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metal-ligand cooperation (255) 255
chemistry, inorganic & nuclear (109) 109
bond activation (88) 88
chemistry, multidisciplinary (81) 81
catalysis (73) 73
pincer complexes (73) 73
hydrogenation (70) 70
chemistry, organic (69) 69
alcohols (66) 66
ruthenium (64) 64
dehydrogenation (57) 57
chemistry, physical (55) 55
ligands (48) 48
amines (44) 44
aromatization-dearomatization (44) 44
activation (38) 38
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c-h (30) 30
hydrogen (30) 30
ruthenium complexes (30) 30
efficient hydrogenation (29) 29
esters (29) 29
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iron (26) 26
ketones (24) 24
complexes (22) 22
homogeneous catalysis (22) 22
nitriles (21) 21
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c-h activation (20) 20
iridium (20) 20
rhodium (20) 20
chemistry (19) 19
reduction (18) 18
h bond activation (17) 17
secondary alcohols (17) 17
selective hydrogenation (17) 17
manganese (16) 16
amides (15) 15
analysis (15) 15
electron-rich (15) 15
h-2 activation (15) 15
n-heterocyclic carbene (15) 15
transfer hydrogenation (15) 15
asymmetric hydrogenation (14) 14
density functionals (14) 14
hydrieren (14) 14
iridium complexes (14) 14
methanol (14) 14
oxidative addition (14) 14
borrowing hydrogen (13) 13
chemical properties (13) 13
dihydrogen (13) 13
formic-acid (13) 13
homogeneous hydrogenation (13) 13
index medicus (13) 13
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palladium (13) 13
ruthenium-complex (13) 13
rutheniumkomplex (13) 13
alcohol (12) 12
aldehydes (12) 12
ammonia (12) 12
acceptorless dehydrogenation (11) 11
metal–ligand cooperation (11) 11
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transition-metals (11) 11
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coordination compounds (10) 10
molecular-orbital methods (10) 10
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water (10) 10
alkylation (9) 9
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chemical synthesis (9) 9
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efficient (9) 9
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ACS Catalysis, ISSN 2155-5435, 08/2017, Volume 7, Issue 8, pp. 5483 - 5490
A facile ruthenium­(II)-catalyzed α-alkylation of arylmethyl nitriles using alcohols is reported. The ruthenium pincer catalyst serves as an efficient catalyst... 
borrowing hydrogen | ruthenium | alkylation | alcohols | nitriles | metal-ligand cooperation | METHANOL | CATALYZED REACTIONS | OLEFIN CROSS-METATHESIS | CHEMISTRY, PHYSICAL | DEHYDROGENATION | MILD CONDITIONS | ARYLACETONITRILES | IRIDIUM COMPLEX | EFFICIENT | C-H
Journal Article
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, ISSN 1364-503X, 03/2015, Volume 373, Issue 2037, p. 20140189
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2013, Volume 3, Issue 11, pp. 2522 - 2526
The metal–ligand cooperative activation of CO2 with pyridine-based ruthenium PNP pincer catalysts leads to pronounced inhibition of the activity in the... 
pincer catalyst | ruthenium | hydrogenation | metal-ligand cooperation | TRANSFORMATION | FORMIC-ACID | ACTIVATION | CONVERSION | DEFINED IRON CATALYST | COMPLEXES | CHEMISTRY, PHYSICAL | ALKYL FORMATES | REDUCTION | CO2 hydrogenation
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2018, Volume 8, Issue 9, pp. 8014 - 8019
Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction... 
amide | deoxygenative hydrogenation | amine | manganese pincer complex | metal-ligand cooperation | SUSTAINABLE SYNTHESIS | TERTIARY AMIDES | CHEMISTRY, PHYSICAL | N-METHYLATION | ALCOHOLS | MILD | KETONES | AMINES | NITRILES | ACCEPTORLESS DEHYDROGENATION | ESTERS | Letter | metal−ligand cooperation
Journal Article
by Liu, JG and Chen, JY and Jia, MJ and Ming, BR and Jia, J and Liao, RZ and Tung, CH and Wang, WG
ACS CATALYSIS, ISSN 2155-5435, 05/2019, Volume 9, Issue 5, pp. 3849 - 3857
An air-stable half-sandwich nickel(II) complex bearing a phosphinophenolato ligand, Cp*Ni(1,2-Ph2PC6H4O) (1), has been designed and synthesized for activation... 
