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chemistry, multidisciplinary (37) 37
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FEBS Letters, ISSN 0014-5793, 05/2014, Volume 588, Issue 9, pp. 1827 - 1831
We report the trapping of two metalloradical intermediates corresponding to the transitions S to S and S to S of the oxygen evolving complex (OEC) of... 
Metalloradical | Photosystem II
Journal Article
FEBS Letters, ISSN 0014-5793, 05/2014, Volume 588, Issue 9, pp. 1827 - 1831
•The S2TyrZ intermediate is trapped on the onset of the S2 to S3 transition.•An intermediate trapped at 250K in the S3 to S0 transition is ascribed to... 
Metalloradical | Photosystem II | formula omitted
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2017, Volume 53, Issue 81, pp. 11173 - 11176
A chemoselective Co(ii)-catalyzed effective synthesis of sulfonylamidyl amide and 3-imine indole derivatives by using isocyanides and sulfonyl azides has been... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 81, pp. 11173 - 11176
A chemoselectiveCo(II)-catalyzed effective synthesis of sulfonylamidyl amide and 3-imine indole derivatives by using isocyanides and sulfonyl azides has been... 
ALKENES | ACTIVATION | BONDS | CYCLOPROPANATION | CHEMISTRY | OLEFIN AZIRIDINATION | GENERATION | CO(II)-BASED METALLORADICAL CATALYSIS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 16, pp. 4828 - 4832
A new strategy for the sequential formation of aryl and amidyl C–N bonds is reported. Using trichloroethoxysulfonyl azide as a bifunctional nitrogen source,... 
TRACELESS STAUDINGER LIGATION | AMINATION | ACTIVATION | ARENES | CHEMISTRY, ORGANIC | BOND FORMATION | ACYL AZIDES | ORGANIC AZIDES | METALLORADICAL CATALYSIS | CARBOXYLIC-ACIDS | AMIDATING REAGENT
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 04/2018, Volume 24, Issue 20, pp. 5253 - 5258
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2017, Volume 53, Issue 44, pp. 5993 - 5996
An unprecedented coupling reaction between aromatic amines and diazo compounds was well developed, which afforded a bridge connecting between radical chemistry... 
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5896 - 5899
In this letter, an unprecedented cross-coupling reaction between copper carbene and nitroso radical has been developed. This radical-carbene coupling reaction... 
H FUNCTIONALIZATION | FACILE SYNTHESIS | GAMMA-AMINO KETONES | DIRECT CONVERSION | CHEMISTRY, ORGANIC | BOND FORMATION | DIAZO-COMPOUNDS | BETA-HYDROXY KETONES | TERT-BUTYL NITRITE | CO(II)-BASED METALLORADICAL CATALYSIS | UNACTIVATED ALKENES
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 20, pp. 5589 - 5592
A cobalt-catalyzed decarboxylative cross-coupling reaction of (hetero)­aryl carboxylic acids with benzothiazoles or benzoxazoles is reported. This represents a... 
RADICAL CONDITIONS | C(SP)-H BONDS | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | RECENT PROGRESS | CARBON-HYDROGEN BONDS | METALLORADICAL CATALYSIS | BENZOIC-ACIDS | CARBOXYLIC-ACIDS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 9, pp. 2670 - 2674
Novel D-2-symmetric chiral amidoporphyrins with alkyl bridges across two chiral amide units on both sides of the porphyrin plane (designated "HuPhyrin") have... 
ligand design | chiral porphyrinoids | cobalt | metalloradical catalysis | synthetic methods | ENANTIOSELECTIVE RADICAL CYCLIZATION | INTRAMOLECULAR CYCLOPROPANATION | ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | ASYMMETRIC CYCLOPROPANATION | CONSTRUCTION | C-H AMINATION
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2016, Volume 55, Issue 17, pp. 8603 - 8611
The synthesis, spectroelectrochemical characterization (ultraviolet–visible and nuclear magnetic resonance), solid state structures, and computational metric... 
