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1. Full Text Transition-Metal-Free Oxidative α‑C–H Amination of Ketones via a Radical Mechanism: Mild Synthesis of α‑Amino Ketones
by Jiang, Qing and Xu, Bin and Zhao, An and Jia, Jing and Liu, Tian and Guo, Cancheng
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2014, Volume 79, Issue 18, pp. 8750 - 8756
A transition-metal-free direct α-C–H amination of ketones has been developed using commercially available ammonium iodide as the catalyst and sodium... 
FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | ACTIVATION | INTERMOLECULAR AMINATION | NATURAL-PRODUCTS | ARENES | CHEMISTRY, ORGANIC | AMBIENT-TEMPERATURE | N BOND FORMATION | METHYL KETONES | IMIDATION | Research | Chemical properties | Ketones | Chemical synthesis
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2. Full Text Ligand-Enabled γ‑C(sp3)–H Activation of Ketones
by Zhu, Ru-Yi and Li, Zi-Qi and Park, Han Seul and Senanayake, Chris H and Yu, Jin-Quan
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 10, pp. 3564 - 3568
We report the first example of Pd­(II)-catalyzed γ-C­(sp3)–H activation of ketones directed by a practical 2,2-dimethyl aminooxyacetic acid auxiliary.... 
FUNCTIONALIZATION | GAMMA | PALLADIUM | INTERMOLECULAR AMIDATION | C(SP)-H ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CATALYZED INTRAMOLECULAR AMINATION | Ligands | Molecular Structure | Catalysis | Manganese - chemistry | Pyridones - chemistry | Ketones - chemistry | Palladium | Chemical properties | Ketones | Acetic acid | Methyl groups
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3. Full Text Copper(I) Iodide‐Catalysed Aerobic Oxidative Synthesis of Imidazo[1,2‐a]pyridines from 2‐Aminopyridines and Methyl Ketones
by Chandra Mohan, Darapaneni and Reddy Donthiri, Ramachandra and Nageswara Rao, Sadu and Adimurthy, Subbarayappa
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2013, Volume 355, Issue 11‐12, pp. 2217 - 2221
We report here an operationally simple copper‐catalysed synthesis of imidazo[1,2‐a]pyridines through CH activation with oxidative linkage of two CN bonds... 
CH activation | copper | aerobic oxidation | zolimidine synthesis | imidazo[1,2‐a]pyridines | C-H activation | Zolimidine synthesis | Copper | Imidazo [1,2-α]pyridines | Aerobic oxidation | PALLADIUM | DIRECT ARYLATION | CHEMISTRY, ORGANIC | 2-a]pyridines | CARBON-HYDROGEN BONDS | IMIDAZOPYRIDINES | IMIDAZOLES | ALCOHOL OXIDATIONS | imidazo | CH activation | FACILE SYNTHESIS | OXIDANT | ARYL | CHEMISTRY, APPLIED | MOLECULAR-OXYGEN | Pyridine | Ketones | Gastrointestinal agents | Linkages | Sole | Synthesis | Activation | Tolerances | Assembly | Functional groups
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4. Full Text Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via β‑C(sp3)–H Activation
by Zhu, Ru-Yi and Liu, Luo-Yan and Park, Han Seul and Hong, Kai and Wu, Yongwei and Senanayake, Chris H and Yu, Jin-Quan
Journal of the American Chemical Society, ISSN 0002-7863, 11/2017, Volume 139, Issue 45, pp. 16080 - 16083
We report Pd­(II)-catalyzed β-C­(sp3)–H (hetero)­aryl­ation of a variety of ketones using a commercially available 2,2-dimethyl amino­oxy­acetic acid... 