nickel(II) catalyst | SILANE SIGMA-COMPLEXES | hydroboration | B-H bond cleavage | HYDROSILYLATION | CHEMISTRY, PHYSICAL | TRANSFER HYDROGENATION | RUTHENIUM | REGIOSELECTIVE 1,4-HYDROBORATION | PYRIDINES | metal-ligand cooperation | REDUCTION | HETEROCYCLES | CHEMISTRY | nickel hydride | DEAROMATIZATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2013, Volume 3, Issue 12, pp. 2930 - 2934
Indenediide Pd complexes 1a–c are shown to very efficiently catalyze the cycloisomerization of alkynoic acids into alkylidene lactones via metal–ligand... 
palladium | homogeneous catalysis | noninnocent ligand | cycloisomerization | pincer complexes | metal-ligand cooperation | ASYMMETRIC CATALYSIS | METHANOL | CHEMISTRY, PHYSICAL | ENOL LACTONES | HYDROGEN | DEHYDROGENATION | INTRAMOLECULAR CYCLIZATION | RUTHENIUM COMPLEXES | CATALYZED CYCLIZATION | CARBON-DIOXIDE | WATER
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 24, pp. 9758 - 9761
A bis(phosphine)/triflatosilyl pincer-type Rh(I) complex can reversibly store one equivalent of H-2 across the Si-Rh bond upon triflate migration from silicon... 
D6 ML5 COMPLEXES | PALLADIUM | RHODIUM | NICKEL | CARBON-MONOXIDE | SILYLENE COMPLEXES | REACTIVITY | METAL-LIGAND COOPERATION | BOND ACTIVATION | REDUCTIVE ELIMINATION | CHEMISTRY, INORGANIC & NUCLEAR | Catalysts | Cooperation | Migration | Strategy | Silicon | Catalysis | Bonding | Hydrogenation
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2015, Volume 2015, Issue 28, pp. 4761 - 4768
An 8‐fluoroquinoline‐based dearomatized PNF‐pincer (Ar)PdII complex 1 reacts with N‐methylaniline to give an aromatized PNNH‐pincer complex, the product of the... 
Pincer complexes | Palladium | Fluorine | Cross‐coupling | Metal–ligand cooperation | Metal-ligand cooperation | Cross-coupling | HALIDES | CATALYSIS | AMMONIA | NUCLEOPHILIC-SUBSTITUTION | OXIDATIVE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR | ALCOHOLS | AMINES | WATER | Polychlorinated biphenyls | Sulfides | Fluorides | Hydrogen | Activation energy | Ligands | Cooperation | Pathways | Amides | Activation | Joining | Bonding
Journal Article
Journal of Coordination Chemistry, ISSN 0095-8972, 07/2018, Volume 71, Issue 11-13, pp. 1679 - 1689
Journal Article
International Journal of Hydrogen Energy, ISSN 0360-3199, 10/2016, Volume 41, Issue 39, pp. 17208 - 17215
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 06/2016, Volume 45, Issue 24, pp. 9758 - 9761
A bis(phosphine)/triflatosilyl pincer-type Rh(i) complex can reversibly store one equivalent of H2 across the Si-Rh bond upon triflate migration from silicon... 
Journal Article
ACS Applied Materials & Interfaces, ISSN 1944-8244, 08/2018, Volume 10, Issue 32, pp. 27365 - 27373
Journal Article
Chemistry Letters, ISSN 0366-7022, 4/2019, Volume 48, Issue 4, pp. 364 - 366
Iron(II) dichloride coordinated with a phenanthroline-based meridional PNNP ligand [FeCl2(PNNP)] (1) (PNNP =... 
Metal-ligand cooperation | ACTIVATION | PNP | AMINES | PNNP ligand | Iron | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | DEAROMATIZATION | X-ray diffraction | Single crystals | Ligands | Dichlorides | Crystals | Iron chlorides
Journal Article
Journal of Coordination Chemistry, ISSN 0095-8972, 07/2018, Volume 71, Issue 11-13, pp. 1679 - 1689
Herein we report the reversible activation of CO 2 by the dearomatized complex [( t BuPNP*)Ir(COE)] (1) and by the aromatized complex [( t BuPNP)Ir(C 6 H 5 )]... 
2 | carbon dioxide, CO | Iridium complex | Activation | metal-ligand cooperation
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2013, Volume 3, Issue 5, pp. 920 - 927
Full quantum mechanical calculations demonstrate that cooperativity in the form of the activation of the M–C bond (M: transition metal or boron, C: the ipso... 
catalysis | small molecule activation | density functional theory | metal-ligand cooperativity | AUXILIARY BASIS-SETS | HYDROGENATION | CORRELATION-ENERGY | CHEMISTRY, PHYSICAL | RUTHENIUM | AMMONIA-BORANE | DEHYDROGENATION | PINCER COMPLEXES | BOND ACTIVATION | REDUCTIVE AMINATION | LIGAND COOPERATION
Journal Article
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