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mn-iii catalyst (11) 11
alpha,beta-unsaturated ketones (9) 9
chemistry, organic (8) 8
manganese (7) 7
mn catalyst (6) 6
phenylsilane (6) 6
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oxidation (5) 5
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oxidation-reduction hydration (3) 3
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allyl 2-iodophenyl ether (2) 2
c-h activation (2) 2
catalysts (2) 2
chemical synthesis (2) 2
chemistry (2) 2
chemistry, inorganic & nuclear (2) 2
esters (2) 2
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mn (2) 2
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-kopsidasine-n-oxide (1) 1
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abamectin (1) 1
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Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 4153 - 4156
A diastereoselective approach for the synthesis of the hydroperoxide–keto form of (±)-steenkrotin B (2′) is described. The key features of the strategy involve... 
PHENYLSILANE | SINGLET MOLECULAR-OXYGEN | ALPHA,BETA-UNSATURATED KETONES | MN-III CATALYST | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | OLEFINS | COBALT(II) PORPHYRIN | MN(DPM) CATALYST | OXIDATION-REDUCTION HYDRATION | UNACTIVATED ALKENES
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2018, Volume 74, Issue 26, pp. 3358 - 3369
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2004, Volume 43, Issue 31, pp. 4099 - 4102
Enhanced activity, lower catalyst loading, shorter reaction times, and expanded substrate scope are the advantages of [Mn(dpm)3] over Co catalysts in the... 
silanes | hydrazination | homogeneous catalysis | alkenes | manganese | Silanes | Hydrazination | Alkenes | Homogeneous catalysis | Manganese | III CATALYST | ASYMMETRIC-SYNTHESIS | ALPHA,BETA-UNSATURATED KETONES | AMINO | STEREOSELECTIVE AMINATION | ALPHA-HYDRAZINO ACIDS | MN(DPM) CATALYST | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE AMINATION | PHENYLSILANE | MOLECULAR-OXYGEN
Journal Article
Tetrahedron, ISSN 0040-4020, 2002, Volume 58, Issue 17, pp. 3423 - 3443
Pictet–Spengler condensation of 13 with tryptamine gave 14 , which was converted into 17 . Treatment of 17 with phenyl chloroformate resulted in 18 , which... 
tryptamine | pauciflorine B | Kopsia alkaloids | Tryptamine | Pauciflorine B | PHENYLSILANE | DIOXYGEN | ALPHA,BETA-UNSATURATED KETONES | REDUCTION | VINBLASTINE DERIVATIVES | MN-III CATALYST | CHEMISTRY, ORGANIC | MN(DPM) CATALYST | HEPTACYCLIC INDOLE ALKALOIDS | RING-SYSTEM | PAUCIFLORINE-A
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 06/2001, Volume 42, Issue 25, pp. 4127 - 4129
Treatment of alpha,beta -unsaturated nitriles with Mn(dpm)(3) (3 mol%), PhSiH3 in isopropyl alcohol in the presence of oxygen resulted in reduction and alpha-... 
KETONES | MN-III CATALYST | oxidation | CHEMISTRY, ORGANIC | cyanohydrin | OXIDATIVE DECYANATION | reduction | manganese | phenylsilane
Journal Article
Israel Journal of Chemistry, ISSN 0021-2148, 2001, Volume 41, Issue 4, pp. 231 - 240
A new copper(II) fluoride-chiral diphosphines catalytic system was developed. This one is very efficient and selective for the hydrosilylation of several... 
ASYMMETRIC HYDROSILYLATION | ALPHA,BETA-UNSATURATED KETONES | CONJUGATE REDUCTION | COMPLEXES | ESTERS | MN(DPM) CATALYST | ALDEHYDES | BITE ANGLE | TITANIUM | CHEMISTRY, MULTIDISCIPLINARY | POLYMETHYLHYDROSILOXANE
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 09/2001, Volume 42, Issue 38, pp. 6633 - 6636
Saturated ketones and aldehydes are reduced to alcohols by phenylsilane and Mn(dpm)(3)(cat) in the presence of dioxygen. (C) 2001 Elsevier Science Ltd. All... 
ACID | dioxygen | ALPHA,BETA-UNSATURATED KETONES | tris(dipivaloylmethanato)manganese(III) | MN-III CATALYST | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | hydridic
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 07/2019, Volume 55, Issue 53, pp. 7699 - 7702
Two cis-beta-Mn(III)SALPN catalysts were synthesised and tested in the Mukaiyama-Isayama hydration of alpha,beta-unsaturated esters. The Mn(III)EtOSALPN(acac)... 
PHENYLSILANE | KETONES | REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | MN-III CATALYST | MOLECULAR-OXYGEN
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 02/2016, Volume 308, pp. 191 - 235
Journal Article
Journal of Catalysis, ISSN 0021-9517, 2007, Volume 252, Issue 1, pp. 110 - 118
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 13, pp. 1706 - 1709
New avermectin derivatives were prepared by Mn(III)-catalysed hydration reaction of different substrates. The Mn(dpm) 3-catalysed olefin hydration reaction of... 
Abamectin | Acaricide | Insecticide | Hydration | Natural product | Emamectin | Avermectin | Mn(III) | DIOXYGEN | ALPHA,BETA-UNSATURATED KETONES | CONVERSION | CHEMISTRY, ORGANIC | (+/-)-KOPSIDASINE-N-OXIDE | PHENYLSILANE | REDUCTION | MN-III CATALYST | ESTERS | MOLECULAR-OXYGEN
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2016, Volume 2016, Issue 23, pp. 3912 - 3929
Manganese is a non‐toxic, inexpensive and earth abundant metal, so is a perfect candidate for catalysis whether as a replacement for precious metals or in the... 
C–H activation | Fluorination | Homogeneous catalysis | Manganese | OXIDATION | CROSS-COUPLING REACTION | ALPHA,BETA-UNSATURATED KETONES | 1,3-DICARBONYL COMPOUNDS | HYDROSILYLATION | CHEMISTRY, ORGANIC | HIGHLY EFFICIENT | CARBONYL-COMPLEXES | C-H activation | MN-III CATALYST | C-H HYDROXYLATION | GRIGNARD-REAGENTS | Chemical synthesis | Catalysis
Journal Article
Russian Journal of Organic Chemistry, ISSN 1070-4280, 3/2012, Volume 48, Issue 3, pp. 309 - 348
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 71, pp. 17954 - 17963
Molecular engineering of manganese(II) diamine diketonate precursors is a key issue for their use in the vapor deposition of manganese oxide materials. Herein,... 
nanomaterials | Mn β-diketonates | chemical vapor deposition | manganese oxides | single-crystal X-ray diffraction | Oxides | Chemical vapor deposition | Usage | Fluorine | Vapors | Atomic layer epitaxy | Fabrication | Engineering | Manganese oxides | Precursors | Ligands | Coordination compounds | Atomic structure | Thermodynamic properties | Deposition | Adducts | Manganese
Journal Article