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monoarylation (52) 52
chemistry, organic (41) 41
palladium (29) 29
aryl chlorides (23) 23
ligands (21) 21
catalysis (20) 20
arylation (19) 19
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amination (18) 18
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selective monoarylation (11) 11
activation (10) 10
ammonia (10) 10
chlorides (10) 10
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ketones (10) 10
chemistry, inorganic & nuclear (9) 9
functionalization (9) 9
aromatic compounds (8) 8
c-h activation (8) 8
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esters (8) 8
index medicus (8) 8
reductive elimination (8) 8
suzuki-miyaura (8) 8
arylierung (7) 7
c-n (7) 7
chemistry, applied (6) 6
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efficient (6) 6
molecular structure (6) 6
palladium-catalyzed amination (6) 6
chemistry, physical (5) 5
cross‐coupling (5) 5
inhibitors (5) 5
nitriles (5) 5
palladium - chemistry (5) 5
ruthenium (5) 5
sequential monoarylation/amidation (5) 5
stereoselective-synthesis (5) 5
synthesis (5) 5
water (5) 5
acids (4) 4
addressing challenges (4) 4
amides (4) 4
anilines (4) 4
article (4) 4
aryl bromides (4) 4
base (4) 4
couplings (4) 4
direct arylation (4) 4
heteroaryl chlorides (4) 4
homogeneous catalysis (4) 4
joining (4) 4
palladium catalysts (4) 4
phosphines (4) 4
precatalysts (4) 4
pyridine (4) 4
room-temperature (4) 4
substrates (4) 4
synthetic methods (4) 4
aldehydes (3) 3
alkylation (3) 3
alpha-arylation (3) 3
amination reactions (3) 3
amino-beta-lactams (3) 3
analysis (3) 3
arenes (3) 3
aryl (3) 3
arylations (3) 3
asymmetric arylation (3) 3
buchwald-hartwig amination (3) 3
c-h bonds (3) 3
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enantioselective synthesis (3) 3
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letter (3) 3
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nickel (3) 3
phosphine-ligands (3) 3
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unactivated c-h bonds (3) 3
acetates (2) 2
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Tetrahedron, ISSN 0040-4020, 08/2014, Volume 70, Issue 32, pp. 4754 - 4759
A readily accessible catalytic system, PdCl (Ph P) /Ph P, was developed for the selective arylation of primary anilines with aryl bromides. The strong... 
Diarylation | Amination | Monoarylation | Palladium | Triphenylphosphine
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2014, Volume 70, Issue 32, pp. 4754 - 4759
A readily accessible catalytic system, PdCl (Ph P) /Ph P, was developed for the selective arylation of primary anilines with aryl bromides. The strong... 
Diarylation | Palladium | Amination | Triphenylphosphine | Monoarylation
Journal Article
Organic Letters, ISSN 1523-7060, 03/2017, Volume 19, Issue 6, pp. 1434 - 1437
A general Pd-catalyzed Suzuki–Miyaura cross-coupling of N-mesylamides with arylboronic acids by selective N–C cleavage has been developed. The presented... 
FUNCTIONALIZATION | ACYLSACCHARINS | ACTIVATION | KETONE SYNTHESIS | MONOARYLATION | ARYL MESYLATES | NICKEL CATALYSIS | NITROGEN BOND-CLEAVAGE | TWISTED AMIDES | ESTERS | CHEMISTRY, ORGANIC
Journal Article
Nature Communications, ISSN 2041-1723, 03/2016, Volume 7, Issue 1, p. 11073
Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical... 
HALIDES | CROSS-COUPLING REACTIONS | AMINATION | AMMONIA | MONOARYLATION | C-N | MULTIDISCIPLINARY SCIENCES | MEDICINAL CHEMISTS | BROMIDES | ARYL CHLORIDES | PRECATALYST
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 05/2019, Volume 84, Issue 10, pp. 6337 - 6346
This paper presents the first general examples of selective palladium-catalyzed mono-alpha-arylation of aryl and heteroaryl ketones with aryl phosphates. The... 
MONOARYLATION | C-N | ACIDS | COMPLEXES | MESYLATES | ACETONE | CHEMISTRY, ORGANIC | ASYMMETRIC ARYLATION | LIGAND | REDUCTIVE ELIMINATION | EFFICIENT
Journal Article
Organometallics, ISSN 0276-7333, 09/2018, Volume 37, Issue 18, pp. 2941 - 2944
Recent developments in the chemistry of C–N bond formation and the synthesis of anilines have allowed for the use of first-row transition metals to catalyze... 
HETEROARYL CHLORIDES | AMMONIA | MONOARYLATION | AMINES | ARYL HALIDES | ARYLATION | CATALYZED AMINATION | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 02/2019, Volume 17, Issue 7, pp. 1791 - 1795
A simple protocol for copper-catalyzed arene amination using aqueous ammonia without any additional ligands and organic coordinating solvents has been... 
SYSTEM | MONOARYLATION | ANILINES | WELL | ARYL HALIDES | TRANSITION-METAL | ARYLATION | CHLORIDES | CHEMISTRY, ORGANIC | BROMIDES | SELECTIVITIES
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2018, Volume 54, Issue 11, pp. 1303 - 1306
Organosulfides are a common class of structure units in bioactive molecules and functional materials motivating continuous developments of efficient synthetic... 
Journal Article
Organometallics, ISSN 0276-7333, 01/2019, Volume 38, Issue 1, pp. 167 - 175
We report herein on the synthesis of new heteroaryl analogues of PAd-DalPhos and related bis(di(o-tolyl)phosphino) ancillary ligand variants based on pyridine... 
