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Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 48, pp. 14232 - 14242
Transition‐metal‐catalyzed radical reactions are becoming increasingly important in modern organic chemistry. They offer fascinating and unconventional ways... 
radical reactions | homogeneous catalysis | Michael acceptors | conjugate addition | umpolung | 4-EXO CYCLIZATIONS | O-STANNYL KETYLS | HYDROGEN-ATOM TRANSFER | ALPHA-AMINO RADICALS | CYCLIZATION REACTIONS | COUPLING REACTIONS | ARYL HALIDES | LIGHT PHOTOREDOX CATALYSIS | ELECTRON-DEFICIENT ALKENES | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2011, Volume 50, Issue 36, pp. 8412 - 8415
leahciM! The N‐heterocyclic carbene catalyzed umpolung of Michael acceptors proceeds through the formation of a deoxy‐Breslow intermediate (see scheme;... 
organocatalysis | carbenes | Michael acceptors | nitrogen heterocycles | umpolung | STABLE CARBENE | 1,3,4-TRIPHENYL-4,5-DIHYDRO-1H-1,2,4-TRIAZOL-5-YLIDENE | NHC | DIMERIZATION | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-BUTYROLACTONES | ENALS | CONJUGATE UMPOLUNG | DIRECT ANNULATIONS | HYDROACYLATION
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 12/2018, Volume 360, Issue 23, pp. 4459 - 4463
The alkene cyclopropanation with chloromethyl silicate as a methylene transfer reagent has been accomplished via visible-light-mediated redox-neutral... 
Cyclopropanation | Photoredox catalysis | 1-Arylcyclopropylphosphonate | Michael acceptor | Radical | STYRENES | CHEMISTRY, ORGANIC | GENERATION | RADICALS | CHEMISTRY, APPLIED | DIMETHYLSULFONIUM METHYLIDE | METAL-COMPLEXES | Substitutes | Catalysis | Substrates | Functional groups | Reagents | Methylene
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2018, Volume 8, Issue 7, pp. 5947 - 5951
The gold­(I)-catalyzed, stereoselective hydrofluorination of electron-deficient alkynes with triethylamine trihydrogen fluoride (Et3N·3HF) is described.... 
michael acceptors | gold catalysis | hydrofluorination | monofluoroalkenes | fluorine | FLUOROALKENES | ENTRY | CHEMISTRY, PHYSICAL | ALDEHYDES | FLUORINATION | SALTS | MEDICINAL CHEMISTRY | CONSTRUCTION | ACRYLATES
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2011, Volume 47, Issue 28, pp. 7917 - 7932
The direct enantioselective 1,4-addition of water to alpha,beta-unsaturated acceptors is an open challenge in asymmetric catalysis. Enantioselective conjugate... 
OXY-MICHAEL ADDITION | ENOYL-COA HYDRATASE | NOREPHEDRINE-DERIVED OXAZOLIDINES | STEREOSELECTIVE ROUTE | CARBONYL-COMPOUNDS | BETA-UNSATURATED ESTERS | N-HETEROCYCLIC CARBENES | SI-B LINKAGE | CHEMISTRY, MULTIDISCIPLINARY | BASE-CATALYZED HYDRATION | ELECTRON-DEFICIENT OLEFINS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2013, Volume 135, Issue 21, pp. 7851 - 7854
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4732 - 4736
A site‐divergent stereoselective Michael reaction system is developed based on the identification of two distinct catalysts. Cinchonidine‐derived thiourea... 
carbohydrates | Michael addition | organocatalysis | alkynes |