations, indicate that the... 
METALLOCORROLES | APPROXIMATION | ELECTRONIC ABSORPTION | METAL CENTERS | COMPLEXES | REACTIVITY | CHEMISTRY | STRAIGHT | IRON(IV) | INSIGHTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2017, Volume 56, Issue 4, pp. 2287 - 2296
A minor modification of the reported procedure for the synthesis of a corrole dimer that is fused by the cyclooctatetraene (COT) unit, (H3tpfc)2COT, allowed... 
TRIPLET-STATE DELOCALIZATION | METALLOCORROLES | APPROXIMATION | CORROLES | CORRELATION-ENERGY | CHEMISTRY | REACTIVITY | COPPER | IDENTIFICATION | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2016, Volume 55, Issue 17, pp. 8920 - 8927
Cobalt, gallium, silver, and copper complexes of 5,5′-linked corrole dimer 1 and 10,10′-linked corrole dimer 2 were synthesized by metalations with... 
METALLOCORROLES | COPPER CORROLES | PYRROLE | MOLECULAR-STRUCTURE | REACTIVITY | CHEMISTRY | COBALT(III) | 1ST DIRECT SYNTHESIS | PHOTOPHYSICAL PROPERTIES | GALLIUM(III) CORROLES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2016, Volume 55, Issue 12, pp. 6061 - 6067
The fluorescence intensity of phosphorus corroles increases upon meso-aryl C–F/C–H and P–OH/P–F substitutions, the latter affects corrole-centered redox... 
ELECTROCHEMISTRY | METALLOCORROLES | FLUORESCENCE PROPERTIES | ENERGY | FREE-BASE CORROLES | COMPLEXES | PHOTOPHYSICAL PROPERTIES | PORPHYRIN | DERIVATIVES | OCTAETHYLCORROLES | CHEMISTRY, INORGANIC & NUCLEAR | Phosphorus compounds | Chemical properties | Research | Quantum chemistry
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 12/2007, Volume 46, Issue 25, pp. 10791 - 10799
The reaction of meso-triarylcorroles with AgNO2 proceeds with concomitant metalation and peripheral substitution to give the corresponding nitro-substituted... 
ELECTROCHEMISTRY | METALLOCORROLES | SUBSTITUTION | COPPER CORROLES | PORPHYRINS | COMPLEXES | 5,10,15-TRIPHENYLCORROLE | OCTAETHYLCORROLES | METALLOPORPHYRINS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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