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Chemical communications (Cambridge, England), ISSN 1364-548X, 2018, Volume 54, Issue 72, pp. 10112 - 10115
A direct, single synthetic homologative transformation of halostannanes into mono- or di-substituted methyl analogues is documented. A direct, single synthetic... 
Nucleophiles | Homology | Reagents
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2018, Volume 9, Issue 9, pp. 2628 - 2632
A new asymmetric conjugate addition method was developed for β-substituted cyclopentenones to form quaternary centres using alkylzirconocene nucleophiles... 
Substitutes | Ligands | Selectivity | Nucleophiles
Journal Article
Tetrahedron letters, ISSN 0040-4039, 01/2015, Volume 56, Issue 2, pp. 283 - 295
[Display omitted] The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the... 
N-Nucleophiles | Copper | Asymmetric catalysis | Propargylic substitution | C-Nucleophiles | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology | Cycloaddition | Tetrahedrons | Handles | Selectivity | Sulfur | Nucleophiles | Carbon
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 13858 - 13861
The enantioselective synthesis of 4-fluoroisochromanones via chiral aryl iodide-catalyzed fluorolactonization is reported. This methodology uses HF-pyridine as... 
Chemical reactions | Usage | Pyridine | Chemical properties | Nucleophiles
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 41, pp. 14409 - 14412
While the reactive pocket of many enzymes has been shown to modify reactions of substrates by changing their chemical properties, examples of reactions whose... 
Stereochemistry | Chemical properties | Nucleophiles | Carbon compounds | Analysis
Journal Article
Synthesis, ISSN 0039-7881, 06/2015, Volume 47, Issue 11, pp. 1581 - 1592
Abstract A practical BF 3 ·OEt 2 -catalyzed regioselective 1,2-addition or 1,4-hetero-Michael addition of oxygen, sulfur, and nitrogen nucleo­philes to... 
paper | Michael addition | maleimide | sulfur nucleophiles | oxygen nucleophiles | nitrogen nucleophiles | boron trifluoride diethyl etherate
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14194 - 14197
The first asymmetric synthesis of α,α-disubstituted allylic N-arylamines based on a palladium-catalyzed allylic amination has been developed. The protocol uses... 
Usage | Amines | Chemical properties | Research | Catalysis | Chemical synthesis | Nucleophiles
Journal Article
2013, ISBN 9783527656172, xiii, 472
This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these... 
Aromatic compounds | Synthesis | Nucleophilic reactions | Substitution reactions
Book
Chemistry : a European journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 51, pp. 18717 - 18723
Addition of organotrimethylsilane reagents to chiral N‐tert‐butanesulfinyl imines can be achieved in good yields and with excellent diastereoselectivities by... 
trimethylsilyloxide activation | pro‐nucleophiles | diastereoselectivity | organotrimethylsilanes | chiral imines | pro-nucleophiles | Enantiomers | Schiff bases | Imines | Reagents | Amides | Lewis base | Nucleophiles | Chemical synthesis | Aliphatic compounds | Synthesis | Metalorganic compounds | Robustness
Journal Article
Chemical Society reviews, ISSN 0306-0012, 8/2016, Volume 45, Issue 16, pp. 4448 - 4458
The two main strategies of gold-catalysed oxidative cyclisation are discussed in this tutorial. The first one employs nucleophilic oxidants as either internal... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Oxidants | Oxidizing agents | Bonding strength | Strategy | Transformations | Catalysis | Nucleophiles | Alkynes
Journal Article
Chemical Society reviews, ISSN 1460-4744, 2018, Volume 47, Issue 21, pp. 7899 - 7925
This review focusses on the use of amide activation for chemoselective functionalisation and its application in natural product synthesis. It is textbook... 
Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Amides | Activation | Synthesis | Nucleophiles | Natural products | Carbonyls
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2018, Volume 54, Issue 50, pp. 6692 - 6704
The transfer of a reactive nucleophilic CH 2 X unit into a preformed bond enables the introduction of a fragment featuring the exact and desired degree of... 
Organic chemistry | Homology | Stability | Nucleophiles | Molecular chains | Reagents
Journal Article