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International Journal of Quantum Chemistry, ISSN 0020-7608, 02/2020, Volume 120, Issue 3, p. n/a
The von Braun reaction, discovered at the dawn of the past century, consists of the reaction between a tertiary amine and cyanogen bromide. It leads to the... 
strained heterocycles | multibonded bromine atom | electrocyclic reactions | nucleophilic substitution | DFT‐calculations | Chemical Sciences
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 02/2020, Volume 41, Issue 4, pp. 317 - 327
We have computationally studied the bimolecular nucleophilic substitution (SN2) reactions of MnNH2(n−1) + CH3Cl (M+ = Li+, Na+, K+, and MgCl+; n = 0, 1) in the... 
solvent effects | amide | nucleophilic substitution | ion‐pair SN2 | DFT calculations | activation strain model
Journal Article
by Li, J and Hu, MY and Pei, HC and Ma, XH and Yan, F and Dlamini, DS and Cui, ZY and He, BQ and Li, JX and Matsuyama, H
JOURNAL OF MEMBRANE SCIENCE, ISSN 0376-7388, 02/2020, Volume 595, p. 117547
Polysulfone (PSf)-grafted graphene oxide (GO) nanosheets (GO-g-PSf) were synthesized via a nucleophilic substitution reaction between hydroxyl groups of GO and... 
Dye separation | POLYMER SCIENCE | Graphene oxide (GO) | FILM | 2-DIMENSIONAL MATERIALS | NANOSHEETS | FUNCTIONALIZATION | ENGINEERING, CHEMICAL | TRANSPORT | DEHYDRATION | Polysulfone (PSf) | Nucleophilic substitution | NANOFILTRATION MEMBRANE | GO-Based membrane
Journal Article
by Yang, XH and Li, DS and Zhai, J and Wang, F and Xue, B and Zhu, J and Li, YX
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, ISSN 0927-7757, 01/2020, Volume 585, p. 124138
In this contribution, Pickering emulsion system was prepared by bi-functional graphene oxide (GO) grafted with polyethylene glycol (PEG) and... 
3-Aminopropyltrimethoxysilane | Pickering emulsion | Polyethylene glycol | PERFORMANCE | PHASE-TRANSFER CATALYST | CHEMISTRY, PHYSICAL | Graphene oxide | Nucleophilic substitution | POLYETHYLENE-GLYCOL | BIPHASIC SYSTEMS | WALLED CARBON NANOTUBES
Journal Article
Electrochimica Acta, ISSN 0013-4686, 01/2020, Volume 330, p. 135253
Lithium-sulphur (Li–S) batteries are promising energy storage systems, but it suffers from several limitations mainly due to the electrolytes. In this study,... 
Lithium-sulphur batteries | Organic sulphides | High capacity | Catholyte | SOLID-ELECTROLYTE | ELECTROCHEMISTRY | SCISSION | NUCLEOPHILIC-SUBSTITUTION | THIOLATE IONS | DISULFIDE | SHUTTLE | ACYL CHLORIDES | ENHANCED PERFORMANCE | LITHIUM-SULFUR BATTERIES | ANODE
Journal Article
Phosphorus, Sulfur, and Silicon and the Related Elements, ISSN 1042-6507, 01/2020, Volume 195, Issue 1, pp. 29 - 36
Several bis(N'-arylpropanehydrazonoyl chlorides) were synthesized in good yields from condensation reactions of hydrazonoyl chlorides and phosphonic... 
X-ray crystallography | bis(N'-arylpropanehydrazonoyl chlorides) | azines | nucleophilic substitution reaction | Phosphonic dihydrazide | heterocycles
Journal Article
Theoretical Chemistry Accounts, ISSN 1432-881X, 1/2020, Volume 139, Issue 1, pp. 1 - 14
Journal Article
Journal of Inorganic Biochemistry, ISSN 0162-0134, 01/2020, Volume 202, p. 110857
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 01/2020, Volume 402, p. 213052
Journal Article
Synthesis, ISSN 0039-7881, 12/2019, Volume 51, Issue 24, pp. 4582 - 4589
Abstract A simple gram-scale method for the preparation of esters and dialkylamides of 2-(fluoro/iodo)-2 H -azirine-2-carboxylic acids via the halogen exchange... 
paper | nucleophilic- substitution | 2H-AZIRINES | halogen exchange reaction | ISOMERIZATION | CHEMISTRY, ORGANIC | FLUORINATION | 2-HALO-2H-AZIRINES | ISOXAZOLES | HALOGEN EXCHANGE | I-124 | CHEMISTRY | iodine | azirines | fluorine
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2019, Volume 21, Issue 23, pp. 9320 - 9325
Nitronaphthalene derivatives react as Michael acceptors in the Corey-Chaykovsky reaction with alkyl phenyl selenones and alkyl diphenyl sulfonium salts.... 
