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-alkene dipeptide isosteres (20) 20
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Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 11, pp. 3734 - 3738
Presented herein is a mild, facile, and efficient iron‐catalyzed synthesis of substituted allenes from propargyl carboxylates and Grignard reagents. Only 1–5 mol... 
cross-coupling | allenes | Grignard reagents | iron | chirality | OXIDATIVE CARBOCYCLIZATION | ORGANIC-SYNTHESIS | ORGANOCOPPER REAGENTS | ASYMMETRIC-SYNTHESIS | ENALLENES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | CHIRAL ALLENES | PHOSPHATES | CHLORIDES | METAL CATALYSIS | Chemical tests and reagents | Cross coupling | Reagents | Benign | Iron | Chemical synthesis | Functional groups | Carboxylates | Communications | Communication
Journal Article
1994, Practical approach in chemistry series, ISBN 0198557574, xii, 362
Book
Tetrahedron Letters, ISSN 0040-4039, 07/2004, Volume 45, Issue 29, pp. 5585 - 5588
The reaction of allylic compounds with alkyl Grignard reagents in the presence of a catalytic amount of copper N-heterocyclic carbene (NHC... 
Allylic substitution | Organocopper | Asymmetric reaction | N-Heterocyclic carbene | N-heterocyclic carbene | asymmetric reaction | LIGANDS | REDUCTION | CHLORIDES | CHEMISTRY, ORGANIC | organocopper | CARBONYL-COMPOUNDS | allylic substitution | CONJUGATE ADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 12/2005, Volume 7, Issue 25, pp. 5593 - 5595
Direct addition of Grignard reagents to acid chlorides in the presence of bis[2-(N,N-dimethylamino)ethyl] ether proceeds selectively to provide aryl ketones in high yields... 
FRIEDEL-CRAFTS ACYLATION | CONVENIENT SYNTHESIS | FUNCTIONALIZED KETONES | ORGANOCOPPER REAGENTS | ACYL CHLORIDES | COUPLING REACTIONS | MEDIATED SYNTHESIS | CHEMISTRY, ORGANIC | CATALYZED ACYLATION | ORGANOMANGANESE(II) REAGENTS | VERSATILE PREPARATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 37, pp. 10963 - 10967
Functionalized secondary alkyllithium reagents obtained by I/Li exchange from the corresponding secondary alkyl iodides undergo two successive transmetalations with Me3SiCH2ZnBr⋅LiBr and CuBr⋅2 LiCl... 
lithium | copper | diastereoselectivity | configurational stability | zinc | COPPER REAGENTS | STEREOCHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | DIASTEREOSELECTIVE SYNTHESIS | CHIRAL DIAMINES | SYNTHETIC APPLICATIONS | ORGANOCOPPER | LITHIATION | Ethylene oxide | Dichloropropane | Chemical tests and reagents | Chlorides | Exchange | Solvents | Iodides | Esters | Derivatives | Acetone
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 19, pp. 4009 - 4012
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 04/2004, Volume 101, Issue 16, pp. 5834 - 5838
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 03/2007, Volume 40, Issue 3, pp. 179 - 188
Journal Article
Synthesis, ISSN 0039-7881, 10/2012, Volume 44, Issue 20, pp. 3109 - 3128
Abstract Herein, an overview of the most important developments and concepts related to the 1,6-conjugate addition reactions are reviewed. 1 Introduction 2... 
review | enantioselectivity | organocatalysis | asymmetric synthesis | 1,6-conjugate addition | nucleophiles | ORGANOCOPPER REAGENTS | MECHANISM | CATALYZED ASYMMETRIC 1,6-ADDITION | COMPLEXES | CHEMISTRY, ORGANIC | BORONIC ACIDS | ESTERS | TRIALKYLALUMINUM REAGENTS | GRIGNARD-REAGENTS | DIENONES | CONJUGATE ADDITION
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 41, pp. 13547 - 13550
... into the corresponding chiral products. Smooth addition of organomagnesium reagents to relatively unreactive dienyl amides with excellent 1,6- and 1,4-selectivities, as well as enantioselectivites above 90... 
regioselectivity | Lewis acids | copper | asymmetric catalysis | conjugation | To be checked by Faculty | 1,6-CONJUGATE ADDITION | ORGANOCOPPER REAGENTS | MECHANISM | ACIDS | ASYMMETRIC 1,6-ADDITION | 1,4-CONJUGATE ADDITION | CARBONYL-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | KETONES | ESTERS | GRIGNARD-REAGENTS | Amides | Catalysis | Chemical tests and reagents | Enantiomers | Copper | Lewis acid | Alkylation | Reagents
Journal Article