TRANSITION-METAL-COMPLEXES | NON-INNOCENT | PALLADIUM COMPLEXES | RADICAL LIGANDS | ORGANOMETALLIC CHEMISTRY | H BOND AMINATION | CATECHOLATE LIGANDS | OXIDATIVE ADDITION | CO(II)-BASED METALLORADICAL CATALYSIS | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2016, Volume 81, Issue 23, pp. 11743 - 11750
The cobalt-catalyzed cross-dehydrogenative coupling of (benz)­oxazoles and ethers is described. Access to some important bioactive heteroaryl ether derivatives... 
FUNCTIONALIZATION | C(SP)-H BONDS | HETEROARENES | DIRECT AMINATION | AMINO-ACIDS | CHEMISTRY, ORGANIC | DIRECT C2-ALKYLATION | CARBON-HYDROGEN BONDS | METALLORADICAL CATALYSIS | C-H ACTIVATION | DIRECT ALKYLATION | Chemical properties | Catalysis | Research | Ethers | Cobalt
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2017, Volume 7, Issue 6, pp. 3893 - 3899
A Co­(II)-catalyzed synthesis of sulfonyl guanidines by using amines, isonitriles, and organic azides as nitrene sources has been developed. This protocol... 
computational study | nitrene | amines | cobalt(II)-catalysis | organic azides | sulfonyl guanidines | isonitriles | AZIDES | SOLID-PHASE SYNTHESIS | CYCLOPROPANATION | CHEMISTRY, PHYSICAL | OLEFIN AZIRIDINATION | (+)-SAXITOXIN | ALKENES | GENERATION | STEREOSELECTIVE-SYNTHESIS | CO(II)-BASED METALLORADICAL CATALYSIS | C-H AMINATION
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2017, Volume 139, Issue 14, pp. 5031 - 5034
A new reactivity pattern of Rh-2(II)-Narylnitrenes was discovered that facilitates the synthesis of medium-sized N-heterocycles from... 
TANDEM REACTIONS | ORGANIC-SYNTHESIS | DESIGN | CASCADE REACTIONS | FUNCTION-ORIENTED SYNTHESIS | BOND AMINATION | METALLORADICAL CATALYSIS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | NITRENE COMPLEXES
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 9/2016, Volume 55, Issue 38, pp. 11604 - 11608
Co(II)-based metalloradical catalysis (MRC) has been successfully applied for effective construction of the highly strained... 
intramolecular aziridination | aziridine ring-opening | neurokinin 1 (NK1) receptor | metalloradical catalysis | cobalt porphyrin
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2018, Volume 83, Issue 21, pp. 13402 - 13413
A novel cobalt-catalyzed C–H alkylation of arenes and olefins is achieved with (pyridin-2-yl)­isopropyl amine as an N,N-bidentate directing group. Different... 
FUNCTIONALIZATION | ACTIVATION | NICKEL | STRATEGY | CHEMISTRY, ORGANIC | UNACTIVATED C(SP)-H | IRON | METALLORADICAL CATALYSIS | DEHYDROGENATIVE COUPLING REACTION | C-H BONDS | DIRECTED ALKYLATION
Journal Article
Nature Communications, ISSN 2041-1723, 12/2018, Volume 9, Issue 1, pp. 227 - 13
The development of a general catalytic method for the direct and stereoselective construction of cyclopropanes bearing highly congested vicinal all-carbon... 
VISIBLE-LIGHT | ALKENES | REAGENTS | ENANTIOSELECTIVE SYNTHESIS | MULTIDISCIPLINARY SCIENCES | CONSTRUCTION | SYNTHETIC APPLICATIONS | ORGANOCATALYSIS | METAL | CO(II)-BASED METALLORADICAL CATALYSIS | CYCLIZATION | Construction | Transformation | Alkenes | Quaternary | Aldehydes | Enantiomers | Carbon | Substrates | Intermediates | Cycloaddition | Hexanes | Catalysis | Copper | Chemical synthesis | Organic compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 44, pp. 5993 - 5996
Journal Article
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