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1. Full Text Dual Photoredox/Copper Catalysis for the Remote C(sp3)−H Functionalization of Alcohols and Alkyl Halides by N‐Alkoxypyridinium Salts
by Bao, Xu and Wang, Qian and Zhu, Jieping
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 7, pp. 2139 - 2143
Under mild dual photoredox/copper catalysis, the reaction of N‐alkoxypyridinium salts with readily available silyl reagents (TMSN3, TMSCN, TMSNCS) afforded... 
alkoxy radical | C−H activation | dual catalysis | photoredox catalyst | 1,5-HAT | 5-HAT | DECOMPOSITION | HYDROGEN-ATOM | COPPER | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | C-H activation | BONDS | ALKOXYL RADICALS | GENERATION | RELAY CYCLIZATIONS | METAL-FREE | CHLORINATION | Salts | Halides | Reagents | Alcohol | Catalysis | Copper | Enantiomers | Alcohols
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2. Full Text Nickel‐Catalyzed Thiolation of Aryl Halides and Heteroaryl Halides through Electrochemistry
by Liu, Dong and Ma, Hong‐Xing and Fang, Ping and Mei, Tian‐Sheng
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5033 - 5037
Transition‐metal‐catalyzed coupling reactions are useful tools for synthesizing aryl sulfur compounds. However, conventional transition‐metal‐catalyzed... 
nickel | electrosynthesis | electrocatalysis | thiyl radicals | thiolation | C-H THIOLATION | CARBON | FORMING REDUCTIVE ELIMINATION | DIARYL SULFIDES | CHEMISTRY, MULTIDISCIPLINARY | PAIRED ELECTROLYSIS | THIOLS | CROSS-COUPLING REACTIONS | S BOND FORMATION | TRANSITION-METAL | ORGANIC ELECTROSYNTHESIS | Sulfur compounds | Electrochemical reactions | Dichloropropane | Chlorides | Electrochemistry | Nickel | Batteries | Temperature requirements | Temperature | Metals | Chemical reactions | Coupling (molecular) | Halides | Aromatic compounds | Bromides | Chemical synthesis | Sulfur | Electrochemical cells
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3. Full Text Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides
by Biswas, Soumik and Weix, Daniel J
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 43, pp. 16192 - 16197
The direct cross-coupling of two different electrophiles, such as an aryl halide with an alkyl halide, offers many advantages over conventional cross-coupling... 
CARBON BOND FORMATION | DIRECT ARYLATION | AROMATIC HALIDES | KETONE FORMATION | COMPLEXES | RADICAL CATALYSIS | REDUCTIVE CONJUGATE ADDITION | ORGANIC HALIDES | FUNCTIONALIZED GRIGNARD-REAGENTS | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | Hydrocarbons - chemistry | Free Radicals | Nickel - chemistry | Oxidation-Reduction | Halogens - chemistry | Catalysis | Hydrocarbons, Cyclic - chemistry | Nickel | Chemical properties | Research | Halides | Metal catalysts
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4. Full Text An Above‐Room‐Temperature Ferroelectric Organo–Metal Halide Perovskite: (3‐Pyrrolinium)(CdCl3)
by Ye, Heng‐Yun and Zhang, Yi and Fu, Da‐Wei and Xiong, Ren‐Gen
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 42, pp. 11242 - 11247
Hybrid organo–metal halide perovskite materials, such as CH3NH3PbI3, have been shown to be some of the most competitive candidates for absorber materials in... 
perovskites | ferroelectrics | domains | phase transitions | polarization switching | Domains | Perovskites | Ferroelectrics | Polarization switching | Phase transitions | HIGH-PERFORMANCE | SOLAR-CELLS | LIGHT | LENGTHS | SALTS | CHEMISTRY, MULTIDISCIPLINARY | CONDUCTIVITY | POLARIZATION | Perovskite | Solar cells | Electric potential | Ferroelectricity | Photovoltaic effect | Ferroelectric materials | Photovoltaic cells | Stacking | Halides
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5. Full Text From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives
by Xiao, Zewen and Song, Zhaoning and Yan, Yanfa
Advanced Materials, ISSN 0935-9648, 11/2019, Volume 31, Issue 47, pp. e1803792 - n/a
Despite the exciting progress on power conversion efficiencies, the commercialization of the emerging lead (Pb) halide perovskite solar cell technology still... 
