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Advanced Materials, ISSN 0935-9648, 07/2014, Volume 26, Issue 26, pp. 4565 - 4568
Radiosensitizers can increase local treatment efficacy under a relatively low and safe radiation dose, thereby facilitating tumor eradication and minimizing... 
radiotherapy | tumor uptake | gold nanomolecules | gold nanoclusters | radiosensitization
Journal Article
by Song, YB and Wang, SX and Zhang, J and Kang, X and Chen, S and Li, P and Sheng, HT and Zhu, MZ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 2963 - 2965
We report the X-ray structure of a selenolate-capped Au-24(SeR)(20) nanocluster (R = C6H5). It exhibits a prolate Au-8 kernel, which can be viewed as two... 
CORE | NANOPARTICLES | THIOLATE | GOLD NANOCLUSTERS | STABILITY | NANOMOLECULES | AU-130 | CLUSTER | MOTIF | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Das, A and Li, T and Nobusada, K and Zeng, CJ and Rosi, NL and Jin, RC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18264 - 18267
We report the X-ray structure of a cyclohexanethiolate-capped [Au-23(SR)(16)](-) nanocluster (counterion: tetraoctylammonium, TOA(+)). The structure comprises... 
CORE | ELECTRONIC-PROPERTIES | NANOPARTICLES | ORIGIN | GOLD-CLUSTER | CRYSTAL-STRUCTURE | STABILITY | OPTICAL-PROPERTIES | NANOMOLECULES | CHEMISTRY, MULTIDISCIPLINARY | PROTECTED AU-25
Journal Article
by Wang, SX and Meng, XM and Das, A and Li, T and Song, YB and Cao, TT and Zhu, XY and Zhu, MZ and Jin, RC
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 02/2014, Volume 53, Issue 9, pp. 2376 - 2380
The rod-shaped Au-25 nanocluster possesses a low photoluminescence quantum yield (QY=0.1%) and hence is not of practical use in bioimaging and related... 
ALLOY NANOMOLECULES | photoluminescence | NANOCRYSTALS | doping | metal nanoclusters | CHEMISTRY, MULTIDISCIPLINARY | gold | FLUORESCENCE | LIGANDS | GLUTATHIONE | CARBON NANODOTS | AU-25 CLUSTERS | silver | EMISSION | LUMINESCENT GOLD NANOPARTICLES
Journal Article
Journal of Physical Chemistry Letters, 02/2014, Volume 5, Issue 3, pp. 461 - 466
Journal Article
Nature Communications, ISSN 2041-1723, 03/2017, Volume 8, Issue 1, p. 14739
Metal nanoclusters have recently attracted extensive interest not only for fundamental scientific research, but also for practical applications. For... 
TRANSITION | NANOPARTICLES | PHASE | ELECTROCATALYTIC PROPERTIES | CLUSTERS | MULTIDISCIPLINARY SCIENCES | NANOCRYSTALS | SIZE | NANOMOLECULES | NANOSTRUCTURES | THEORETICAL-ANALYSIS
Journal Article
Journal of Physical Chemistry Letters, ISSN 1948-7185, 10/2013, Volume 4, Issue 19, pp. 3351 - 3355
Selenolate protected, stable and atomically precise, hollow silver cluster was synthesized using solid state as well as solution state routes. The optical... 
superatoms | MALDI MS | selenolate | silver clusters | ESI MS | nanomolecules | TDDFT
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2015, Volume 137, Issue 12, pp. 4018 - 4021
A metal exchange method based upon atomically precise gold nanoclusters (NCs) as templates is devised to obtain alloy NCs including CuxAu25-x(SR)(18),... 
NANOPARTICLES | PROTECTED GOLD | FLUORESCENCE | CRYSTAL-STRUCTURE | GOLD-NANOCLUSTERS | NANOMOLECULES | ANTI-GALVANIC REDUCTION | LUMINESCENT GOLD(I)-SILVER(I) CLUSTER | SUPERATOMS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 01/2013, Volume 135, Issue 1, pp. 26 - 29
A bimetallic ligand-protected cluster, Ag4Ni2(DMSA)(4) (DMSA = meso-2,3-climercaptosuccinic acid) was synthesized and characterized through electrospray... 
LIGANDS | GOLD NANOCLUSTERS | COMPLEXES | NANOMOLECULES | IONS | CLUSTER | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 02/2016, Volume 55, Issue 3, pp. 999 - 1001
The single-crystal X-ray structure of Pd-doped Au-25(SR)(18) was solved. The crystal structure reveals that in PdAu24(SR)(18), the Pd atom is localized only to... 
NANOCLUSTERS | AU-25(SR) | PROTECTED AU-25 CLUSTER | OPTICAL-PROPERTIES | NANOMOLECULES | GOLD NANOPARTICLE | AU-144(SR) | ALLOY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2015, Volume 137, Issue 30, pp. 9511 - 9514
Controlling the bimetal nanoparticle with atomic mono dispersity is still challenging. Herein, a monodisperse bimetal nanoparticle is synthesized in 25% yield... 
