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Chemistry – A European Journal, ISSN 0947-6539, 08/2018, Volume 24, Issue 46, pp. 11806 - 11806
Metallocenes can catalyze the polymerization reaction of olefins. Prior to reaction, they require activation on the surface of solid activator particles. The... 
polymerization | acidity | spectroscopy | heterogeneity | methylaluminoxane
Journal Article
Polymer chemistry, ISSN 1759-9954, 2016, Volume 7, Issue 6, pp. 1239 - 1243
The first example of the synthesis of stereodiblock polyisoprene which consists ofcis-1,4 andtrans-1,4 sequences was achieved by using a neodymium catalyst.... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 48, pp. 17291 - 17298
Methylalumoxane (MAO) ionizes highly selectively in the presence of octamethyltrisiloxane (OMTS) to generate [Me Al·OMTS] [(MeAlO) (Me Al) Me] . We can take... 
Journal Article
Journal of Catalysis, ISSN 0021-9517, 08/2014, Volume 317, Issue August, pp. 153 - 157
[Display omitted] •Study activation of an iron-bis(imino)pyridine ethylene oligomerization catalyst.•Investigation of 3 aluminum-based activators.•Plausible... 
Catalyst activation | Oligomerization | DFT | Cocatalyst | Methylaluminoxane | Homogeneous catalysis | Molecular modeling | Ethylene | Mechanism | ALPHA-OLEFINS | AB-INITIO | COMPLEXES | OLEFIN POLYMERIZATION | CHEMISTRY, PHYSICAL | ZIEGLER CATALYSTS | ENGINEERING, CHEMICAL | POLYMERIZATION CATALYSTS | LIGANDS | BEHAVIORS | COBALT | Oligomers | Pyridine | Catalysis | Chemical Sciences
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 10/2016, Volume 45, Issue 39, pp. 15552 - 15556
Electron ionization (EI) is a reliable mass spectrometric method for the analysis of the vast majority of thermally stable and volatile compounds. In direct... 
Journal Article
Macromolecules, ISSN 0024-9297, 11/2017, Volume 50, Issue 21, pp. 8464 - 8468
Neodymium based Ziegler–Natta systems catalyze the 1,4-cis selective copolymerization of isoprene and 1,3-butadiene with different R2N- and RS-functionalized... 
POLYMERS | POLAR | POLYMER SCIENCE | FREE-RADICAL POLYMERIZATION | DIENE-BASED MATERIALS | STYRENE | METHYLALUMINOXANE
Journal Article
Macromolecules, ISSN 0024-9297, 05/2014, Volume 47, Issue 10, pp. 3317 - 3324
A series of asymmetric post-metallocene group 4 complexes based on a modular anilide(pyridine)phenoxide framework have been synthesized and tested for... 
POLYMERS | PRECATALYSTS | POLYMER SCIENCE | METHYLALUMINOXANE CATALYSTS | ZIRCONIUM | OLEFIN POLYMERIZATION | PROPYLENE POLYMERIZATION | PROPENE POLYMERIZATION | LIGAND
Journal Article
Analytical Chemistry, ISSN 0003-2700, 08/2015, Volume 87, Issue 16, pp. 8057 - 8062
Ambient ionization mass spectrometry is achieved in a simple manner by loading a sample solution onto a corner of a microscope cover glass positioned in front... 
ALUMINUM | CHEMISTRY, ANALYTICAL | MECHANISM | MASS-SPECTROMETRIC CHARACTERIZATION | COMPLEXES | PAPER SPRAY | CHAIN TRANSFER | CATALYSTS | METHYLALUMINOXANE | Usage | Ionization | Ethylene | Polymerization | Research | Chemical properties | Catalysis | Mass spectrometry
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2012, Volume 2, Issue 3, pp. 433 - 440
A series of pyridine-amine nickel complexes with various substituents were synthesized and used to evaluate substituent effects of catalyst precursors on the... 
pyridine-amine | nickel complex | ethylene | living polymerization | COMPLEXES/METHYLALUMINOXANE | COMPLEXES | CHEMISTRY, PHYSICAL | IRON | BETA-DIKETIMINATO NI(II) | NORBORNENE | LIGANDS | IMINE | OLIGOMERIZATION | COPOLYMERIZATION
Journal Article
Organometallics, ISSN 0276-7333, 03/2014, Volume 33, Issue 6, pp. 1431 - 1439
The catalyst systems (FI)TiCl3/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH3 donor) display exceptionally high activity in selective ethylene... 
