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n-aryl enamines (88) 88
chemistry, organic (71) 71
chemistry, multidisciplinary (46) 46
oxidative cyclization (42) 42
indoles (41) 41
catalysis (36) 36
index medicus (29) 29
derivatives (24) 24
c-h activation (23) 23
anilines (21) 21
bond formation (21) 21
synthesis (20) 20
c bond formation (19) 19
cyclization (19) 19
molecular structure (18) 18
n-aryl imines (18) 18
efficient synthesis (17) 17
functionalization (17) 17
palladium (17) 17
internal alkynes (16) 16
alkynes (15) 15
organic chemistry (14) 14
activation (12) 12
chemistry, applied (12) 12
heterocycles (12) 12
hydrogenation (12) 12
indoles - chemical synthesis (12) 12
annulation (11) 11
c-h functionalization (11) 11
indole (11) 11
indoles - chemistry (11) 11
oxidation-reduction (11) 11
amination (10) 10
chemistry (10) 10
imines (10) 10
one-pot synthesis (10) 10
polysubstituted pyrroles (10) 10
regioselective synthesis (10) 10
stereoisomerism (10) 10
amines (9) 9
efficient (9) 9
indol (9) 9
reduction (9) 9
stereoselective-synthesis (9) 9
amines - chemistry (8) 8
catalyzed oxidative cyclization (8) 8
chemical reactions (8) 8
direct arylation (8) 8
ketones (8) 8
pyrroles (8) 8
terminal alkynes (8) 8
alkaloids (7) 7
cyclisation (7) 7
ch activation (7) 7
intramolecular cyclization (7) 7
molecular-oxygen (7) 7
nonrearranged monoterpenoid unit (7) 7
trichlorosilane (7) 7
alkenes (6) 6
asymmetric transfer hydrogenation (6) 6
bond-formation (6) 6
bonding (6) 6
complexes (6) 6
cross-coupling reactions (6) 6
enantiomers (6) 6
hydrogen (6) 6
hydrosilylation (6) 6
organocatalysis (6) 6
oxidative coupling (6) 6
pyrrole (6) 6
2,3-disubstituted indoles (5) 5
aldehydes (5) 5
arylation (5) 5
esters (5) 5
expedient synthesis (5) 5
ketones - chemistry (5) 5
palladium - chemistry (5) 5
palladium-catalyzed reactions (5) 5
pyrrol (5) 5
regioselectivity (5) 5
ruthenium (5) 5
substrates (5) 5
1st total-synthesis (4) 4
alcohols (4) 4
amines - chemical synthesis (4) 4
aromatic ketimines (4) 4
aromatic ketones (4) 4
arylboronic acids (4) 4
bond functionalizations (4) 4
cascade reactions (4) 4
catalysts (4) 4
catalyzed formation (4) 4
chlorides (4) 4
coupling (4) 4
enamines (4) 4
enantioselective reduction (4) 4
facile synthesis (4) 4
formamide (4) 4
functionalisation (4) 4
funktionalisierung (4) 4
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Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2018, Volume 360, Issue 22, pp. 4446 - 4451
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 37, pp. 9220 - 9222
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 07/2010, Volume 132, Issue 28, pp. 9585 - 9587
A conceptually novel pyrrole synthesis is reported, efficiently merging enamines and (unactivated) alkynes under oxidative conditions. In an intermolecular Rh... 
FUNCTIONALIZATION | N-ARYL ENAMINES | SUBSTITUTED PYRROLES | EFFICIENT SYNTHESIS | CATALYZED REACTION | BOND FORMATION | INTERNAL ALKYNES | CONTAINING HETEROCYCLES | CHEMISTRY, MULTIDISCIPLINARY | POLYSUBSTITUTED PYRROLES | INDOLES
Journal Article
Russian Chemical Reviews, ISSN 0036-021X, 2015, Volume 84, Issue 6, pp. 601 - 633
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 03/2013, Volume 11, Issue 12, pp. 1929 - 1932
The synthetically and biologically important 4-methyl and 4-methoxy tetrahydro-gamma-carboline compounds were readily synthesized in high yields from an aryl... 
DESIGN | N-ARYL ENAMINES | RECEPTOR ANTAGONISTS | ANALOGS | ANILINES | HORSFILINE | CHEMISTRY, ORGANIC | INHIBITORS | DERIVATIVES | INDOLES | CYCLIZATION | Amines - chemistry | Carbolines - chemical synthesis | Carbolines - chemistry | Oxidation-Reduction | Molecular Structure | Amines - chemical synthesis | Carbon - chemistry
Journal Article
SYNLETT, ISSN 0936-5214, 07/2017, Volume 28, Issue 12, pp. 1481 - 1485
A novel tert- butyl hydroperoxide ( TBHP)- promoted oxidative C= C double- bond cleavage of enamines is described. Heating a solution of an electron- deficient... 
tert-butyl hydroperoxide | N-ARYL ENAMINES | bond cleavage | oxidation | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | arylacetamides | ALPHA-KETOAMIDES | C-H FUNCTIONALIZATION | RADICAL-ADDITION | UNACTIVATED ALKENES | enamines | AEROBIC OXYGENATION | oxamates | FREE ACYLATION | MOLECULAR-OXYGEN | CARBOXYLIC-ACIDS
Journal Article
by Hu, WG and Zheng, J and Li, M and Wu, WQ and Liu, HY and Jiang, HF
CHINESE JOURNAL OF CHEMISTRY, ISSN 1001-604X, 08/2018, Volume 36, Issue 8, pp. 712 - 715
Herein, two efficient palladium-catalyzed intermolecular oxidative coupling reactions of (Z)-enamines with isocyanides via selective -C(sp(2))-H and/or C=C... 
