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1. Analytical chemistry of neptunium
by Mikhailov, ValeriÄ­ Alekseevich
1973, Analytical chemistry of the elements., ISBN 9780470603000, vii, 235
Neptunium | Analysis
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2. Full Text Actinide sulfides in the gas phase: Experimental and theoretical studies of the thermochemistry of AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm)
by Pereira, Cláudia C. L and Marsden, Colin J and Marçalo, Joaquim and Gibson, John K
Physical Chemistry Chemical Physics, ISSN 1463-9076, 07/2011, Volume 13, Issue 28, pp. 12940 - 12958
The gas-phase thermochemistry of actinide monosulfides, AnS, was investigated experimentally and theoretically. Fourier transform ion cyclotron resonance mass... 
INFRARED-SPECTRA | DIPOLE-MOMENT | CORRELATED MOLECULAR CALCULATIONS | TRANSITION-METAL | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | GUIDED ION-BEAM | CHEMISTRY, PHYSICAL | DISSOCIATION-ENERGIES | QUASI-RELATIVISTIC DFT | ROOM-TEMPERATURE KINETICS | GAUSSIAN-BASIS SETS | EXCITED-STATES | Carbon Dioxide - chemistry | Oxidants - chemistry | Oxides - chemistry | Uranium Compounds - chemistry | Sulfides - chemistry | Actinoid Series Elements - chemistry | Protactinium - chemistry | Alkadienes - chemistry | Gases - chemistry | Thermodynamics | Algorithms | Fourier Analysis | Thorium Compounds - chemistry | Actinium - chemistry | Carbon Disulfide - chemistry | Sulfur Oxides - chemistry | Curium - chemistry | Neptunium - chemistry | Plutonium - chemistry | Americium - chemistry | Mass Spectrometry - methods | Cations, Monovalent - chemistry | Actinides | Ionization | Plutonium | Energy of dissociation | Bonding | Dissociation energy | Heat of formation | Free energy | Chemical Sciences | Other
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3. Full Text A Quasi-relativistic Density Functional Theory Study of the Actinyl(VI, V) (An = U, Np, Pu) Complexes with a Six-Membered Macrocycle Containing Pyrrole, Pyridine, and Furan Subunits
by Lan, Jian-Hui and Wang, Cong-Zhi and Wu, Qun-Yan and Wang, Shu-Ao and Feng, Yi-Xiao and Zhao, Yu-Liang and Chai, Zhi-Fang and Shi, Wei-Qun
Journal of Physical Chemistry A, ISSN 1089-5639, 08/2015, Volume 119, Issue 34, pp. 9178 - 9188
Actinyl(VI, V) (An = U, Np and Pu) complexes of the recently reported hybrid macrocycle, cyclo[1]furan[1]pyridine[4]pyrrole (denoted as H4L), have been studied... 
CALIXARENE | NEPTUNYL | CROWN-ETHER COMPLEXES | EXPANDED PORPHYRIN | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | X-RAY | CHEMISTRY | CHEMISTRY, PHYSICAL | URANYL COMPLEX | ACTINIDE ELEMENTS | ELECTRON LOCALIZATION | CATIONS | Macrocyclic Compounds - chemistry | Pyridines - chemistry | Solvents - chemistry | Molecular Conformation | Models, Molecular | Quantum Theory | Furans - chemistry | Neptunium - chemistry | Water - chemistry | Pyrroles - chemistry | Ligands | Organometallic Compounds - chemistry | Plutonium - chemistry | Uranium - chemistry | Methylene Chloride - chemistry | Electrons | Density functionals | Actinide elements | Usage | Research | Chemical properties | Pyrrole | Pyridines | Macrocyclic compounds | Pyrroles | Density functional theory | Formations | Cations | Selectivity | Plutonium | Density
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4. Organometallic Neptunium Chemistry
by Polly L Arnold and Michal S Dutkiewicz and Olaf Walter
Chemical Reviews, ISSN 0009-2665, 09/2017, Volume 117, Issue 17, p. 11460
Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet only a handful of complexes have been reported, and even fewer have... 
Radioactive materials | Chemistry | Uranium | Radiochemical analysis | Metals | Chemical bonds | Ligands | Plutonium | Chemical elements | Neptunium | Bonding | Radioactivity
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5. Full Text Recent progress in actinide borate chemistry
by Wang, Shuao and Alekseev, Evgeny V and Depmeier, Wulf and Albrecht-Schmitt, Thomas E and Materials Science of Actinides (MSA) and Energy Frontier Research Centers (EFRC)
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 39, pp. 10874 - 10885
The use of molten boric acid as a reactive flux for synthesizing actinide borates has been developed in the past two years providing access to a remarkable... 
