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Angewandte Chemie - International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 45, pp. 14227 - 14231
The solution structure of AlMe F and its reactivity with a prototypical ansa-metallocene have been investigated by advanced NMR techniques, in an attempt to... 
methylalumoxane | aluminum fluoride | olefin polymerization | NMR spectroscopy | ion pairs
Journal Article
Macromolecules, ISSN 0024-9297, 04/2012, Volume 45, Issue 8, pp. 3289 - 3297
The discovery of methylaluminoxane (MAO) was the start for investigations and innovations of new classes of highly active olefin polymerization catalysts.... 
METHYLALUMOXANE | POLYMERS | SOLUBLE ZIEGLER CATALYSTS | POLYMER SCIENCE | CHIRAL ZIRCONOCENE | LOW-PRESSURE POLYMERIZATION | METALLOCENE CATALYSTS | KINETICS | ETHYLENE POLYMERIZATION | COPOLYMERIZATION | PROPYLENE POLYMERIZATIONS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 09/2015, Volume 48, Issue 9, pp. 2599 - 2611
For over 40 years following the polyolefin catalyst discoveries of Hogan and Banks (Phillips) and Ziegler (Max Planck Institute), chemists traversed the... 
METHYLALUMOXANE | COBALT CATALYSTS | ACTIVATION | ETHYLENE OLIGOMERIZATION | METAL-CATALYSTS | DIMERIZATION | IRON CATALYSTS | 2,6-BIS(IMINO)PYRIDYL COMPLEXES | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ALPHA-DIIMINE LIGANDS | Polymerization | Pyridine | Chemical properties | Research | Catalysts | Olefins | Oligomerization | Ethylene | Insertion | Ligands | Iron | Catalysis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/1995, Volume 117, Issue 23, pp. 6414 - 6415
Journal Article
Chemistry of Materials, ISSN 0897-4756, 10/2016, Volume 28, Issue 20, pp. 7444 - 7450
An insoluble form of methylaluminoxane, also known as solid polymethylaluminoxane (sMAO), has been synthesized by the controlled hydrolysis of... 
OLEFIN-POLYMERIZATION | METHYLALUMOXANE | METHYLALUMINOXANE MAO | ROUTE | METALLOCENE CATALYSTS | ALUMINOXANES | MATERIALS SCIENCE, MULTIDISCIPLINARY | COMPLEXES | ZIRCONOCENE | HYDROLYSIS | CHEMISTRY, PHYSICAL | TRIMETHYLALUMINUM
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2018, Volume 24, Issue 21, p. n/a
Methylalumoxane (MAO) is an important cocatalyst in olefin polymerization. Its structure is poorly understood but using mass spectrometry we can obtain insight... 
methylalumoxane | mass spectrometry | cocatalysts | activators | homogeneous catalysis | Oligomers | Mass spectrometry | Catalysis | Aging | Polymerization | Mass spectroscopy | Oxidation | Amine oxidase (flavin-containing)
Journal Article
Science, ISSN 0036-8075, 1/2000, Volume 287, Issue 5452, pp. 460 - 462
More than half of the 170 million metric tons of polymers produced each year are polyolefins. Current technology uses highly active cationic catalysts, which... 
Transition metals | Catalysts | Alkenes | Materials | Polymerization | Ligands | Reports | Polymers | Functional groups | Monomers | Phosphines | METHYLALUMOXANE | POLYMERIZATION | ETHYLENE HOMOPOLYMERIZATION | MULTIDISCIPLINARY SCIENCES | Chemistry | Nickel
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2015, Volume 2015, Issue 1, pp. 19 - 43
Journal Article
Macromolecules, ISSN 0024-9297, 11/2018, Volume 51, Issue 21, pp. 8574 - 8584
Syndiotactic poly­(3-methyl-1-butene) (sP3MB) has been obtained for the first time by hydrogenation of 3,4-poly­(isoprene), which in turn has been synthesized... 
