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n-pivaloylindoles (24) 24
chemistry, organic (13) 13
indoles (11) 11
chemistry, multidisciplinary (10) 10
functionalization (9) 9
room-temperature (9) 9
activation (6) 6
arylation (6) 6
nitrogen-source (6) 6
arenes (5) 5
c-h activation (5) 5
mild (5) 5
amination (4) 4
bond activation (4) 4
c-h amidation (4) 4
catalysis (4) 4
catalyzed direct arylation (4) 4
sulfonyl azides (4) 4
1-benzazole (3) 3
7-substituted indoles (3) 3
acyl azides (3) 3
copper (3) 3
diaryliodonium salts (3) 3
direct access (3) 3
directing group (3) 3
heterocycles (3) 3
indol (3) 3
indole (3) 3
ligands (3) 3
mild conditions (3) 3
palladium (3) 3
regioselectivity (3) 3
selective arylation (3) 3
2-substituted indoles (2) 2
2nd total-synthesis (2) 2
access (2) 2
aliphatic amides (2) 2
alkylation (2) 2
amidation (2) 2
antiviral agents (2) 2
azides (2) 2
bond amidation (2) 2
bond arylation (2) 2
bond functionalization (2) 2
c-3 arylation (2) 2
c-h functionalization (2) 2
chelation-assistance (2) 2
chemical synthesis (2) 2
chemistry, applied (2) 2
clavicipitic acid (2) 2
cobalt catalysis (2) 2
conjugated pi-systems (2) 2
derivatives (2) 2
dictyodendrins f (2) 2
direct arylation (2) 2
dual c-h (2) 2
functional groups (2) 2
functional-group (2) 2
functionalisation (2) 2
funktionalisierung (2) 2
funktionelle gruppe (2) 2
h bond functionalization (2) 2
h chalcogenation (2) 2
indolines (2) 2
nonrearranged monoterpenoid unit (2) 2
one-pot synthesis (2) 2
organic azides (2) 2
ortho-metalation (2) 2
regioselektivität (2) 2
rhodium (2) 2
sulfenylation (2) 2
unactivated c-h bonds (2) 2
-duocarmycin sa (1) 1
-lysergic acid (1) 1
4-substituted indoles (1) 1
6,7-benzindole (1) 1
6,7‐benzindole (1) 1
acrolein (1) 1
acyloxylation (1) 1
aldehydes (1) 1
alkenylation (1) 1
alkylierung (1) 1
alkynes (1) 1
allylic alcohols (1) 1
amines (1) 1
antiinflammatory evaluation (1) 1
aromatic carboxylic-acids (1) 1
aromatic compounds (1) 1
aryl (1) 1
aryl boronic acids (1) 1
aryl thiols (1) 1
arylierung (1) 1
asymmetric total-synthesis (1) 1
benzene portion (1) 1
bonds (1) 1
borylation (1) 1
boyland-sims oxidation (1) 1
c-7 position (1) 1
c-c coupling (1) 1
c-h amination (1) 1
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Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 28, pp. 8734 - 8737
The first example of direct and site-selective arylation of indoles at the C6 position has been reported. The key to this high regioselectivity is the... 
FUNCTIONALIZATION | MILD | ROOM-TEMPERATURE | ACTIVATION | ARENES | H BOND ARYLATION | DIARYLIODONIUM SALTS | N-PIVALOYLINDOLES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Arylation | Research | Chemical properties | Catalysis | Copper | Indole
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2502 - 2505
An efficient Ir-catalyzed amidation of indoles with sulfonyl azides is disclosed, affording diverse C4-amidated indoles exclusively under mild conditions. In... 
HETEROCYCLES | FUNCTIONAL MOLECULES | NITROGEN-SOURCE | AMIDATION | CHEMISTRY, ORGANIC | N-PIVALOYLINDOLES | BOND ACTIVATION | SCAFFOLDS | ORGANIC AZIDES | C-H AMINATION | ALKENYLATION
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 14, pp. 1676 - 1685
Recent advances in transition metal-catalyzed selective C–H functionalization of indoles have garnered tremendous attention. Great efforts have been devoted to... 
Regioselectivity | Indoles
Journal Article
Chemical Communications, ISSN 1359-7345, 2/2018, Volume 54, Issue 14, pp. 1676 - 1685
Recent advances in transition metal-catalyzed selective C-H functionalization of indoles have garnered tremendous attention. Great efforts have been devoted to... 