URANIUM | POLYHEDRON GEOMETRIES | HELLANDITE-GROUP | NUCLEAR-WASTE | PLUTONIUM | CRYSTAL-STRUCTURE | CATIONIC FRAMEWORK | NEPTUNIUM | BOND-VALENCE PARAMETERS | THORIUM BORATE | CHEMISTRY, MULTIDISCIPLINARY | nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly) | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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6. Full Text Sorption coefficients and molecular mechanisms of Pu, U, Np, Am and Tc to Fe (hydr)oxides: A review
by Li, Dien and Kaplan, Daniel I
Journal of Hazardous Materials, ISSN 0304-3894, 12/2012, Volume 243, pp. 1 - 18
â–º data of Pu, U, Np, Am and Tc onto Fe (hydr)oxides under different conditions. â–º Molecular-level speciation of Pu, U, Np, and Am sorbed onto Fe (hydr)oxides.... 
Sorption | Radionuclides | Distribution coefficient | Fe (hydr)oxides | Molecular mechanisms | HYDROUS FERRIC-OXIDE | HEMATITE ALPHA-FE2O3 | CORROSION PRODUCTS | IRON-OXIDES | ENVIRONMENTAL SCIENCES | ENGINEERING, ENVIRONMENTAL | REACTIVE TRANSPORT | SURFACE COMPLEXATION | URANIUM(VI) ADSORPTION | GOETHITE ALPHA-FEOOH | NEPTUNIUM(V) SORPTION | HUMIC-ACID | Hydroxides - chemistry | Iron - chemistry | Ferric Compounds - chemistry | Plutonium - isolation & purification | Soil - analysis | Radioactive Waste | Americium - isolation & purification | Elements, Radioactive - chemistry | Neptunium - isolation & purification | Ferric Compounds - isolation & purification | Neptunium - chemistry | Hydroxides - isolation & purification | Plutonium - chemistry | Uranium - chemistry | Uranium - isolation & purification | Americium - chemistry | Elements, Radioactive - isolation & purification | Technetium - chemistry | Technetium - isolation & purification | Oxides | Humic acid | Index Medicus
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7. Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding
by Dutkiewicz, Michal S and Apostolidis, Christos and Walter, Olaf and Arnold, Polly L
Chemical Science, ISSN 2041-6520, 03/2017, Volume 8, Issue 4, pp. 2553 - 2561
Neptunium complexes in the formal oxidation states II, III, and IV supported by cyclopentadienyl ligands are explored, and significant differences between Np... 
Reduction | Valence | Actinides | Ligands | Derivatives | Neptunium | Adducts | Crystal structure
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8. Full Text Reevaluation of Neptunium–Nitric Acid Radiation Chemistry by Multiscale Modeling
by Horne, G. P and Grimes, T. S and Mincher, B. J and Mezyk, S. P and Idaho National Lab. (INL), Idaho Falls, ID (United States)
The Journal of Physical Chemistry B, ISSN 1520-6106, 12/2016, Volume 120, Issue 49, pp. 12643 - 12649
Multiscale modeling has been used to quantitatively reevaluate the radiation chemistry of neptunium in a range of aerated nitric acid solutions (0.1–6.0 mol... 
TBP EXTRACTION SYSTEM | MECHANISM | CATALYZED OXIDATION | PULSE-RADIOLYSIS | ELECTRONS | KINETICS | GAMMA-RADIOLYSIS | EQUILIBRIUM | CHEMISTRY, PHYSICAL | SIMULATION | AQUEOUS-SOLUTION | Radiation chemistry | Usage | Research | Chemical properties | Aqueous solution reactions | Nitric acid | free radicals | neptunium | fuel cycle | radiation chemistry | NUCLEAR FUEL CYCLE AND FUEL MATERIALS
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9. Crystal chemistry of simple compounds of uranium, thorium, plutonium, neptunium
by Makarov, E. S
1959, 145
Actinide elements
Book
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10. Full Text Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates
by Wang, Shuao and Villa, Eric M and Diwu, Juan and Alekseev, Evgeny V and Depmeier, Wulf and Albrecht-Schmitt, Thomas E and Materials Science of Actinides (MSA) and Energy Frontier Research Centers (EFRC)
Inorganic Chemistry, ISSN 0020-1669, 03/2011, Volume 50, Issue 6, pp. 2527 - 2533
U(VI), Np(VI), and Pu(VI) borates with the formula AnO2[B8O11(OH)4] (An = U, Np, Pu) have been prepared via the reactions of U(VI) nitrate, Np(VI) perchlorate,... 
