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ortho-alkenylation (92) 92
chemistry, organic (61) 61
chemistry, multidisciplinary (44) 44
catalysis (39) 39
alkenes (34) 34
c-h activation (29) 29
activation (28) 28
functionalization (28) 28
carbon-hydrogen bonds (24) 24
rhodium (24) 24
directing group (21) 21
bond activation (20) 20
alkynes (19) 19
index medicus (18) 18
olefins (18) 18
direct arylation (17) 17
aryl hydrogen phosphates (16) 16
derivatives (16) 16
h bond activation (16) 16
internal alkynes (15) 15
olefination (15) 15
ruthenium (14) 14
organic-synthesis (13) 13
room-temperature (13) 13
molecular structure (12) 12
open atmosphere (12) 12
arenes (11) 11
arylation (11) 11
coupling reaction (11) 11
hydroarylation (11) 11
ortho-arylation (11) 11
aldehydes (10) 10
chemical properties (10) 10
directing groups (10) 10
organic chemistry (10) 10
ortho-olefination (10) 10
aromatic compounds (9) 9
catalyzed ortho-alkenylation (9) 9
chemistry, physical (9) 9
cyclization (9) 9
palladium (9) 9
regioselective synthesis (9) 9
alkenes - chemistry (8) 8
analysis (8) 8
annulation (8) 8
benzoic-acids (8) 8
cross-coupling reactions (8) 8
c–h activation (8) 8
functionalisation (8) 8
funktionalisierung (8) 8
ketones (8) 8
one-pot synthesis (8) 8
rhodium - chemistry (8) 8
terminal alkynes (8) 8
aromatic-substitution (7) 7
bond formation (7) 7
c-h functionalization (7) 7
catalysts (7) 7
chemistry, applied (7) 7
coupling reactions (7) 7
direct ortho-alkenylation (7) 7
efficient synthesis (7) 7
katalyse (7) 7
organometallic compounds - chemistry (7) 7
oxidizing directing group (7) 7
alkene (6) 6
aromatic imines (6) 6
aromatic ketones (6) 6
bonding (6) 6
c-h bond (6) 6
chemical reactions (6) 6
cleavage (6) 6
c−h activation (6) 6
ch activation (6) 6
direct ortho arylation (6) 6
homogeneous catalysis (6) 6
indole synthesis (6) 6
mild conditions (6) 6
n bond formation (6) 6
oxidant (6) 6
oxidative alkenylation (6) 6
regioselectivity (6) 6
rhodium catalysis (6) 6
alkylation (5) 5
amides (5) 5
aryl ketones (5) 5
asymmetric catalysis (5) 5
c-c (5) 5
complexes (5) 5
direct arylations (5) 5
esters (5) 5
functional groups (5) 5
functional-group (5) 5
funktionelle gruppe (5) 5
o bond (5) 5
oxidationsmittel (5) 5
oxidative olefination (5) 5
palladium-catalyzed ortho-arylation (5) 5
rhodium-catalyzed ortho-alkenylation (5) 5
stereoisomerism (5) 5
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Organic Letters, ISSN 1523-7060, 11/2012, Volume 14, Issue 21, pp. 5506 - 5509
Ruthenium(II)-catalyzed redox-neutral annulative coupling of N-sulfonyl imines with alkynes has been achieved for the synthesis of indenamines, where a... 
DIRECT ORTHO-ALKENYLATION | 3+2 ANNULATION | AROMATIC KETIMINES | ACTIVATION | C-H BOND | ONE-POT SYNTHESIS | RHODIUM(III)-CATALYZED SYNTHESIS | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | CIS-ADDITION | ISOQUINOLINIUM SALTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 35, pp. 12249 - 12251
Journal Article
ACS Catalysis, ISSN 2155-5435, 08/2016, Volume 6, Issue 8, pp. 5520 - 5529
Herein, we report the ruthenium-catalyzed ortho C–H alkenylation of a wide range of N-aryloxazolidinone scaffolds. Alkenylation was achieved with complete... 
ruthenium | kinetic isotope effect | C-H activation | DFT | homogeneous catalysis | heterocycles | AROMATIC KETONES | DIRECT ORTHO ARYLATION | N-ARYLOXAZOLIDINONES | CHEMISTRY, PHYSICAL | ANTITHROMBOTIC AGENT | DISCOVERY | ALKENES | CATALYZED ORTHO-ALKENYLATION | BOND ACTIVATION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 40, pp. 9472 - 9475
A novel cyclic N-phosphoryl ketimine structure can efficiently react with olefins as useful directing groups to construct a myriad of phosphate scaffolds via... 
POLYHETEROAROMATIC COMPOUNDS | 3+2 ANNULATION | SULFONYL KETIMINES | ORTHO-OLEFINATION | S BOND | INTERNAL OXIDANT | CATALYZED ORTHO-ALKENYLATION | CHEMISTRY, ORGANIC | ARYL HYDROGEN PHOSPHATES | BOND ACTIVATION | C-H ACTIVATION
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 08/2017, Volume 4, Issue 8, pp. 1482 - 1492
Using density functional theory (DFT) calculations, the present study explores the mechanisms of two ruthenium(II)-catalyzed phosphoryl-directed... 
CYCLOADDITION | ELEMENTS | POTENTIAL BASIS-SETS | MOLECULAR-ORBITAL METHODS | CHEMISTRY, ORGANIC | GAUSSIAN-TYPE BASIS | ORTHO-ARYLATION | POLARIZATION FUNCTIONS | ARYL PHOSPHATES | CYCLIZATION | ORTHO-ALKENYLATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 04/2014, Volume 47, Issue 4, pp. 1208 - 1219
Rapid progress in the fields of organometallic chemistry and homogeneous catalysis has made it possible for synthetic chemists to consider using ubiquitous yet... 
MILD | ORTHO-ALKYLATION | DIRECT ARYLATION | ARYLZINC REAGENTS | COMPLEXES | AROMATIC IMINES | BOND ACTIVATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | ORTHO-ALKENYLATION | Transition metals | Catalysts | Chlorides | Olefins | Transformations | Catalysis | Cobalt | Alkynes
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4662 - 4665
Synthesis of 3-(indol-2-yl)­succinimide derivatives is presented using a directing group strategy. Selective functionalization of C-2 in the presence of highly... 
DIRECTING GROUP | FUNCTIONALIZATION | ALKENES | DIRECT C2-OLEFINATION | ATOM ECONOMY | RING-OPENING REACTIONS | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | BOND ACTIVATION | DERIVATIVES | ORTHO-ALKENYLATION
Journal Article
Chemical Communications, ISSN 1359-7345, 8/2017, Volume 53, Issue 64, pp. 8931 - 8947
The transition-metal-catalyzed chelation-assisted alkenylation at the inert C-H bond of aromatics with alkenes is one of the efficient methods to synthesize... 
DIRECT ORTHO-ALKENYLATION | DIRECTING GROUP | ASYMMETRIC 1,4-ADDITION | RUTHENIUM-CATALYZED CYCLIZATION | COUPLING REACTION | BOND ACTIVATION | ARYL KETONES | INTERNAL ALKYNES | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | OXIDATIVE ALKENYLATION
Journal Article