ALLOY NANOMOLECULES | OXYGEN REDUCTION | PROTECTED GOLD | GOLD NANOCLUSTERS | GALVANIC REPLACEMENT REACTION | OPTICAL-PROPERTIES | AG NANOCUBES | CLUSTER | CHEMISTRY, MULTIDISCIPLINARY | SILVER NANOPARTICLES | ELECTRONIC-STRUCTURE
Journal Article
by Yao, CH and Lin, YJ and Yuan, JY and Liao, LW and Zhu, M and Weng, LH and Yang, JL and Wu, ZK
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2015, Volume 137, Issue 49, pp. 15350 - 15353
Controlling the dopant type, number, and position in doped metal nanoclusters (nanoparticles) is crucial but challenging. In the work described herein, we... 
ALLOY NANOMOLECULES | PROTECTED GOLD | GOLD NANOCLUSTERS | ANTI-GALVANIC REDUCTION | OXYGEN REDUCTION REACTION | ATOMIC PRECISION | CHEMISTRY, MULTIDISCIPLINARY | SILVER NANOPARTICLES | CHARGE-STATE | RAY CRYSTAL-STRUCTURE | ELECTRONIC-STRUCTURE
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, ISSN 1948-7185, 02/2014, Volume 5, Issue 3, pp. 461 - 466
The atomic arrangement of Au and Ag atoms in Au25-xAgx(SR)(18) was determined by X-ray crystallography. Ag atoms were selectively incorporated in the 12... 
NANOCLUSTERS | NANOPARTICLES | CLUSTERS | MATERIALS SCIENCE, MULTIDISCIPLINARY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | NANOMOLECULES | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | OPTICAL-ABSORPTION SPECTRA | PROTECTED AU-25 | ELECTRONIC-STRUCTURE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 3, pp. 1206 - 1212
We report on how the transition from the bulk structure to the cluster-specific structure occurs in n-dodecanethiolate-protected gold clusters, Aun(SC12)(m).... 
GOLD NANOPARTICLES | NANOCLUSTERS | THIOLATE | AU-25 CLUSTER | NANOMOLECULES | OPTICAL SPECTROSCOPY | SURFACE-PLASMON RESONANCE | THEORETICAL-ANALYSIS | CHEMISTRY, MULTIDISCIPLINARY | MASS-SPECTROMETRY | RAY CRYSTAL-STRUCTURE | Gold compounds | Chemical properties | Structure | Chemical synthesis | Analysis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 11/2017, Volume 139, Issue 43, pp. 15450 - 15459
We report the discovery of an unprecedentedly large, 2.2 nm diameter, thiolate protected gold nanocrystal characterized by single crystal X-ray crystallography... 
CRITICAL SIZE | NANOPARTICLES | ATOMIC-STRUCTURE | METAL NANOCLUSTERS | OPTICAL-PROPERTIES | NANOMOLECULES | QUANTUM CONFINEMENT | MONOLAYER | CHEMISTRY, MULTIDISCIPLINARY | MASS-SPECTROMETRY | PROTECTED GOLD CLUSTERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2013, Volume 135, Issue 27, pp. 10011 - 10013
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 04/2014, Volume 5
Absorption spectra of very small metal clusters exhibit individual peaks that reflect the discreteness of their localized electronic states. With increasing... 
NANOPARTICLES | TEMPERATURE | CRYSTAL-STRUCTURE | MULTIDISCIPLINARY SCIENCES | SIZE | NANOMOLECULES | TIME | SURFACE-PLASMON RESONANCE | OPTICAL-ABSORPTION SPECTRA | METAL-CLUSTERS | PROTECTED AU-25
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2018, Volume 51, Issue 11, pp. 2739 - 2747
Understanding special stability of numerous ligand-protected gold nanoclusters has always been an active area of research. In the past few decades, several... 
NANOPARTICLES | EVOLUTION | CLUSTERS | AU-38 | CRYSTAL-STRUCTURE | SIZE | NANOMOLECULES | STRUCTURAL-CHARACTERIZATION | METAL | CHEMISTRY, MULTIDISCIPLINARY | STRUCTURE PREDICTION
Journal Article
Chemistry of Materials, ISSN 0897-4756, 06/2015, Volume 27, Issue 12, pp. 4289 - 4297
The properties of atomically monodisperse noble metal nanoclusters (NCs) are intricately intertwined with their precise molecular formula. The vast majority of... 
AG NANOCLUSTERS | NANOPARTICLES | AU-25(SR) | FLUORESCENT GOLD NANOCLUSTERS | MATERIALS SCIENCE, MULTIDISCIPLINARY | NANOCRYSTALS | AU-25 CLUSTERS | NANOMOLECULES | CHEMISTRY, PHYSICAL | METAL-CLUSTERS | TOF MASS-SPECTROMETRY | DIRECTED SYNTHESIS
Journal Article
by Liao, LW and Yao, CH and Wang, CM and Tian, SB and Chen, JS and Li, MB and Xia, N and Yan, N and Wu, ZK
ANALYTICAL CHEMISTRY, ISSN 0003-2700, 12/2016, Volume 88, Issue 23, pp. 11297 - 11301
"Size-focusing" is a well-recognized process and widely employed for the synthesis of atomically monodisperse metal nanoclusters. However, quantitatively... 
EXCLUSION CHROMATOGRAPHY | NANOPARTICLES | CHEMISTRY, ANALYTICAL | EVOLUTION | LIQUID-CHROMATOGRAPHY | GROWTH | LIGAND-EXCHANGE | NANOMOLECULES | SEPARATION | PROTECTED GOLD CLUSTERS | NOBLE-METAL CLUSTERS
Journal Article
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