NUCLEAR-WASTE | URANYL | NEPTUNYL | MINERALS | STABILITY | STRUCTURAL-CHARACTERIZATION | CATIONIC FRAMEWORK | BOND-VALENCE PARAMETERS | CRYSTAL-CHEMISTRY | INSIGHTS | CHEMISTRY, INORGANIC & NUCLEAR | Neptunium - chemistry | Models, Molecular | Crystallography, X-Ray | Plutonium - chemistry | Anions - chemistry | Uranium - chemistry | Borates - chemistry | nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly) | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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11. Full Text Aqueous Complexation of Thorium(IV), Uranium(IV), Neptunium(IV), Plutonium(III/IV), and Cerium(III/IV) with DTPA
by Brown, M. Alex and Paulenova, Alena and Gelis, Artem V
Inorganic Chemistry, ISSN 0020-1669, 07/2012, Volume 51, Issue 14, pp. 7741 - 7748
Aqueous complexation of Th(IV), U(IV), Np(IV), Pu(III/IV), and Ce(III/IV) with DTPA was studied by potentiometry, absorption spectrophotometry, and cyclic... 
EXTRACTION | EQUILIBRIUM-CONSTANTS | LANTHANIDE(III) | DECORPORATION | SPECIATION | STABILITY | AMINOPOLYACETIC ACIDS | ACTINIDES | EXCHANGE | IONIZATION MASS-SPECTROMETRY | CHEMISTRY, INORGANIC & NUCLEAR | Thermodynamics | Pentetic Acid - chemistry | Thorium - chemistry | Electrochemical Techniques | Cerium - chemistry | Organometallic Compounds - chemical synthesis | Neptunium - chemistry | Water - chemistry | Organometallic Compounds - chemistry | Plutonium - chemistry | Uranium - chemistry
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12. Full Text Gas-Phase Uranyl, Neptunyl, and Plutonyl: Hydration and Oxidation Studied by Experiment and Theory
by Rios, Daniel and Michelini, Maria C and Lucena, Ana F and Marçalo, Joaquim and Bray, Travis H and Gibson, John K
Inorganic Chemistry, ISSN 0020-1669, 06/2012, Volume 51, Issue 12, pp. 6603 - 6614
The following monopositive actinyl ions were produced by electrospray ionization of aqueous solutions of AnVIO2(ClO4)2 (An = U, Np, Pu): UVO2 +, NpVO2 +, PuVO2... 
AQUO COMPLEXES | EFFECTIVE CORE POTENTIALS | QUANTUM-CHEMICAL METHODS | TRANSITION-METAL | COORDINATION-COMPLEXES | WATER EXCHANGE | ROOM-TEMPERATURE KINETICS | AQUEOUS-SOLUTION | ELECTRONIC-STRUCTURE | ACTINYL IONS | CHEMISTRY, INORGANIC & NUCLEAR | Gases - chemistry | Quantum Theory | Oxidation-Reduction | Neptunium - chemistry | Water - chemistry | Plutonium - chemistry | Uranium - chemistry | Chemical bonds | Oxidation-reduction reaction | Hydration (Chemistry) | Aqueous solution reactions | Ionization | Analysis
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13. Full Text Collection of Lanthanides and Actinides from Natural Waters with Conventional and Nanoporous Sorbents
by Johnson, Bryce E and Santschi, Peter H and Chuang, Chia-Ying and Otosaka, Shigeyoshi and Addleman, Raymond Shane and Douglas, Matt and Rutledge, Ryan D and Chouyyok, Wilaiwan and Davidson, Joseph D and Fryxell, Glen E and Schwantes, Jon M and Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Environmental Science & Technology, ISSN 0013-936X, 10/2012, Volume 46, Issue 20, pp. 11251 - 11258
Effective collection of trace-level lanthanides and actinides is advantageous for recovery and recycling of valuable resources, environmental remediation,... 
