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Synlett, ISSN 0936-5214, 05/2016, Volume 27, Issue 8, pp. 1274 - 1276
Abstract A method for the nucleophilic displacement of the triflate leaving group attached to terminally functionalized alkyl groups with nucleophilic silicon... 
letter | chemoselectivity | copper | silicon | nucleophilic substitution | transmetalation
Journal Article
Synthesis, ISSN 0039-7881, 08/2011, Volume 2011, Issue 15, pp. 2341 - 2356
Abstract Basic concepts, mechanistic principles and the broad application of nucleophilic substitution of hydrogen in nitroarenes and other electron-deficient... 
review | electron-deficient arenes | oxidative nucleophilic substitution | mechanism | vicarious nucleophilic substitution | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology
Journal Article
Physical chemistry chemical physics : PCCP, ISSN 1463-9076, 2019, Volume 21, Issue 15, pp. 7924 - 7931
Moving beyond the textbook mechanisms of bimolecular nucleophilic substitution (SN2) reactions, we characterize several novel stationary points and pathways... 
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 04/2019, Volume 361, Issue 7, pp. 1641 - 1646
Benzyl chloride and its derivatives are efficiently deprotonated with strong bases to form α‐chlorocarbanions. These anions are long‐lived enough to enter VNS... 
Umpolung | Benzylation | VNS | Aromatic substitution | Nucleophilic substitution | Transition metal compounds | Transition metals | Selectivity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2018, Volume 57, Issue 24, pp. 7176 - 7180
Stereospecific nucleophilic substitution was achieved for the first time with arylboronic acids as nucleophiles. This transition‐metal‐free coupling between... 
enantioselectivity | arylboronic acids | α,α-diaryl acetamides | nucleophilic substitution | stereospecificity | Antidepressants | Substitution reactions | Cannabinoid CB1 receptors | Acids | Enantiomers | Nucleophiles | Aromatic compounds
Journal Article
Synthesis (Stuttgart), ISSN 0039-7881, 05/2016, Volume 48, Issue 18, pp. 3134 - 3140
Abstract The coupling reaction between N-substituted ( E )-hex-2-en-ylidene hydrazinecarbothioamides and 2,3-dichloro-1,4-naphthoquinone affords substituted... 
paper | naphthoquinones | nucleophilic substitution | naphthothiazoles | naphthothiadiazepines
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 35, pp. 12201 - 12201
Despite 75 years having passed since its discovery, the heaviest halogen and one of the rarest of all elements, astatine, apparently still has surprises in... 
radiopharmaceuticals | iodonium salts | halogenation | astatine | nucleophilic substitution
Journal Article
Pure and Applied Chemistry, ISSN 0033-4545, 01/2019, Volume 91, Issue 1, pp. 43 - 57
Nucleophilic and electrophilic substitutions are the most often applied reactions in organophosphorus chemistry. They are closely interrelated, because in a... 
stereochemistry | ICPC-22 | nucleophilic substitution | electrophilic substitution | halogenophilic reactions | Substitutes | Organic chemistry | Phosphorus | Stereochemistry | Configurations | Reagents
Journal Article
Synlett, ISSN 0936-5214, 01/2010, Volume 2010, Issue 1, pp. 119 - 122
Abstract A new enantioselective Brønsted acid catalyzed nucleophilic substitution of γ-hydroxylactams with indole is presented. The reaction proceeds via an... 
letter | Protonation | Amino acid | Quaternary stereocenter | Nucleophilic substitution | Organocatalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2019, Volume 58, Issue 19, pp. 6440 - 6443
Robust procedures for two mechanistically distinct C(sp3)−Ge bond formations from alkyl electrophiles and germanium nucleophiles are reported. The germanium... 
magnesium | germanium | radical cross-coupling | nucleophilic substitution | zinc | Chemical tests and reagents | Olefins | Regioselectivity | Reagents | Bromides | Germanium | Lithium | Nickel | Magnesium | Coupling | Nucleophiles | Zinc
Journal Article
Synthesis, ISSN 0039-7881, 01/2019, Volume 51, Issue 2, pp. 530 - 537
Abstract A convenient two-step, one-pot synthesis of 4-chloro-2-(trichloromethyl)pyrimidines starting from 2-(trichloromethyl)-1,3-diazabutadienes is... 
paper | cycloaddition reaction | intramolecular cyclization | nucleophilic substitution | tetrachloropyrimidines | 1,3-diazadienes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2018, Volume 57, Issue 1, pp. 292 - 295
The first example of a direct dehydroxytrifluoromethoxylation of alcohols has been developed. This method generated an alkyl fluoroformate in situ from... 
alcohols | trifluoromethoxylation | nucleophilic substitution | trifluoromethyl arylsulfonate | synthetic methods | Ethers | Alcohol | Alcohols
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 08/2014, Volume 20, Issue 32, pp. 9867 - 9870
A direct process for the trifluoromethylthiolation of allylic and benzylic alcohols under mild conditions has been developed. A wide range of free alcohols... 
alcohols | trifluoromethyl sulfenylation | nucleophilic substitution | thioethers
Journal Article
Synthesis, ISSN 0039-7881, 11/2018, Volume 50, Issue 21, pp. 4301 - 4312
Abstract Complex semicarbazone derivatives were successfully synthesized from substituted semicarbazides in acidic ethanol upon heating in the presence of... 
paper | semicarbazones | substituted semicarbazides | hydrazine | nucleophilic substitution reaction | acid hydrazide
Journal Article
Tetrahedron, ISSN 0040-4020, 05/2008, Volume 64, Issue 20, pp. 4511 - 4574
This review is intended to update the impressive amount of developments in the synthesis of cyclic compounds from the Baylis–Hillman chemistry covering the... 
Heterocycles | Baylis–Hillman reaction | Nucleophilic substitution | Cyclic compounds | Baylis-Hillman reaction | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology | Chemical tests and reagents | Glycol ethers
Journal Article