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Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 12, pp. 4763 - 4766
This paper describes the development of a new variant of stereoselective strain-release driven reactions (formal homo [3 + 2] dipolar cycloadditions) which... 
CHEMISTRY, ORGANIC | N-OXIDES
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2017, Volume 50, Issue 11, pp. 2799 - 2808
Conspectus Transition-metal-catalyzed cross-coupling has emerged as an effective strategy for chemical synthesis. Within this area, direct C–H bond... 
DENSITY | QUINOLINE N-OXIDES | RH(III) CATALYST | ACTIVATION | AMINATION | NITROGEN-SOURCE | DUAL ROLE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ATOM TRANSFER
Journal Article
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8787 - 8863
Transition metal-mediated C–H bond activation and functionalization represent one of the most straightforward and powerful tools in modern organic synthetic... 
TRACELESS DIRECTING GROUPS | HEXA-PERI-HEXABENZOCORONENES | AZINE N-OXIDES | 1ST TOTAL-SYNTHESIS | METALATION-DEPROTONATION MECHANISM | CARBON-HYDROGEN BONDS | ASYMMETRIC TOTAL-SYNTHESIS | SINGLE-ELECTRON TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | CATALYZED DIRECT ARYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 10, pp. 2518 - 2521
A synthetic method of a wide range of cinnolin-3(2H)-one derivatives is developed from the reaction of symmetrical as well as unsymmetrical azobenzenes with... 
C-H ACTIVATION/CYCLIZATION | CHEMISTRY, ORGANIC | N-OXIDES | CYCLIZATION | BONDS | CARBENOID FUNCTIONALIZATION
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2015, Volume 51, Issue 95, pp. 16928 - 16931
Copper-catalysed direct C-H bond sulfonylation of aminoquinolines using commercially available and inexpensive arylsulfonyl chlorides as the sulfonylation... 
PALLADIUM | DIRECT ARYLATION | ACIDS | UNSYMMETRICAL DIARYL SULFONES | ALKYLATION | BOND FUNCTIONALIZATION | ARYL | C(SP)-H | N-OXIDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 38, pp. 6961 - 6968
The preparation of chiral pool-derived nitrone 3 and its use in the protecting-group free, stereoselective synthesis of a range of 1,3-disubstituted... 
Stereoselectivity | Synthesis | Phenylalanine | Reagents | Oxides | N-Oxides
Journal Article
Organic Letters, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6086 - 6089
A simple and mild protocol for copper­(I)-mediated sulfonylation of 8-aminoquinoline amides with sulfonyl chlorides was developed, affording desired products... 
FUNCTIONALIZATION | ACID-DERIVATIVES | AMINATION | ACTIVATION | VINYL SULFONES | CHEMISTRY, ORGANIC | INHIBITORS | SINGLE-ELECTRON | N-OXIDES | C-H BONDS | ARYLSULFONYL CHLORIDES
Journal Article
Organic Letters, ISSN 1523-7060, 01/2016, Volume 18, Issue 2, pp. 192 - 195
The Rh­(III)-catalyzed regioselective C2–H bond carbenoid insertion/cyclization of N-amidoindoles with α-acyl diazo compounds has been developed. This method... 
REARRANGEMENT | ACTIVATION | INSERTION | BENZAMIDES | INTERMOLECULAR CARBENOID FUNCTIONALIZATION | TOSYLHYDRAZONES | CHEMISTRY, ORGANIC | H BOND FUNCTIONALIZATION | N-OXIDES | CATALYSTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 15, pp. 4908 - 4911
The first example of Rh­(III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular... 
FUNCTIONALIZATION | QUINOLINE N-OXIDES | PALLADIUM | CYCLOADDITION | AMINATION | NITRONES | BOND FORMATION | STEREOSELECTIVE-SYNTHESIS | ALKYNES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 10/2019, Volume 60, Issue 40
Pyridine- -oxides bearing a pharmacophoric oxadiazole moiety could be C H functionalized the acid-catalyzed reaction with dialkylcyanamides, providing access... 
Dialkylcyanamides | Ureas | C[sbnd]H activation | N-Oxides
Journal Article
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 13, pp. 4950 - 4954
A multicomponent sulfonylation of O-aryl oximes via iminyl radicals with the insertion of sulfur dioxide under photoredox catalysis is achieved. This... 
QUINOLINE N-OXIDES | 2-AZA-21-CARBAPORPHYRIN | NORCORROLE | METABISULFITE | CHEMISTRY | CHEMISTRY, ORGANIC | METAL | STEREOSELECTIVE-SYNTHESIS | DERIVATIVES | AMINOSULFONYLATION | CARBOXYLIC-ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2019, Volume 141, Issue 6, pp. 2274 - 2278
An eight-step asymmetric synthesis of (+)-marineosin A is described. The route proceeds by condensing fragments of reversed polarity relative to conventional... 
N-OXIDES | MARINEOSINS | CHEMISTRY, MULTIDISCIPLINARY | HYDRATION | STEPS
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8649 - 8709
Computational studies on carboxylate-assisted C–H activation and functionalization at group 8–10 transition metal centers are reviewed. This Review is... 
QUINOLINE N-OXIDES | C(SP)-H ACTIVATION | CATALYZED INTRAMOLECULAR ARYLATION | AMINO-ACID LIGANDS | BOND ACTIVATION | NONCOVALENT INTERACTIONS | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY | PROTON-ABSTRACTION MECHANISM | ASTERISK-IR | ACTIVATION/CYCLOADDITION REACTIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2015, Volume 137, Issue 42, pp. 13448 - 13451
A complete switch in the Cp*Ir­(III)-catalyzed paths between C–H olefination and hydroarylation was found to be crucially dependent on the type of directing... 
FUNCTIONALIZATION | MILD | ACTIVATION | DIRECT ARYLATION | PYRIDINE-N-OXIDES | AROMATIC AMIDES | ALKYLATION | COUPLING REACTION | RUTHENIUM | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9302 - 9332
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 01/2019, Volume 17, Issue 2, pp. 363 - 368
A novel and efficient protocol concerning palladium catalyzing the three-component reaction of 2-azidobenzaldehyde, isocyanide, and hydroxylamine hydrochloride... 
TANDEM CATALYSIS | 3-OXIDES | ANNULATION | SCOPE | CHEMISTRY, ORGANIC | N-OXIDES | BOND
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 09/2017, Volume 58, Issue 39, pp. 3772 - 3776
An expeditious, one-pot and room temperature protocol is reported for the synthesis of 2-chloroimidazoles from imidazole -oxide. Simple mixing of the imidazole... 
Imidazole N-oxides | 2-Chloroimidazole | Oxalyl chloride | CHEMISTRY, ORGANIC | Oxides
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 03/2016, Volume 45, Issue 6, pp. 1720 - 1737
Molecular containers have attracted the interest of supramolecular chemists since the early beginnings of the field. Cavitands' inner cavities were quickly... 
O-BENZYNE | ASSEMBLED COORDINATION CAGE | INNER PHASE | CAPSULE | RADICAL-CATION STABILIZATION | HOST | N-OXIDES | CHEMISTRY, MULTIDISCIPLINARY | ROOM-TEMPERATURE STABILIZATION | MOLECULAR CONTAINERS | CARBOXYLIC-ACIDS
Journal Article
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