MARINE ORGANIC-MATTER | GULF-OF-MEXICO | SEA-WATER | URANIUM | ENVIRONMENTAL SCIENCES | MESOPOROUS SUPPORTS | SELF-ASSEMBLED MONOLAYERS | ENGINEERING, ENVIRONMENTAL | MANGANESE-DIOXIDE | CARBONATE COMPLEXES | NEPTUNIUM | ADSORPTION | Water Pollutants, Radioactive - chemistry | Water Pollutants, Chemical - chemistry | Actinoid Series Elements - chemistry | Seawater - chemistry | Environmental Restoration and Remediation - methods | Water Pollutants, Chemical - analysis | Lanthanoid Series Elements - analysis | Actinoid Series Elements - analysis | Lanthanoid Series Elements - chemistry | Adsorption | Rivers - chemistry | Nanostructures - chemistry | Water Pollutants, Radioactive - analysis | Index Medicus | Actinide, lanthanide, mesoporous, nanoporous, manganese oxide, SAMMS, chelation, sorbent, ion exchange, adsorption
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14. Full Text Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates
by Diwu, Juan and Wang, Shuao and Liao, Zuolei and Burns, Peter C and Albrecht-Schmitt, Thomas E and Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
Inorganic Chemistry, ISSN 0020-1669, 11/2010, Volume 49, Issue 21, pp. 10074 - 10080
The in situ hydrothermal reduction of Np(VI) to Np(IV) and Pu(VI) to Pu(IV) in the presence of 1,2-phenylenediphosphonic acid (PhP2) results in the... 
CATALYZED TRANSFORMATION | POWDER DIFFRACTION DATA | SOLID-SOLUTIONS | CHEMISTRY | CRYSTAL-STRUCTURES | THORIUM PHOSPHATE | TETRAVALENT ACTINIDE PHOSPHATES | BOND-VALENCE PARAMETERS | URANYL PHENYLPHOSPHONATE | HYDROTHERMAL SYNTHESIS | CHEMISTRY, INORGANIC & NUCLEAR | Cerium - chemistry | Organometallic Compounds - chemical synthesis | Neptunium - chemistry | Organophosphonates - chemistry | Models, Molecular | Organometallic Compounds - chemistry | Plutonium - chemistry | nuclear (including radiation effects), materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly)
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15. Full Text Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate
by Wang, Shuao and Alekseev, Evgeny V and Miller, Hannah M and Depmeier, Wulf and Albrecht-Schmitt, Thomas E and Materials Science of Actinides (MSA) and Energy Frontier Research Centers (EFRC)
Inorganic Chemistry, ISSN 0020-1669, 11/2010, Volume 49, Issue 21, pp. 9755 - 9757
Molten methylboronic acid has been used as a reactive flux to prepare the first neptunium(V) borate, NpO2[B3O4(OH)2] (NpBO-1), and the first actinide boronate,... 
STRUCTURAL-CHARACTERIZATION | COMPLEX | NUCLEAR-WASTE | INSIGHTS | CHEMISTRY, INORGANIC & NUCLEAR | Temperature | Organometallic Compounds - chemical synthesis | Neptunium - chemistry | Models, Molecular | Crystallography, X-Ray | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Uranium - chemistry | Borates - chemistry | Uranium | Chemical properties | Structure | Neptunium | Organoboron compounds | Methyl groups | synthesis (novel materials) | synthesis (self-assembly) | materials and chemistry by design | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY | nuclear (including radiation effects)
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16. Full Text Understanding the Interactions of Neptunium and Plutonium Ions with Graphene Oxide: Scalar-Relativistic DFT Investigations
by Wu, Qun-Yan and Lan, Jian-Hui and Wang, Cong-Zhi and Zhao, Yu-Liang and Chai, Zhi-Fang and Shi, Wei-Qun
The Journal of Physical Chemistry A, ISSN 1089-5639, 11/2014, Volume 118, Issue 44, pp. 10273 - 10280
Due to the vast application potential of graphene oxide (GO)-based materials in nuclear waste processing, it is of pivotal importance to investigate the... 
AQUEOUS-SOLUTIONS | ENERGY | LIGANDS | COMPLEXES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | MULTIWALLED CARBON NANOTUBES | BASIS-SETS | GAS-PHASE URANYL | DENSITY-FUNCTIONAL THEORY | ACTINIDE | ELECTRON-DENSITY | Plutonium - chemistry | Ions - chemistry | Quantum Theory | Graphite - chemistry | Oxides - chemistry | Neptunium - chemistry | Density functionals | Chemical properties | Plutonium | Graphene | Neptunium | Analysis | Actinides | Binding energy | Oxides | Cations | Bonding
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17. Full Text Hydroxypyridinonate Complex Stability of Group (IV) Metals and Tetravalent f‑Block Elements: The Key to the Next Generation of Chelating Agents for Radiopharmaceuticals
by Sturzbecher-Hoehne, Manuel and Choi, Taylor A and Abergel, Rebecca J
Inorganic Chemistry, ISSN 0020-1669, 04/2015, Volume 54, Issue 7, pp. 3462 - 3468
The solution thermodynamics of the water-soluble complexes formed between 3,4,3-LI­(1,2-HOPO) and Zr­(IV) or Pu­(IV) were investigated to establish the metal... 
