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o-methyl oximes (82) 82
chemistry, organic (54) 54
chemistry, multidisciplinary (37) 37
tert-butyl hydroperoxide (31) 31
aldehydes (29) 29
oxidative ortho-acylation (25) 25
activation (21) 21
alpha-oxocarboxylic acids (21) 21
catalysis (20) 20
acylation (19) 19
room-temperature (19) 19
c-h activation (18) 18
derivatives (16) 16
palladium (16) 16
index medicus (15) 15
convenient route (14) 14
decarboxylative ortho-acylation (14) 14
direct access (14) 14
toluene derivatives (12) 12
ketones (11) 11
acetanilides (10) 10
electroorganic chemistry (10) 10
functionalization (10) 10
organic-synthesis (10) 10
asymmetric-synthesis (9) 9
bond activation (9) 9
c-h bond (9) 9
ch activation (9) 9
rhodium (9) 9
synthesis (9) 9
aryl (8) 8
cyclization (8) 8
oximes (8) 8
carbon-hydrogen bonds (7) 7
chemistry (7) 7
coupling reactions (7) 7
internal alkynes (7) 7
molecular structure (7) 7
samarium diiodide (7) 7
aromatic compounds (6) 6
arylation (6) 6
chemical properties (6) 6
chemical reactions (6) 6
efficient synthesis (6) 6
o-methyl ketoximes (6) 6
palladium - chemistry (6) 6
regioselectivity (6) 6
research (6) 6
rhodium - chemistry (6) 6
1,2-amino alcohols (5) 5
alcohols (5) 5
analysis (5) 5
arenes (5) 5
aryl bromides (5) 5
bonding (5) 5
ch activation (5) 5
direct arylation (5) 5
direct functionalization (5) 5
directing group (5) 5
electrophilic cyclization (5) 5
ethers (5) 5
functional groups (5) 5
one-pot synthesis (5) 5
oxidation-reduction (5) 5
2-amino alcohols (4) 4
aldehydes - chemistry (4) 4
bond (4) 4
carbohydrates (4) 4
carbonyl-compounds (4) 4
carboxylic-acids (4) 4
catalyzed ortho-acylation (4) 4
chemical synthesis (4) 4
chemistry, applied (4) 4
chemistry, inorganic & nuclear (4) 4
chemistry, physical (4) 4
construction (4) 4
c–h activation (4) 4
decarboxylative acylation (4) 4
n bond formation (4) 4
o-methyl-oximes (4) 4
ortho-acylation (4) 4
oxidation (4) 4
pharmacology & pharmacy (4) 4
samarium (4) 4
stereoisomerism (4) 4
terminal alkynes (4) 4
acids (3) 3
acyl chlorides (3) 3
alcohol oxidation (3) 3
alkynes (3) 3
alkynes - chemistry (3) 3
alkynyl oxime ethers (3) 3
amides - chemistry (3) 3
aqueous-media (3) 3
aromatic-aldehydes (3) 3
beckmann rearrangement (3) 3
benzamides (3) 3
benzoic-acids (3) 3
benzylic alcohols (3) 3
biochemistry & molecular biology (3) 3
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Chemical Reviews, ISSN 0009-2665, 11/2017, Volume 117, Issue 21, pp. 13039 - 13122
This review classifies and summarizes the past 10–15 years of advancements in the field of metal-involving (i.e., metal-mediated and metal-catalyzed) reactions... 
4-MEMBERED CYCLIC NITRONES | CARBON BOND FORMATION | CATALYZED SKELETAL REARRANGEMENT | ONE-POT SYNTHESIS | X-RAY-STRUCTURE | FREE-RADICAL REACTIONS | N-ACETYL ENAMIDES | HIGHLY EFFICIENT SYNTHESIS | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | O-METHYL KETOXIMES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2017, Volume 359, Issue 5, pp. 710 - 771
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2012, Volume 354, Issue 16, pp. 2916 - 2920
The rhodium‐catalyzed oxidative ortho‐acylation of aryl ketone O‐methyl oximes with aryl and alkyl aldehydes via CH bond activation is described. The... 
aryl ketone O‐methyl oximes | CH activation | aldehydes | acylation | rhodium catalysis | aryl ketone O-methyl oximes | C-H activation | ACETANILIDES | ROUTE | INSERTION | DIRECT FUNCTIONALIZATION | CHEMISTRY, ORGANIC | BOND FORMATION | TERT-BUTYL HYDROPEROXIDE | BENZAMIDES | NITRILES | CHEMISTRY, APPLIED | Aldehydes | Business parks | Bonds | Acylation | Oximes | Synthesis | Ketones | Aromatic compounds | Activation | Tolerances | Bonding
Journal Article
RSC Advances, 05/2016, Volume 6, Issue 54, pp. 48666 - 48675
For the first time, 4-chloroisoxazoles are directly synthesized in moderate to excellent yields from (E/Z)-alkynyl-O- methyl oximes via chlorinative... 