OLEFIN-POLYMERIZATION | ACTIVATION | OXIDATION-STATES | CHEMISTRY, ORGANIC | ETHENE TRIMERIZATION | COORDINATION | STYRENE | MAO | OLIGOMERIZATION | CATALYSTS | METHYLALUMINOXANE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2013, Volume 3, Issue 11, pp. 2582 - 2585
Variable temperature spectroscopic, kinetic, and chemical studies were performed on a soluble CrIIICl3(PNP) (PNP = bis(diarylphosphino)alkylamine) ethylene... 
chromium | active species | ethylene trimerization | intermediates | metallacycle | methylaluminoxane | MECHANISTIC INVESTIGATIONS | TETRAMERIZATION | EPR | COMPLEXES | OLEFIN POLYMERIZATION | CHEMISTRY, PHYSICAL | METAL OXIDATION-STATE | ORTHO-METHOXYARYL | BRIDGED DIPHOSPHINE LIGAND | OLIGOMERIZATION | CHROMIUM CATALYSTS
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 08/2004, Volume 42, Issue 16, pp. 3911 - 3921
Journal Article
Catalysis Today, ISSN 0920-5861, 08/2019, Volume 334, pp. 223 - 230
[Display omitted] •Metallocene polymerization catalysts are activated by methylaluminoxane (MAO) as co-catalyst.•AlMe2+ species inherent to the MAO are... 
Olefin polymerization | Activation | Metallocenes | Methylaluminoxane | UV–vis DR spectroscopy | TD-DFT | Chemistry(all) | Catalysis | MECHANISM | MASS-SPECTROMETRIC CHARACTERIZATION | COMPLEXES | CHEMISTRY, PHYSICAL | CHROMIUM | ETHYLENE POLYMERIZATION | ENGINEERING, CHEMICAL | ZIRCONOCENE CATALYSTS | UV-vis DR spectroscopy | CHEMISTRY | MAO | CHEMISTRY, APPLIED | Polymerization | Catalysts | Silica | Olefins
Journal Article
Macromolecules, ISSN 0024-9297, 05/2011, Volume 44, Issue 9, pp. 3293 - 3301
Nickel complexes [(X,O)NiR(PPh3)] (X = N or P), designed for the polymerization of ethylene, were found to be efficient for the homo- and copolymerization of... 
POLYMER SCIENCE | POLYMERIZATION CATALYSTS | METHYL-METHACRYLATE | PALLADIUM COMPLEXES | MECHANISTIC INSIGHTS | POLAR VINYL MONOMERS | HOMOPOLYMERIZATION | RADICAL COPOLYMERIZATION | OLIGOMERIZATION | ACRYLATES | METHYLALUMINOXANE | Polymers | Chemical Sciences | Catalysis
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 12/2015, Volume 44, Issue 47, pp. 20745 - 20752
A series of iron complexes bearing a bis(imino)pyridine ligand were synthesised and examined as precatalysts for homopolymerisation of propylene. The alkyl... 
Journal Article
Macromolecules, ISSN 0024-9297, 09/2018, Volume 51, Issue 18, pp. 7061 - 7076
Solution copolymerizations of ethylene and 1-hexene were performed using the dichloride (HfCl2) and dimethyl (HfMe2) analogues of the... 
METHYLALUMOXANE | POLYMER SCIENCE | TRIS(PENTAFLUOROPHENYL)BORANE | HOMOGENEOUS OLEFIN POLYMERIZATION | METALLOCENE CATALYSTS | KINETICS | COMPLEXES | COCATALYSTS | MAO | ETHYLENE POLYMERIZATION | METHYLALUMINOXANE
Journal Article
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