INSERTION | CASCADE REACTIONS | cleavage reaction | N-ARYL ENAMINES | CHEMISTRY, MULTIDISCIPLINARY | (Z)-enamines | oxidative coupling | MULTICOMPONENT REACTIONS | ALKENES | isocyanides | 1,2-ACYL MIGRATION | REGIOSELECTIVE SYNTHESIS | palladium | SINGLET OXYGEN | CYCLIZATION | MOLECULAR-OXYGEN | Olefins | Palladium
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2011, Volume 76, Issue 8, pp. 2860 - 2866
A new and efficient synthesis of polysubstituted pyrroles by a sequential one-pot three-component reaction between primary aliphatic amines, active methylene... 
MULTICOMPONENT REACTIONS | NATURAL-PRODUCT SYNTHESIS | N-ARYL ENAMINES | C BOND FORMATION | ONE-POT | 1,3-DICARBONYL COMPOUNDS | SUBSTITUTED PYRROLES | BIOLOGICAL-ACTIVITY | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | POLYSUBSTITUTED PYRROLES | Chemical reactions | Chemical properties | Chemical synthesis | Methylene compounds | Analysis | Pyrrole
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2016, Volume 358, Issue 14, pp. 2267 - 2272
Imino‐/enaminophosphonates derived from amines and diethyl phenacyl phosphonates undergo oxidative cyclization via CH bond activation catalyzed by palladium... 
ketophosphonates | indoles | imine‐enamines | CH bond activation | phosphonates | pyrroles | imine-enamines | N-ARYL ENAMINES | PHOSPHORYLATION | ANNULATION | ARYLATION | C-H bond activation | CHEMISTRY, ORGANIC | BOND FORMATION | INDOLE-DERIVATIVES | C-H ACTIVATION | FUNCTIONALIZATION | AMINATION | INHIBITORS | CHEMISTRY, APPLIED | Palladium | Phosphonates | Synthesis | Amines | Chlorides | Activation | Catalysis | Bonding
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 21, pp. 4631 - 4634
The reactions of various enaminones with elemental sulfur giving rise to both sulfur-bridged enaminones and chromones have been realized via iodine promotion.... 
ELEMENTAL SULFUR | PALLADIUM | CATALYZED OXIDATIVE CYCLIZATION | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | N-ARYL ENAMINES | CHEMISTRY, ORGANIC | BOND FORMATION | TERTIARY ENAMINES | C-H ACTIVATION | INDOLES
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 05/2017, Volume 15, Issue 21, pp. 4631 - 4634
The reactions of various enaminones with elemental sulfur giving rise to both sulfur-bridged enaminones and chromones have been realized via iodine promotion.... 
Journal Article
Chemical Reviews, ISSN 0009-2665, 05/2018, Volume 118, Issue 9, pp. 4485 - 4540
Journal Article
ISSN 2041-6520, 11/2012, Volume 4, Issue 1, pp. 29 - 41
Indoles, both naturally occurring and synthetic, exhibit wide-ranging biological activity. Unusual and complex molecular architectures occur among their... 
Journal Article
Chemical Science, ISSN 2041-6520, 2013, Volume 4, Issue 1, pp. 29 - 41
Indoles, both naturally occurring and synthetic, exhibit wide-ranging biological activity. Unusual and complex molecular architectures occur among their... 
INTRAMOLECULAR CYCLIZATION | N-ARYL ENAMINES | FISCHER INDOLIZATION | C BOND FORMATION | EXPEDIENT SYNTHESIS | TERMINAL ALKYNES | OXIDATIVE CYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY | RHODIUM CARBENOIDS | ARYLBORONIC ACIDS | H INSERTION REACTIONS
Journal Article
by Wang, JY and Liu, SP and Yu, W
SYNLETT, ISSN 0936-5214, 09/2009, Issue 15, pp. 2529 - 2533
Enamine esters or ketones could undergo homocoupling by the action of (diacetoxyiodo)benzene in the presence of BF3 center dot OEt2, giving rise to pyrrole... 
LEAD-TETRAACETATE | N-ARYL ENAMINES | VINYL AZIDES | HIGHLY SUBSTITUTED PYRROLES | 1,3-DICARBONYL COMPOUNDS | (diacetoxyiodo) benzene | CHEMISTRY, ORGANIC | pyrroles | INDOLES | oxidative coupling | enamine esters | CHEMISTRY | POLYVALENT IODINE | FUNCTIONALIZED PYRROLES | TETRASUBSTITUTED PYRROLES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2013, Volume 52, Issue 18, pp. 4892 - 4896
sp3ectacularly mild! An efficient PdII‐catalyzed intramolecular dehydrogenative cyclization of imines affords (dihydro)pyrrole products using molecular oxygen... 
imines | palladium | enamines | dioxygen | pyrroles | DIRECT ARYLATION | N-ARYL ENAMINES | PD(II)-CATALYZED OLEFINATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | OXIDATIVE OLEFINATION | FUNCTIONALIZATION | METAL-CATALYZED REACTIONS | HECK REACTION | MOLECULAR-OXYGEN | Sole | Synthesis | Ketones | Imines | Dehydrogenation | Pyrroles | Assembly | Functional groups
Journal Article