FUNCTIONALIZATION | SUBSTITUTION | MACROCYCLES | ARYLATION | INTERMOLECULAR AMIDATION | UNACTIVATED METHYL-GROUPS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | Hydrocarbons, Aromatic - chemistry | Aminooxyacetic Acid - chemical synthesis | Aminooxyacetic Acid - chemistry | Ketones - chemical synthesis | Ketones - chemistry | Iodides - chemistry | Catalysis | Hydrocarbons, Aromatic - chemical synthesis | Iodides - chemical synthesis | Palladium - chemistry | Alkylation
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5. Full Text Highly Diastereo‐ and Enantioselective Palladium‐Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and α,β‐Unsaturated Ketones
by Xu, Chao‐Fan and Zheng, Bao‐Hui and Suo, Jia‐Jia and Ding, Chang‐Hua and Hou, Xue‐Long
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 5, pp. 1604 - 1607
A palladium‐catalyzed asymmetric [3+2] cycloaddition reaction of vinylaziridines with α,β‐unsaturated ketones, wherein the alkenes have a single activator, is... 
palladium | cycloaddition | asymmetric catalysis | heterocycles | synthetic methods | Heterocycles | Cycloaddition | Palladium | Synthetic methods | Asymmetric catalysis | SUBSTITUTED PYRROLIDINES | CASCADE REACTIONS | ALLYLIC ALKYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | ACYCLIC AMIDES | AMINATION | REGIO | ACTIVATED OLEFINS | ALKALOIDS | Alkenes - chemistry | Stereoisomerism | Ketones - chemistry | Catalysis | Aziridines - chemistry | Cycloaddition Reaction | Palladium - chemistry | Stereochemistry | Ketones | Asymmetry | Alkenes | Acetone
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6. Full Text Aldol Reactions of Ketone Donors with Aryl Trifluoromethyl Ketone Acceptors Catalyzed by 1,8‐Diazabicyclo[5.4.0]undec‐7‐ene (DBU) for Concise Access to Aryl‐ and Trifluoromethyl‐ Substituted Tertiary Alcohols
by Zhang, Dongxin and Tanaka, Fujie
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2015, Volume 357, Issue 16‐17, pp. 3458 - 3462
Molecules bearing aryl‐ and trifluoromethyl‐substituted tertiary alcohol moieties are important as bioactive molecules, enantiomer‐discriminating reagents, and... 
organocatalysis | regioselectivity | amines | aldol reaction | chiral resolution | VINYLOGOUS ALDOL | ESTERS | CONSTRUCTION | CHEMISTRY, ORGANIC | CHEMISTRY, APPLIED | Esters | Catalysis | Ketones | Chemical tests and reagents | Enantiomers | Aromatic compounds | Reagents | Chemical reactions | Aldehydes | Carbon | Alcohols
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7. Full Text Iridium-catalyzed selective α-methylation of ketones with methanol
by Ogawa, Shinji and Obora, Yasushi
Chemical Communications, ISSN 1359-7345, 03/2014, Volume 50, Issue 19, pp. 2491 - 2493
Iridium-catalyzed selective alpha-dimethylation and alpha-methylation of ketones or phenylacetonitriles, using methanol as the methylating agent, were... 
SECONDARY ALCOHOLS | DEHYDROGENATION | BETA-ALKYLATION | BORROWING HYDROGEN | COUPLING REACTION | BONDS | TRANSFER HYDROGENATION | CARBON-CARBON | PINCER COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | Ketones | Methyl alcohol | Alcohols
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8. Full Text CC Coupling of Ketones with Methanol Catalyzed by a N‐Heterocyclic Carbene–Phosphine Iridium Complex
by Quan, Xu and Kerdphon, Sutthichat and Andersson, Pher G and Stockholms universitet and Naturvetenskapliga fakulteten and Institutionen för organisk kemi
Chemistry – A European Journal, ISSN 0947-6539, 02/2015, Volume 21, Issue 9, pp. 3576 - 3579
An N‐heterocyclic carbene–phosphine iridium complex system was found to be a very efficient catalyst for the methylation of ketone via a hydrogen transfer... 