ANTIBODIES | EQUILIBRIA | DECORPORATION AGENTS | 3,4,3-LI(1,2-HOPO) | PLUTONIUM | NEPTUNIUM(IV) | THORIUM(IV) | TRANSURANIUM ELEMENTS | SEQUESTERING AGENTS | PET | CHEMISTRY, INORGANIC & NUCLEAR | Thermodynamics | Gas Chromatography-Mass Spectrometry | Radiopharmaceuticals - chemistry | Drug Stability | Zirconium - chemistry | Chelating Agents - chemistry | Ligands | Plutonium - chemistry | Molecular Structure | Pyridones - chemistry | Coordination Complexes - chemistry | Pyridine | Chelating agents | Chemical properties | Radiopharmaceuticals | Analysis | Chelating | Orbitals | Separation | Stability | Electronics | Liquid chromatography | Estimates
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18. Full Text The pentavalent actinide solution chemistry in the environment
by Topin, Sylvain and Aupiais, Jean
Journal of Environmental Radioactivity, ISSN 0265-931X, 03/2016, Volume 153, pp. 237 - 244
With regard to environmental monitoring of certain nuclear facilities, pentavalent actinides, in particular neptunium and plutonium, play a key role, as the... 
Actinide | Complexation | Migration | Speciation | ENVIRONMENTAL SCIENCES | PLASMA-MASS SPECTROMETRY | SULFATE | COMPLEXES | PROTACTINIUM(V) | NP(V) | STABILITY-CONSTANTS | NEPTUNIUM | Thermodynamics | Electrophoresis, Capillary | Actinoid Series Elements - analysis | Mass Spectrometry | Neptunium - chemistry | Plutonium - chemistry | Actinoid Series Elements - chemistry | Radiation Monitoring | Solutions - chemistry | Carbonates | Oxalates | Oxalic acid | Environmental monitoring | Sulfates | Analogies | Actinides | Chlorides | Nuclear engineering
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19. Full Text Quantum Chemistry Study of Uranium(VI), Neptunium(V), and Plutonium(IV,VI) Complexes with Preorganized Tetradentate Phenanthrolineamide Ligands
by Xiao, Cheng-Liang and Wu, Qun-Yan and Wang, Cong-Zhi and Zhao, Yu-Liang and Chai, Zhi-Fang and Shi, Wei-Qun
Inorganic Chemistry, ISSN 0020-1669, 10/2014, Volume 53, Issue 20, pp. 10846 - 10853
The preorganized tetradentate 2,9-diamido-1,10-phenanthroline ligand with hard–soft donors combined in the same molecule has been found to possess high... 
FINE-STRUCTURE SPECTROSCOPY | 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID | ACTINIDES | SEPARATION | DENSITY-FUNCTIONAL THEORY | METAL-IONS | SELECTIVITY | NITROGEN LIGANDS | HIGHER CHARGE | AQUEOUS-SOLUTION | CHEMISTRY, INORGANIC & NUCLEAR | Quantum Theory | Phenanthrolines - chemistry | Organometallic Compounds - chemical synthesis | Neptunium - chemistry | Ligands | Organometallic Compounds - chemistry | Plutonium - chemistry | Molecular Structure | Uranium - chemistry
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20. Full Text Influence of riboflavin on the reduction of radionuclides by Shewanella oneidenis MR-1
by Cherkouk, Andrea and Law, Gareth T W and Rizoulis, Athanasios and Law, Katie and Renshaw, Joanna C and Morris, Katherine and Livens, Francis R and Lloyd, Jonathan R
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 03/2016, Volume 45, Issue 12, pp. 5030 - 5037
Uranium (as UO2(2+)), technetium (as TcO4(-)) and neptunium (as NpO2(+)) are highly mobile radionuclides that can be reduced enzymatically by a range of... 
Biodegradation, Environmental | X-Ray Absorption Spectroscopy | Riboflavin - chemistry | Oxidation-Reduction | Neptunium - chemistry | Ferric Compounds - chemistry | Shewanella - metabolism | Uranium - chemistry | Radioisotopes - chemistry | Technetium - chemistry
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