Oximes | Hydrochloric acid | Solvents | Nitromethane | Chlorination | Synthesis | Chlorine
Journal Article
RSC Advances, ISSN 2046-2069, 2016, Volume 6, Issue 54, pp. 48666 - 48675
For the first time, 4-chloroisoxazoles are directly synthesized in moderate to excellent yields from (E/Z)-alkynyl-O-methyl oximes via chlorinative... 
ELECTROPHILIC CYCLIZATION | ISOXAZOLES | DESIGN | ACYL CHLORIDES | TERMINAL ALKYNES | CONVENIENT | ALDEHYDES | HALOGENATION | FLUORINATION | O-METHYL OXIMES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2005, Volume 12, Issue 2, pp. 499 - 509
Journal Article
Helvetica Chimica Acta, ISSN 0018-019X, 07/2014, Volume 97, Issue 7, pp. 915 - 922
An efficient two‐step procedure for the preparation of a new type of 1H‐isoindoles, i.e., N‐(3‐alkyl‐1‐aryl‐ or... 
Nitriles | Methanone O‐methyl oximes | 1H‐Isoindol‐1‐amines | Br/Li Exchange | 1H-Isoindol-1-amines | Methanone O-methyl oximes | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synthetic Communications, ISSN 0039-7911, 12/2016, Volume 46, Issue 24, pp. 1981 - 1988
A palladium-catalyzed highly regioselective ortho-C(sp 2 )-H alkoxylation of oxime ethers with PhI(OAc) 2 as the oxidant and alcohols as the alkoxylation... 
alkoxylation | palladium catalysis | C-H activation | Acetoxylation | oxime ethers | MECHANISM | HYDROXYLATION | 3-METHYLENEISOINDOLIN-1-ONES | CHEMISTRY, ORGANIC | FUNCTIONALIZATION | ALCOHOLS | CONSTRUCTION | BOND ACTIVATION | ARYL | O-METHYL OXIMES | ORTHO-ACYLATION
Journal Article
Magnetic Resonance in Chemistry, ISSN 0749-1581, 08/2000, Volume 38, Issue 8, pp. 627 - 638
Axial equatorial populations were determined for (E)‐2‐X‐cyclohexanone oximes and O‐methyl oxime ethers in chloroform by the Eliel method [X = F, Cl, Br, OCH3,... 
1H NMR | O‐methyl oximes | NMR | conformational analysis | 13C NMR | oximes | O-methyl oximes | Oximes | C NMR | H NMR | Conformational analysis | KETONES | H-1 NMR | SPECTROSCOPY | 2-SUBSTITUTED CYCLOHEXANONES | CHEMISTRY, PHYSICAL | ACETONE OXIMES | C-13 NMR | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
CHEMICAL REVIEWS, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9163 - 9227
The transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized pi bonds has emerged as a particularly efficient and powerful... 
N-SULFONYL KETIMINES | 3+2 ANNULATION | CYCLIZATION DIRECT SYNTHESIS | OXIDATIVE ORTHO-ACYLATION | ASYMMETRIC-SYNTHESIS | EFFICIENT SYNTHESIS | CASCADE CYCLIZATION | DIRECT ACCESS | O-METHYL OXIMES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2016, Volume 52, Issue 39, pp. 6589 - 6592
A general method for isoxazoles from readily available ynones using trimethylsilyl azide as an amino surrogate, likely via an unprecedented hydroazidation of... 
Catalysts | Compatibility | Functional groups | Alkynes
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 39, pp. 6589 - 6592
A general method for isoxazoles from readily available ynones using trimethylsilyl azide as an amino surrogate, likely via an unprecedented hydroazidation of... 
ELECTROPHILIC CYCLIZATION | GOLD | VALDECOXIB | S31N MUTANT | ALKYNYL OXIME ETHERS | CATALYZED SYNTHESIS | CYCLOISOMERIZATION | TRISUBSTITUTED ISOXAZOLES | O-METHYL OXIMES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Heterocycles, ISSN 0385-5414, 10/2000, Volume 53, Issue 10, pp. 2285 - 2336
Modern methodologies of preparation of three-, five-, six- and seven-membered heterocyclic compounds from oximes and their derivatives have been reviewed.... 