iridium | CC coupling reactions | ketones | hydrogen transfer | methylation | Hydrogen transfer | Iridium | Ketones | Methylation | C-C coupling reactions | TRANSITION-METAL CATALYSIS | BORROWING HYDROGEN | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | DEHYDROGENATION | TEMPERATURE | CC coupling reactions | ALPHA-ALKYLATION | PD(IPR-ASTERISK(OME))(CIN)CL CIN | BOND ACTIVATION | ACETONITRILE | Iridium compounds | Catalysts | Methyl alcohol | Branched | Bonding | Conversion | Naturvetenskap | C[BOND]C coupling reactions | Kemi | Natural Sciences | Organisk kemi | Chemical Sciences | Organic Chemistry
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9. Full Text Single‐Step Synthesis of 3‐Iodoquinolines from 2‐Aminophenyl Ketones through a Regioselective (6‐endo‐dig) Electrophilic Cyclization
by Yaragorla, Srinivasarao and Pareek, Abhishek and Dada, Ravikrishna and Saini, Pyare Lal
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2017, Volume 2017, Issue 31, pp. 4600 - 4608
A highly facile single‐step synthetic approach to 3‐iodoquinolines has been developed for the first time from readily available 2‐aminobenzophenones and... 
Nitrogen heterocycles | Cyclization | Regioselectivity | Cross‐coupling | Iodine | Cross-coupling | ORGANOBORON DERIVATIVES | VINYL CATIONS | METHYL AZAARENES | CHEMISTRY, ORGANIC | CASCADE SYNTHESIS | RING-SYSTEMS | C-H ACTIVATION | HIGHLY EFFICIENT | CROSS-COUPLING REACTIONS | FACILE SYNTHESIS | MULTIPLY SUBSTITUTED QUINOLINES | Ketones
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10. Full Text Pd(II)-Catalyzed Direct ortho-C–H Acylation of Aromatic Ketones by Oxidative Decarboxylation of α‑Oxocarboxylic Acids
by Lee, Pui-Yiu and Liang, Peiwen and Yu, Wing-Yiu
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 8, pp. 2082 - 2085
A Pd-catalyzed decarboxylative acylation of aromatic ketones with α-oxocarboxylic acids was developed, and 1,2-diacylbenzenes were formed in up to 90% yield... 
ARYL BROMIDES | ROOM-TEMPERATURE | REGIOSPECIFIC SYNTHESIS | ARENES | CHEMISTRY, ORGANIC | BOND ACTIVATION | FORMING REDUCTIVE ELIMINATION | DUAL CATALYSIS | TERT-BUTYL HYDROPEROXIDE | O-METHYL OXIMES | DIACYLBENZENES
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11. Full Text Metal‐Free CN‐ and NN‐Bond Formation: Synthesis of 1,2,3‐Triazoles from Ketones, N‐Tosylhydrazines, and Amines in One Pot
by Chen, Zhengkai and Yan, Qiangqiang and Liu, Zhanxiang and Zhang , Yuhong
Chemistry – A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 52, pp. 17635 - 17639
A novel synthetic approach toward 1,4‐disubstituted 1,2,3‐triazoles by CN‐ and NN‐bond formation has been established under transition‐metal‐free conditions.... 
metal‐free reactions | anilines | ketones | 1,2,3‐triazoles | synthetic methods | Anilines | Synthetic methods | Metal-free reactions | Ketones | 1 2 3-triazoles | metal-free reactions | 1,2,3-triazoles | AZIDE-ALKYNE CYCLOADDITION | 1,3-DIPOLAR CYCLOADDITIONS | CLICK CHEMISTRY | EFFICIENT SYNTHESIS | TERMINAL ALKYNES | TRIAZOLE FORMATION | CHEMISTRY, MULTIDISCIPLINARY | REGIOSELECTIVE SYNTHESIS | SULFONYL HYDRAZIDES | 1.3-DIPOLARE CYCLOADDITIONEN | METHYL KETONES | Amines - chemistry | Triazoles - chemistry | Metals | Ketones - chemistry | Tosyl Compounds - chemistry | Triazoles - chemical synthesis | Molecular Structure | Catalysis | Formations | Synthesis | Amines | Aniline | Iodine
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12. Full Text Tetrabutylammonium Fluoride (TBAF)-Catalyzed Addition of Substituted Trialkylsilylalkynes to Aldehydes, Ketones, and Trifluoromethyl Ketones
by Chintareddy, Venkat Reddy and Wadhwa, Kuldeep and Verkade, John G
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2011, Volume 76, Issue 11, pp. 4482 - 4488
Herein we report that tetrabutylammonium fluoride (TBAF) is a very efficient catalyst for the addition of trialkylsilylalkynes to aldehydes, ketones, and... 