lead‐free | optoelectronic properties | halide perovskites | solar cells | double perovskites | lead-free | THIN-FILMS | PHYSICS, CONDENSED MATTER | LIFE-CYCLE ASSESSMENT | PHYSICS, APPLIED | SOLAR-CELLS | CHARGE-CARRIERS | MATERIALS SCIENCE, MULTIDISCIPLINARY | OPTICAL-PROPERTIES | INTRINSIC DEFECTS | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | EFFECTIVE MASSES | PHOTOVOLTAIC PERFORMANCE | IODIDE PEROVSKITE | DENSITY-FUNCTIONAL THEORY | Solar cells | Photovoltaic cells | Optical properties | Energy conversion | Lead | Metal halides | Perovskites | Lead compounds | Derivatives | Commercialization | Index Medicus
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6. Full Text Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp3-carbons with aryl halides
by Zhiwei Zuo and Derek T. Ahneman and Lingling Chu and Jack A. Terrett and Abigail G. Doyle and David W. C. MacMillan
Science, ISSN 0036-8075, 7/2014, Volume 345, Issue 6195, pp. 437 - 440
Over the past 40 years, transition metal catalysis has enabled bond formation between aryl and olefinic (sp2) carbons in a selective and predictable manner... 
Transition metals | Metal bonding | Halides | Extrasolar planet detection | REPORTS | Corporate mergers | Amino acids | Oxidation | Catalysis | Carbon | Inner planets | Cross coupling | Catalysts | Reagents | Chemical bonds | Nickel | Coupling
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7. Full Text Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond
by Kubota, Koji and Yamamoto, Eiji and Ito, Hajime
Journal of the American Chemical Society, ISSN 0002-7863, 02/2013, Volume 135, Issue 7, pp. 2635 - 2640
A borylative exo-cyclization of alkenyl halides has been reported. The reaction includes the regioselective addition of a borylcopper(I) intermediate to... 
CROSS-COUPLING REACTIONS | BORATION | ESTERS | COMPLEXES | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS | ARYL | COPPER-CATALYZED BORYLATION | DIBORATION | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Thermal properties | Metal bonding | Analysis | Copper compounds | Catalysis | Chemical properties | Ring formation (Chemistry)
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8. Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides
by Vargini Thangavadivale and Pedro M Aguiar and Naseralla A Jasim and Sarah J Pike and Dan A Smith and Adrian C Whitwood and Lee Brammer and Robin N Perutz
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 15, pp. 3767 - 3781
The syntheses of three series of complexes designed with self-complementary motifs for formation of halogen bonds between an iodotetrafluorophenyl ligand and a... 
Angles (geometry) | Temperature dependence | Nuclear magnetic resonance--NMR | Bond strength | Chains | Fluorides | Charge distribution | Solid state | Reduction | Halides | Benzene | Bonding strength | Chemical bonds | Ligands | Nickel | Crystal structure | Iodine
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9. Full Text Pyridine-Catalyzed Radical Borylation of Aryl Halides
by Zhang, Li and Jiao, Lei
Journal of the American Chemical Society, ISSN 0002-7863, 01/2017, Volume 139, Issue 2, pp. 607 - 610
A pyridine-catalyzed transition-metal-free borylation reaction of haloarenes has been developed based on the selective cross-coupling of an aryl radical and a... 
METAL-FREE BORYLATION | H BOND ACTIVATION | ROOM-TEMPERATURE | HETEROCYCLIC CARBENE BORANES | LEWIS-BASES | ARYLATION | REACTIVITY | GENERATION | ALKOXY DIBORON REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-TRANSFER REACTIONS | Usage | Pyridine | Aromatic amines | Chemical properties | Chemical synthesis
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10. Full Text Optimized opto-electronic and mechanical properties of orthorhombic methylamunium lead halides (MAPbX3) (X = I, Br and Cl) for photovoltaic applications
by Laamari, Mohammed Elmamoun and Cheknane, Ali and Benghia, Ali and Hilal, Hikmat S
Solar Energy, ISSN 0038-092X, 04/2019, Volume 182, pp. 9 - 15
•The intrinsic properties of MAPbX3 (X = I, Br and Cl) are described.•The optimized orthorhombic structures based on the ab-initio DFT calculation.•The... 