VICARIOUS NUCLEOPHILIC-SUBSTITUTION | NITROARENES | HYDROGEN | METHYLATION | CHEMISTRY, ORGANIC | ORGANIC-ANIONS | 3-NITROINDOLES | DIMETHYLSULFONIUM METHYLIDE | 3+2 CYCLOADDITION | TRANSFORMATIONS | DEAROMATIZATION
Journal Article
Electrochimica Acta, ISSN 0013-4686, 12/2019, Volume 326, p. 134990
The electrochemical reduction of 9 substituted aryl-5 -dibenzo[b,i]xanthene-5,7,12,14(13 )-tetraones ( ) and 10 substituted... 
Cyclic voltammetry | Electrochemical reduction | Hammett equation | Dibenzo-xanthene derivatives | Diffusion coefficient | OXIDATION | ELECTROSYNTHESIS | ELECTROCHEMISTRY | ACID | MECHANISM | NUCLEOPHILIC-SUBSTITUTION | BENZOFURAN | RESONANCE | 1,4-QUINONES
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 12/2019, Volume 58, Issue 23, pp. 15769 - 15787
Herein we report the synthesis of 5,10,15,20-tetraaryl-(X)-substituted-2,3,7,8,12,13,17,18-octaethylporphyrins (OETArXPs) and a structural investigation of... 
PERIPHERAL SUBSTITUTION | STERICALLY STRAINED PORPHYRINS | NUCLEOPHILIC-SUBSTITUTION | NONPLANAR DISTORTION | TETRAPHENYLPORPHYRINS | MACROCYCLE | CHEMISTRY | STRUCTURAL-CHARACTERIZATION | METAL-COMPLEXES | ARCHITECTURES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 06/2019, Volume 10, Issue 1, pp. 2786 - 10
Journal Article
CHEMICAL & PHARMACEUTICAL BULLETIN, ISSN 0009-2363, 12/2019, Volume 67, Issue 12, pp. 1259 - 1270
The biary unit having heteroatom as important scaffolds widely exist in a large number of biologically active compounds and functional organic molecules. Since... 
ROOM-TEMPERATURE | ORGANIC-SYNTHESIS | CHEMISTRY, MEDICINAL | NATURAL-PRODUCTS | NUCLEOPHILIC-SUBSTITUTION | PHENOL-ARENE | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | PHENYLIODINE BIS(TRIFLUOROACETATE) | hypervalent iodine(III) | C-H ARYLATION | cross-coupling | heteroatom | SELECTIVE ARYLATION | PHARMACOLOGY & PHARMACY | HYPERVALENT IODINE REAGENTS
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 08/2019, Volume 10, Issue 1, pp. 3826 - 9
Optically pure alcohols are abundant in nature and attractive as feedstock for organic synthesis but challenging for further transformation using atom... 
AMINATION | ALLYLIC ALCOHOLS | AMINES | ALKYLATION | MULTIDISCIPLINARY SCIENCES | NUCLEOPHILIC-SUBSTITUTION | MECHANISMS | SOLVOLYSES | EFFICIENCY | Agricultural chemicals | Transformation | Catalysts | Alcohol | Iron | Glucose | Alcohols | Substitutes | Agrochemicals | Aromatic compounds | Heterocyclic compounds | Sustainability | Chirality | Catalysis | Nucleophiles | Naturvetenskap | Natural Sciences | Kemi | Chemical Sciences
Journal Article
The Canadian Journal of Chemical Engineering, ISSN 0008-4034, 12/2019, Volume 97, Issue 12, pp. 3012 - 3024
This work focused on the preparation and characterization of cysteine‐formaldehyde cross‐linked complex derived from cysteine hydrochloride and formaldehyde.... 
nucleophilic substitution | molecular simulation | thiazolidine‐carboxylic acid | CO2 adsorption | Pyrolysis | Cysteine | Nuclear magnetic resonance--NMR | Crystal surfaces | Carbon dioxide | Crystals | Nitrogen atoms | Substitution reactions | Formaldehyde | Covalent bonds | Dehydrogenation | Morphology | Breakage | Carbon capture and storage | Crystal structure | Carbonyls
Journal Article