METHYLALUMOXANE | POLYMER SCIENCE | HYDROGENATION | POLYPROPYLENE | CRYSTAL-STRUCTURE | CHAIN CONFORMATION | PROPENE | PARAMETERS | POLYMORPHISM | CATALYSTS | PROPYLENE POLYMERIZATIONS
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 01/2011, Volume 696, Issue 2, pp. 473 - 487
Dinuclear complexes of palladium(II), containing two bridging halogen (Cl or Br) ligands, [N Bu ] [(X C ) Pd(μ-Cl) Pd(C X ) ] and [(X C )(L)Pd(μ-Y) Pd(C X... 
Norbornene | Methylalumoxane, MAO | Palladium, cyclopentadienyl complexes | Polymerization, vinyl - addition | Half-sandwich complexes
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 05/2019, Volume 2019, Issue 18, pp. 2392 - 2395
In this contribution, we investigated the key factors for the successful preparation of methylaluminoxane (MAO) from CO2 and Me3Al by analyzing the reaction... 
Polymerization | Cocatalysts | Synthesis design | Methylaluminoxane | Carbon dioxide | AL-27 NMR | ROUTE | ACTIVATION | NMR-SPECTROSCOPY | OLEFIN POLYMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR | METHYLALUMOXANE | ETHYLENE | MAO | METALLOCENE | TRIMETHYLALUMINUM | Analysis | Olefins | Propylene | Nuclear magnetic resonance--NMR | Polyolefins
Journal Article
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, ISSN 1463-9076, 09/2016, Volume 18, Issue 34, pp. 24106 - 24118
Calculations of NMR shielding tensors and nuclear quadrupole coupling (NQC) tensors at the Kohn-Sham density functional level are used to simulate Al-27... 
OLEFIN-POLYMERIZATION | QUADRUPOLAR NUCLEI | SURFACE SITES | ALUMINUM | CORRELATED MOLECULAR CALCULATIONS | METHYLALUMOXANE MAO | MASS-SPECTROMETRIC CHARACTERIZATION | DYNAMIC EQUILIBRIUM | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | STRUCTURAL-CHARACTERIZATION | GAUSSIAN-BASIS SETS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 45, pp. 14262 - 14266
Radical heterocyclizations triggered by electron transfer to amide‐type carbonyls, using SmI2‐H2O, provide straightforward access to bicyclic heterocyclic... 
cyclizations | reaction mechanisms | samarium | radicals | heterocycles | OLEFIN-POLYMERIZATION | ION-PAIRS | COMPLEXES | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | METHYLALUMOXANE | ALUMINUM | REACTION EQUILIBRIA | ZIRCONOCENE | CATALYSTS | CONTAINING ACTIVATORS | Electron transport | Electron transfer | Carbonyl compounds | Scaffolds | Cascades | Carbonyls
Journal Article
by Guo, YT and He, F and Zhang, Z and Khan, A and Fu, ZS and Xu, JT and Fan, ZQ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 04/2016, Volume 808, pp. 109 - 116
Ethylene polymerization with rac-Et(Ind)(2)ZrCl2/aluminoxane catalysts were conducted under different conditions, including varied reaction time, cocatalyst... 
REDUCED NUMBER | MOLECULAR-WEIGHT POLYETHYLENE | METALLOCENE CATALYSTS | Ethylene | Polymerization | OLEFIN POLYMERIZATION | PROPYLENE POLYMERIZATION | ZIRCONIUM COMPLEXES | CHEMISTRY, ORGANIC | Metallocene | CHEMISTRY, INORGANIC & NUCLEAR | METHYLALUMOXANE | METHYLALUMINOXANE MAO | Trimethylaluminum | ACTIVE-CENTER DISTRIBUTION | MAO | ZIEGLER-NATTA CATALYSTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/1996, Volume 118, Issue 1, pp. 267 - 268
Journal Article