HYDROXYPHENETHYL KETONE O-2,4-DINITROPHENYLOXIMES | DIELS-ALDER-REACTIONS | X=Y-ZH SYSTEMS | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | 1,3-DIPOLAR CYCLOADDITION REACTIONS | INTRAMOLECULAR NITRILE OXIDE | 1,3-AZAPROTIO CYCLOTRANSFER | O-METHYL OXIMES | TETRASULFUR TETRANITRIDE | BECKMANN REARRANGEMENT
Journal Article
by Mi, X and Wang, CY and Huang, MM and Wu, YS and Wu, YJ
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 01/2015, Volume 80, Issue 1, pp. 148 - 155
A new and efficient metal-free tandem acylation/cyclization of alkynoates with aldehydes was developed for the synthesis of 3-acyl-4-arylcoumarins. The... 
ALKENES | N-HYDROXYPHTHALIMIDE NHPI | CATALYZED SYNTHESIS | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | IONIC LIQUID | DIRECT ACCESS | TERT-BUTYL HYDROPEROXIDE | O-METHYL OXIMES | ORTHO-ACYLATION | COUMARINS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2013, Volume 78, Issue 20, pp. 10414 - 10420
A palladium-catalyzed decarboxylative ortho acylation of azobenzenes with α-oxocarboxylic acids via ligand-directed C–H activation has been explored. The... 
H BOND ACTIVATION | ROOM-TEMPERATURE | OXIDATIVE ORTHO-ACYLATION | TOLUENE DERIVATIVES | BENZOPHENONE RELATED-COMPOUNDS | AROMATIC AZO-COMPOUNDS | CHEMISTRY, ORGANIC | N-METHOXYBENZAMIDES | DIRECT ACCESS | O-METHYL OXIMES | C-H | Oxo compounds | Azo compounds | Palladium | Chemical properties | Research
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2013, Volume 2013, Issue 29, pp. 6656 - 6665
A highly efficient palladium‐catalyzed oxidative ortho‐acylation of O‐methyl ketoximes and O‐methyl aldoximes with benzylic and aliphatic alcohols from the... 
C–H Activation | Oximes | Palladium | Acylation | Alcohols | C-H Activation | TRANSITION-METAL CATALYSIS | ROOM-TEMPERATURE | ACETANILIDES | CHEMISTRY, ORGANIC | ALDEHYDES | CARBON-HYDROGEN BONDS | DIRECT ACCESS | TERT-BUTYL HYDROPEROXIDE | ALPHA-OXOCARBOXYLIC ACIDS | DECARBOXYLATIVE ORTHO-ACYLATION | O-METHYL OXIMES | Drugstores | Oxidation-reduction reaction
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 8, pp. 2082 - 2085
A Pd-catalyzed decarboxylative acylation of aromatic ketones with α-oxocarboxylic acids was developed, and 1,2-diacylbenzenes were formed in up to 90% yield... 
ARYL BROMIDES | ROOM-TEMPERATURE | REGIOSPECIFIC SYNTHESIS | ARENES | CHEMISTRY, ORGANIC | BOND ACTIVATION | FORMING REDUCTIVE ELIMINATION | DUAL CATALYSIS | TERT-BUTYL HYDROPEROXIDE | O-METHYL OXIMES | DIACYLBENZENES
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2016, Volume 52, Issue 7, pp. 1416 - 1419
The NHPI and palladium cocatalyzed radical oxidative acylation of arenes with aldehydes and alcohols as acyl equivalents via selective C-H functionalization... 
ALCOHOL OXIDATION | C-H BOND | TOLUENE DERIVATIVES | ALPHA-KETOESTERS | CATALYZED ORTHO-ACYLATION | N-HYDROXYPHTHALIMIDE | DEHYDROGENATIVE COUPLING CDC | TERT-BUTYL HYDROPEROXIDE | O-METHYL OXIMES | CHEMISTRY, MULTIDISCIPLINARY | MOLECULAR-OXYGEN
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2016, Volume 52, Issue 7, pp. 1416 - 1419
The NHPI and palladium cocatalyzed radical oxidative acylation of arenes with aldehydes and alcohols as acyl equivalents via selective C-H functionalization... 
Journal Article
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