DUAL C-H | ROOM-TEMPERATURE | 2-SUBSTITUTED INDOLES | C-3 ARYLATION | DICTYODENDRINS F | SELECTIVE ARYLATION | N-PIVALOYLINDOLES | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | ORTHO-METALATION | CATALYZED DIRECT ARYLATION
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 06/2016, Volume 14, Issue 21, pp. 4804 - 4808
Iridium(iii)-catalyzed direct C7-sulfonamidation of indoles with sulfonyl azides is described. The developed method has good compatibility with diverse... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 21, pp. 4804 - 4808
Iridium(III)-catalyzed direct C7-sulfonamidation of indoles with sulfonyl azides is described. The developed method has good compatibility with diverse... 
ANTIVIRAL AGENTS | CHELATION-ASSISTANCE | DIRECT ARYLATION | SULFONYL AZIDES | 7-SUBSTITUTED INDOLES | C-H AMIDATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | N-PIVALOYLINDOLES | CLAVICIPITIC ACID | NONREARRANGED MONOTERPENOID UNIT
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 37, pp. 5117 - 5120
The C4-aminated indole scaffold is frequently encountered in several natural products and biologically active compounds. Herein we disclose a simple and short... 
DIRECTING GROUP | BOND AMIDATION | ROOM-TEMPERATURE | INDOLACTAM-V | SULFONYL AZIDES | NITROGEN-SOURCE | C-H AMIDATION | INTERMOLECULAR AMIDATION | N-PIVALOYLINDOLES | SYNTHETIC ROUTE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2017, Volume 15, Issue 39, pp. 8302 - 8307
An Ir(III)-catalyzed regioselective C-H amidation of anilines with sulfonyl azides is described. The developed protocol has good compatibility with diverse... 
MILD | FUNCTIONALIZATION | AMINATION | ACTIVATION | LIGANDS | NITROGEN-SOURCE | ARENES | CHEMISTRY, ORGANIC | N-PIVALOYLINDOLES | ACYL AZIDES | INDOLES
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 10/2017, Volume 15, Issue 39, pp. 8302 - 8307
An Ir(iii)-catalyzed regioselective C-H amidation of anilines with sulfonyl azides is described. The developed protocol has good compatibility with diverse... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2017, Volume 7, Issue 2, pp. 1030 - 1034
A versatile protocol for the C–H chalcogenation of indolines and indoles by means of copper catalysis was established. The C–H functionalization occurred... 
indolines | copper | indoles | CâH activation | chalcogenation | ROOM-TEMPERATURE | BOND FUNCTIONALIZATION | CHEMISTRY, PHYSICAL | UNACTIVATED ARENES | DIRECT THIOLATION | ARYL THIOLS | DIRECTING GROUPS | ELEMENTAL SULFUR | C-H activation | COBALT CATALYSIS | N-PIVALOYLINDOLES | DIARYL DISULFIDES
Journal Article
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 22, pp. 6184 - 6187
A Rh­(III)-catalyzed site-selective C–H activation of C(3)-functionalized indoles in a coupling with diazo esters has been realized with carbonyl as a weakly... 
DIRECTING GROUP | FUNCTIONALIZATION | COMPOUNDS ACCESS | MILD CONDITIONS | ARYLATION | CHEMISTRY, ORGANIC | N-PIVALOYLINDOLES | BOND ACTIVATION | RH(III)-CATALYZED SYNTHESIS | C-H ACTIVATION | OXYGEN-ATOM
Journal Article
Organic Letters, ISSN 1523-7060, 07/2017, Volume 19, Issue 13, pp. 3664 - 3667
An efficient rhodium-catalyzed method for direct C–H functionalization at the C4 position of unprotected indoles has been developed. The utility of this method... 
CLAVINE ALKALOIDS | LYSERGIC-ACID | ONE-POT SYNTHESIS | 4-SUBSTITUTED INDOLES | ERGOT ALKALOIDS | CHEMISTRY, ORGANIC | (+)-LYSERGIC ACID | N-PIVALOYLINDOLES | ASYMMETRIC TOTAL-SYNTHESIS | C-H ACTIVATION | ENANTIOSELECTIVE TOTAL-SYNTHESIS
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2017, Volume 53, Issue 90, pp. 12197 - 12200
A straightforward Rh(iii)-catalyzed general strategy was developed for the site-selective remote C4 (sp2) and C2 (sp3)-methyl thiolation of an indole core,... 