Perovskites | Stiffness | DFT | Band gap tuning | Optical absorption | PHASE | ENERGY & FUELS | Density functionals | Perovskite | Solar energy industry | Optoelectronics industry | Anisotropy | Halides | Solar cells | Dielectric constant | Optoelectronics | Refractivity | Mechanical properties | Solar power | Absorptivity | Metal halides | Energy gap | Absorption | Photovoltaic cells | Energy | Mathematical analysis | Optical properties | Lead | Visible spectrum | Density functional theory | Elastic properties | Photovoltaics | Energy conversion efficiency
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11. Full Text Palladium-Catalyzed C(sp(3)) C(sp(2)) Cross-Coupling of (Trimethylsilyl)methyllithium with (Hetero)Aryl Halides
by Heijnen, Dorus and Hornillos, Valentin and Corbet, Brian P and Giannerini, Massimo and Feringa, Ben L
Organic letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 9, pp. 2262 - 2265
The palladium-catalyzed direct cross-coupling of a range of organic chlorides and bromides with the bifunctional C(sp(3))-(trimethylsilyl)methyllithium reagent... 
CARBON BOND FORMATION | ORTHO-SUBSTITUTED BIARYLS | ORGANIC-SYNTHESIS | NOBEL-PRIZE | ALKENYL HALIDES | EFFICIENT SYNTHESIS | SELECTIVE SYNTHESIS | ORGANOLITHIUM COMPOUNDS | GRIGNARD-REAGENTS | ARYL CHLORIDES | ALKYL | ARYL DERIVATIVES | CHEMISTRY, ORGANIC | ORGANIC HALIDES | METAL | ALKENYL
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12. Full Text Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size, and Luminescence Properties of the Coordination Polymers
by Knorr, Michael and Khatyr, Abderrahim and Dini Aleo, Ahmed and El Yaagoubi, Anass and Strohmann, Carsten and Kubicki, Marek M and Rousselin, Yoann and Aly, Shawkat M and Fortin, Daniel and Lapprand, Antony and Harvey, Pierre D
Crystal Growth & Design, ISSN 1528-7483, 11/2014, Volume 14, Issue 11, pp. 5373 - 5387
Bis(phenylthio)methane (L1) reacts with CuI to yield the 1D-coordination polymer [{Cu4(μ3-I)4}(μ-L1)2] n (1) bearing cubane Cu4I4 clusters as connecting nodes.... 
CRYSTAL-STRUCTURE | MATERIALS SCIENCE, MULTIDISCIPLINARY | FLEXIBLE DITHIOETHER | STRUCTURAL-CHARACTERIZATION | M4X4 CORE | CRYSTALLOGRAPHY | CHEMISTRY, MULTIDISCIPLINARY | DITHIOETHER LIGANDS | LEWIS-BASE ADDUCTS | IODIDE CLUSTERS | METAL-ORGANIC FRAMEWORKS | SPECTROSCOPIC CHARACTERIZATION | SPACER LENGTH | Physics | Astrophysics
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13. Full Text Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: Fluoride ligands: Vs. other halides
by Thangavadivale, Vargini and Aguiar, Pedro M and Jasim, Naseralla A and Pike, Sarah J and Smith, Dan A and Whitwood, Adrian C and Brammer, Lee and Perutz, Robin N
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 15, pp. 3767 - 3781
The syntheses of three series of complexes designed with self-complementary motifs for formation of halogen bonds between an iodotetrafluorophenyl ligand and a... 
SINGLE-CRYSTAL | TRANSITION-METAL-COMPLEXES | INSERTION REACTIONS | MAGNETIC-RESONANCE | CRYSTAL-STRUCTURES | SUPRAMOLECULAR CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | CHEMICAL SHIELDING TENSORS | DOT-X'-C | INJECTION FIELD DESORPTION/IONIZATION | HYDROGEN-BONDS
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