PRACTICAL SYNTHESIS | PHENYLACETYLENE | TITANIUM COMPLEX | PROPARGYLIC ALCOHOLS | HILLMAN-TYPE ADDUCTS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | AROMATIC-ALDEHYDES | ENANTIOSELECTIVE ADDITION | CATALYTIC ALKYNYLATION | BASE | Ammonium compounds | Chemical reactions | Chemical properties | Ammonium paratungstate | Analysis | Methyl groups
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13. Full Text Organocatalyzed Enantioselective Conjugated Addition of Sodium Bisulfite to β‑Trifluoromethyl-α,β-unsaturated Ketones
by Hu, Wen-Fei and Zhao, Jian-Qiang and Chen, Yong-Zheng and Zhang, Xiao-Mei and Xu, Xiao-Ying and Yuan, Wei-Cheng
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2018, Volume 83, Issue 10, pp. 5771 - 5777
An efficient organocatalyzed enantioselective conjugated addition of sodium bisulfite to β-trifluoromethyl-α,β-unsaturated ketones using a cinchona... 
MEDICINAL CHEMISTRY | TRANSFORMATION | ASYMMETRIC-SYNTHESIS | ACID | TRIENAMINE CATALYSIS | PHARMACEUTICALS | CHEMISTRY, ORGANIC | BETA-LACTAM ANTIBIOTICS | FLUORINE | METHYL SULFONATES | DERIVATIVES
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14. Full Text Regioselective Copper‐Catalyzed Oxidative Cross‐Coupling of Imidazo[1,2‐a]pyridines with Methyl Ketones: An Efficient Route for Synthesis of 1,2‐Diketones
by Lei, Sai and Chen, GuiJun and Mai, Yingying and Chen, Longbin and Cai, Huiyin and Tan, Jingwen and Cao, Hua
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2016, Volume 358, Issue 1, pp. 67 - 73
An efficient copper‐catalyzed oxidative coupling of imidazo[1,2‐a]pyridines with methyl ketones to directly generate structurally sophisticated 1,2‐dicarbonyl... 
methyl ketones | copper catalysts | cross‐coupling | 1,2‐diketones | imidazo[1,2‐a]pyridines | cross-coupling | imidazo[1,2-a]pyridines | 1,2-diketones | DIRECT ARYLATION | HECK | ONE-POT SYNTHESIS | C-N | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | DIRECT ACCESS | CLEAVAGE | INDOLES | ARYL BROMIDES | imidazo[1,2-a] pyridines | CHEMISTRY, APPLIED | METAL-FREE | Drugstores | Pyridine | Ketones | Copper | Pharmacy | Coupling (molecular) | Oxygen | Cross coupling | Synthesis | Oxidants | Derivatives | Catalysis
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15. Methyl ethyl ketone
and International Labour Organisation and World Health Organization and International Program on Chemical SafetyUnited Nations Environment Programme
1993, Environmental health criteria, ISBN 9241571438, Volume 143, 161
Environmental aspects | Toxicology | Organic solvents | Physiological effect | Methyl ethyl ketone
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16. Full Text Palladium‐Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study
by Huo, Xiaohong and Yang, Guoqiang and Liu, Delong and Liu, Yangang and Gridnev, Ilya D and Zhang, Wanbin
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 26, pp. 6776 - 6780
Allylic alcohols were directly used in Pd‐catalyzed allylic alkylations of simple ketones under mild reaction conditions. The reaction proceeded smoothly at 20... 
organocatalysis | DFT calculation | palladium | allylic alcohol | allylic alkylation | ACID | PLATINUM | ALDEHYDES | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC ALPHA-ALLYLATION | DIRECT AMINATION | LIGANDS | TRANSITION-METAL | COUPLING REACTION | SELECTIVE SYNTHESIS | Propanols - chemistry | Thermodynamics | Hydrogen Bonding | Ketones - chemistry | Catalysis | Methanol - chemistry | Coordination Complexes - chemistry | Palladium - chemistry | Alkylation | Aldehydes - chemistry | Palladium catalysts | Ketones | Chemical tests and reagents | Hydrogen | Pharmacy | Drugstores | Palladium | Solvents | Methyl alcohol | Activation | Formations | Activation analysis | Alcohols
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