AMINATION | PRECATALYSTS | MONOARYLATION | BISPHOSPHINES | TRANSITION-METAL | PRIMARY ALKYLAMINES | COMPLEXES | CHEMISTRY, ORGANIC | N-ARYLATION | BROMIDES | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 2018, Volume 84, Issue 8, pp. 4670 - 4679
alpha-Arylations of cyclopropyl and related nitriles provide access to important synthetic intermediates and pharmacophores for biologically active molecules.... 
HIGH-THROUGHPUT EXPERIMENTATION | PRECATALYSTS | ARYL HALIDES | ESTERS | ACETONE | CHEMISTRY, ORGANIC | COUPLINGS | LIGAND | SMALL RING | DERIVATIVES | SELECTIVE MONOARYLATION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 05/2019, Volume 84, Issue 10, pp. 6366 - 6376
The first general palladium-catalyzed amination of aryl phosphates is described. The combination of MorDalPhos with [Pd(pi-cinnamyl)Cl](2) enables the... 
ROOM-TEMPERATURE | MONOARYLATION | C-N | AMINES | ARYLATION | CHEMISTRY, ORGANIC | BUCHWALD-HARTWIG AMINATION | AROMATIC AMINATION | EFFICIENT | ARYL CHLORIDES | REDUCTIVE AMINATION
Journal Article
Organometallics, ISSN 0276-7333, 01/2017, Volume 36, Issue 2, pp. 251 - 254
Herein we report the first example of (hetero)­arylation of ammonia using a monoligated palladium-NHC complex. The new, rationally designed, precatalyst... 
ARYLATIONS | MONOARYLATION | LIGANDS | AMINES | ROOM-TEMPERATURE AMINATION | CHEMISTRY, ORGANIC | BROMIDES | ARYL CHLORIDES | PALLADIUM-CATALYZED AMINATION | BASE | EQUIVALENT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 33, pp. 6896 - 6900
Here, we report a ligand- and reductant-free nickel-catalyzed N-vinylation of heteroaromatic amines using biorenewable p-cymene as a solvent. This... 
MONOARYLATION | LIGANDS | PHOTOREDOX | ANILINES | ALKYLATION | PYRIMIDINE | CHEMISTRY, ORGANIC | AMINATION REACTIONS | CLEAVAGE | ARYL CHLORIDES | INDOLES
Journal Article
Organometallics, ISSN 0276-7333, 11/2018, Volume 37, Issue 21, pp. 4015 - 4023
We report herein on the results of our combined experimental/computational study regarding the catalytic performance of PAd-DalPhos (L1) in nickel-catalyzed... 
AMINATION | ARYLATIONS | MONOARYLATION | BISPHOSPHINES | PRIMARY ALKYLAMINES | CHEMISTRY, ORGANIC | AMINE | REDUCTIVE ELIMINATION | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 11, pp. 1303 - 1306
Organosulfides are a common class of structure units in bioactive molecules and functional materials motivating continuous developments of efficient synthetic... 
STEVENS REARRANGEMENT | FACILE N-ARYLATION | TRIARYLSULFONIUM SALTS | INSERTION | MONOARYLATION | AMINES | EMPLOYING ARYNES | RATE CONSTANTS | CARBON-ATOM | NUCLEOPHILICITY | CHEMISTRY, MULTIDISCIPLINARY | Molecular structure | Nucleophiles | Ring opening | Continuity (mathematics)
Journal Article
by Shi, P and Wang, J and Gan, ZX and Zhang, JY and Zeng, RS and Zhao, YS
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 71, pp. 10523 - 10526
Functionalized beta-lactams are highly important motifs in synthetic chemistry. We report an efficient and novel approach to the synthesis of beta-lactams via... 
UNACTIVATED C(SP)-H BONDS | SEQUENTIAL MONOARYLATION/AMIDATION | ACTIVATION | INTRAMOLECULAR AMINATION | ARYLATION | GAMMA-LACTAMS | AMIDATION | CARBOXAMIDES | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 04/2011, Volume 13, Issue 7, pp. 1690 - 1693
Using TMPZnCl center dot"LiCl as a kinetically highly active base, nitriles and esters undergo a Pd-catalyzed alpha-arylation under mild conditions.... 
ARYL BROMIDES | PALLADIUM | METALATION | ZINC AMIDE | DIRECTED ZINCATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | FUNCTIONALIZED ARENES | SELECTIVE MONOARYLATION | GENERAL-METHOD | BASE
Journal Article
Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 19, pp. 6198 - 6201
A selective O-cyclization of N-methoxy aryl amides with CH2Br2 or 1,2-DCE (1,2-dichloroethane) via palladium-catalyzed C–H activation has been described. New... 
FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | SEQUENTIAL MONOARYLATION/AMIDATION | ACIDS | ARYLATION | CHEMISTRY, ORGANIC | AMINO-BETA-LACTAMS | CARBON-HYDROGEN BONDS | STEREOSELECTIVE-SYNTHESIS | ALKYL IODIDES
Journal Article
Organometallics, ISSN 0276-7333, 01/2019, Volume 38, Issue 1, pp. 66 - 75
This perspective describes the formation of strategic partnerships between our academic laboratory and researchers at three major chemical organizations (the... 
LIGANDS | AMMONIA | COMPLEXES | CATALYZED AMINATION | CHEMISTRY, ORGANIC | PD-PEPPSI-IPENT(CL) | REDUCTIVE ELIMINATION | BROMIDES | ARYL CHLORIDES | PALLADIUM CATALYSTS | SELECTIVE MONOARYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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