Catalysis | Indoles | Rhodium | Functional groups
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 90, pp. 12197 - 12200
A straightforward Rh(III)-catalyzed general strategy was developed for the site-selective remote C4 (sp(2)) and C2 (sp(3))-methyl thiolation of an indole core,... 
ALIPHATIC AMIDES | FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | CONJUGATED PI-SYSTEMS | ARYLATION | SULFENYLATION | N-PIVALOYLINDOLES | DIRECT ACCESS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | H CHALCOGENATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 3966 - 3971
An effective and practical strategy has been established for the direct and site‐selective arylation of indoles at the C4 and C5 positions with the aid of a... 
regioselectivity | copper | palladium | indoles | arylation | ROOM-TEMPERATURE | DIAZONAMIDE-A | DIARYLIODONIUM SALTS | 2ND TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | MILD CONDITIONS | BOND ARYLATION | REGIOSELECTIVE SYNTHESIS | N-PIVALOYLINDOLES | CATALYZED DIRECT ARYLATION | Chemical synthesis | Palladium | Transformation | Indoles | Indole | Functional groups
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2019, Volume 60, Issue 20, pp. 1349 - 1352
A rhodium-catalyzed direct C–H sulfonamidation and amidation of C-7 position of indolines by simple and commercially available arylsulfonamides and... 
C–H amidation | N-arylsulfonamides | Rhodium-catalyzed | Indolines | SITE | C7-FUNCTIONALIZATION | CHEMISTRY, ORGANIC | OXIDATIVE ANNULATION | INDOLES | MILD | BONDS | N-PIVALOYLINDOLES | ARYL | ACCESS | C-H amidation | Rhodium
Journal Article
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 04/2018, Volume 360, Issue 8, pp. 1644 - 1649
A Cu(I)-catalyzed regioselective cross-dehydrogenative coupling of indoline with a variety aryl and alkyl carboxylic acids is described. The divergent process... 
ROOM-TEMPERATURE | C-H BOND | C-7 POSITION | Indole | 7-SUBSTITUTED INDOLES | EXPEDIENT SYNTHESIS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | DIRECT ACCESS | C-H functionalization | copper catalysis | acyloxylation | COUPLING REACTION | N-PIVALOYLINDOLES | CHEMISTRY, APPLIED | cross-dehydrogenative coupling | AROMATIC CARBOXYLIC-ACIDS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2017, Volume 359, Issue 10, pp. 1717 - 1724
An efficient cobalt(III)‐catalyzed C‐2‐selective indole C–H hydroarylation of acrolein, enones, and glyoxylates was achieved under mild reaction conditions.... 
positional selectivity | indoles | hydroarylation | C–H functionalization | cobalt(III) catalysis | ROOM-TEMPERATURE | ACTIVATION | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | CARBON-HYDROGEN BONDS | C-H functionalization | UNSATURATED-KETONES | FUNCTIONALIZATION | ALLYLIC ALCOHOLS | COBALT CATALYSIS | N-PIVALOYLINDOLES | CHEMISTRY, APPLIED | Ketones | Cobalt | Catalysis | Esters | Selectivity | Catalysts | Aldehydes
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 01/2019, Volume 2019, Issue 1, pp. 73 - 76
A palladium‐catalyzed protocol for the first direct diarylation of 6,7‐benzindoles with aryl iodides at the C4 and C5 positions was developed. The key to this... 
C–C coupling | Diarylation | 6,7‐Benzindole | C–H activation | Palladium | 6,7-Benzindole | C-C coupling | ACTIVATION | ALKYLATION | CHEMISTRY, ORGANIC | CYANATION | INDOLES | FUNCTIONALIZATION | MILD | FORMYLATION | C-H activation | OLEFINATION | N-PIVALOYLINDOLES | ACCESS
Journal Article
CHEMISTRY-AN ASIAN JOURNAL, ISSN 1861-4728, 10/2017, Volume 12, Issue 19, pp. 2634 - 2643
A highly efficient and regioselective Ir-III-catalyzed C-H amidation of 2-phenoxypyridines has been developed by using sulfonyl azides as an amino source. The... 
BOND AMIDATION | azides | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | iridium | MILD CONDITIONS | SULFONYL AZIDES | COUPLING REACTIONS | NITROGEN-SOURCE |