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by Zang, C and Liu, YG and Xu, ZJ and Tse, CW and Guan, XG and Wei, JH and Huang, JS and Che, CM
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2016, Volume 55, Issue 35, pp. 10253 - 10257
The development of environmentally benign catalysts for highly enantioselective asymmetric cis-dihydroxylation (AD) of alkenes with broad substrate scope... 
NONHEME IRON | asymmetric catalysis | cis-dihydroxylation | H2O2 | CHEMISTRY, MULTIDISCIPLINARY | DFT calculations | EPOXIDATION | SYN-DIHYDROXYLATION | N-ligands | RIESKE DIOXYGENASES | ASYMMETRIC DIHYDROXYLATION | OXIDATIONS | OLEFINS | iron catalysis | LIGAND | C-H
Journal Article
Chemical Communications, ISSN 1359-7345, 2008, Volume 59, Issue 32, pp. 3747 - 3749
High turnover enantioselective alkene cis-dihydroxylation is achieved with H2O2 catalysed by manganese based complexes containing chiral carboxylato ligands. 
ALKENES | OXIDATION CATALYSIS | SERIES | ACIDS | COMPLEXES | 1,4,7-TRIAZACYCLONONANES | OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | Hydrogen Peroxide - chemistry | Alkenes - chemistry | Temperature | Hydroxylation | Stereoisomerism | Carboxylic Acids - chemistry | Molecular Conformation | Ligands | Catalysis | Manganese - chemistry
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2011, Volume 1, Issue 9, pp. 1035 - 1042
[Fe(Me2EBC)(OTf)2], the iron(II) complex of the tetraazamacrocyclic Me2EBC ligand (Me2EBC = 4,11-dimethyl-1,4,8,11-tetraazabicyclo [6.6.2]hexadecane), has been... 
nonheme iron | olefin epoxidation | cis-dihydroxylation | cyclam | DIOXYGEN ACTIVATION | OXIDATION | MECHANISM | CHEMISTRY, PHYSICAL | CROSS-BRIDGED CYCLAM | ALKENES | 2-HIS-1-CARBOXYLATE FACIAL TRIAD | CHEMISTRY | HYDROGEN-PEROXIDE | SELECTIVITY | INSIGHTS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 10/2010, Volume 8, Issue 19, pp. 4444 - 4450
A practical method for the multigram scale selective cis-dihydroxylation of electron deficient alkenes such as diethyl fumarate and N-alkyl and... 
OXIDATION | SYSTEM | ALCOHOLS | ACID | COMPLEXES | CHEMISTRY, ORGANIC | OLEFINS | HYDROGEN-PEROXIDE | EPOXIDATION
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 08/2007, Volume 46, Issue 16, pp. 6353 - 6372
In the presence of carboxylic acids the complex [MnIV 2(μ-O)3(tmtacn)2]2+ (1, where tmtacn = N,N‘,N‘ ‘-trimethyl-1,4,7-triazacyclononane) is shown to be highly... 
OXYGEN-EVOLVING COMPLEX | OLEFIN EPOXIDATION | OXIDATION CATALYSIS | ELECTRON-TRANSFER | ASYMMETRIC DIHYDROXYLATION | FUNCTIONAL MODELS | PHOTOSYSTEM-II | HYDROGEN-PEROXIDE | 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE COMPLEXES | NONHEME IRON CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2016, Volume 55, Issue 35, pp. 10253 - 10257
The development of environmentally benign catalysts for highly enantioselective asymmetric cis‐dihydroxylation (AD) of alkenes with broad substrate scope... 
N-ligands | asymmetric catalysis | iron catalysis | cis-dihydroxylation | DFT calculations | Cytokinins | Hydrogen peroxide | Analysis | Olefins | Cyclohexane | Catalysis | Enantiomers | Dimethyl | Catalysts | Alkenes | Benign | Labels | Iron | Marking | Asymmetry | Mathematical analysis | Yield | Bonding | Diols
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 40, pp. 11204 - 11206
A practical protocol has been developed for asymmetric cis-dihydroxylation of electron-deficient alkenes with Oxone catalysed by a manganese complex bearing a... 
COMPLEX | MECHANISM | PORPHYRINS | OXO | OXIDATIONS | REACTIVITY | OLEFINS | LIGAND | H2O2 | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | Alkenes - chemistry | Spectrometry, Mass, Electrospray Ionization | Hydroxylation | Stereoisomerism | Molecular Conformation | Models, Molecular | Substrate Specificity | Catalysis | Manganese - chemistry | Electrons
Journal Article
Organic Letters, ISSN 1523-7060, 01/2006, Volume 8, Issue 1, pp. 75 - 78
The cis-dihydroxylation of olefin-containing potassium alkyl- and aryltrifluoroborates proceeds readily in moderate to excellent yields. The resulting diols... 
CROSS-COUPLING REACTIONS | HYDROBORATION | CROTYLATION | EFFICIENT AGENTS | ALLYLATION | CHEMISTRY, ORGANIC | OLEFINS | ALDEHYDES | EXPANDING ORGANOBORON CHEMISTRY | CATALYZED VICINAL HYDROXYLATION | TERT-BUTYL HYDROPEROXIDE | Hydroxylation | Borates - chemistry | Potassium - chemistry
Journal Article
Journal of Molecular Catalysis. A, Chemical, ISSN 1381-1169, 2008, Volume 285, Issue 1, pp. 111 - 119
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2005, Volume 127, Issue 45, pp. 15672 - 15673
Nature has evolved enzymes that carry out the cis-dihydroxylation of CC bonds in the biodegradation of arenes in the environment. These enzymes, called Rieske... 
DIOXYGEN ACTIVATION | NAPHTHALENE 1,2-DIOXYGENASE | 2 FACES | MODELS | ACTIVE-SITES | ENZYMES | OXIDATIONS | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | IRON(III) COMPLEXES | Alkenes - chemistry | Ligands | Molecular Structure | Catalysis | Hydroxylation | Iron - chemistry | Chemical properties | Research | Olefins | Methyl groups
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2003, Volume 125, Issue 33, pp. 9912 - 9913
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2010, Volume 132, Issue 50, p. 17713
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2005, Volume 127, Issue 22, pp. 7990 - 7991
The carboxylic acid promoted cis-dihydroxylation and epoxidation of alkenes catalyzed by [MnIV 2O3(tmtacn)2]2+ 1 employing H2O2 as oxidant is described. The... 
OXIDATION | SYSTEM | ALCOHOLS | ASYMMETRIC DIHYDROXYLATION | PRACTICAL METHOD | OLEFINS | HYDROGEN-PEROXIDE | H2O2 | CHEMISTRY, MULTIDISCIPLINARY | DINUCLEAR MANGANESE(IV) COMPLEX | NONHEME IRON CATALYSTS | Carboxylic acids | Chemical properties | Catalysis | Olefins
Journal Article
Dalton Transactions (Print Edition), ISSN 1477-9226, 01/2010, Volume 39, Issue 34, pp. 7888 - 7890
We report on the activity of fullerene-supported OsO4 catalysts in the achiral dihydroxylation of olefins using N-methylmorpholine N-oxide as co-oxidant. The... 
Catalysts | Olefins | Recycled | Leaching | Conversion | Prints | Osmium
Journal Article
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