X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
ortho-arylation (261) 261
chemistry, organic (246) 246
chemistry, multidisciplinary (197) 197
catalysis (148) 148
activation (145) 145
functionalization (127) 127
palladium (121) 121
c-h activation (116) 116
index medicus (74) 74
direct ortho arylation (71) 71
derivatives (67) 67
room-temperature (64) 64
carbon-hydrogen bonds (60) 60
bond activation (55) 55
cross-coupling reactions (54) 54
alkenylation (52) 52
arenes (52) 52
directing group (50) 50
arylation (49) 49
chemical properties (49) 49
catalyzed ortho-arylation (48) 48
coupling reactions (47) 47
organic-synthesis (44) 44
c-h bonds (43) 43
palladium - chemistry (43) 43
simple arenes (42) 42
benzoic-acids (41) 41
molecular structure (40) 40
analysis (39) 39
alkylation (37) 37
c-h functionalization (37) 37
complexes (36) 36
ruthenium (36) 36
aromatic compounds (35) 35
aryl halides (34) 34
boronic acids (34) 34
cyclization (33) 33
direct ortho-arylation (33) 33
bond formation (32) 32
chemistry, inorganic & nuclear (32) 32
rhodium (32) 32
acids (30) 30
anilide ortho-arylation (29) 29
aryl (29) 29
carboxylic-acids (29) 29
h bond activation (29) 29
chemistry, applied (28) 28
ligands (27) 27
aromatic ketones (26) 26
chemistry, physical (26) 26
phenols (26) 26
sodium persulfate (26) 26
aryl chlorides (25) 25
aryl iodides (24) 24
c-h bond (24) 24
olefination (24) 24
synthesis (24) 24
halides (23) 23
ketones (23) 23
c−h activation (22) 22
directing groups (22) 22
palladium catalysts (22) 22
anilides (21) 21
catalysts (21) 21
c–h activation (21) 21
one-pot synthesis (21) 21
alkenes (20) 20
article (20) 20
chemical sciences (20) 20
coupling reaction (20) 20
heterocycles (20) 20
structure (20) 20
aldehydes (19) 19
alkynes (19) 19
arylboronic acids (19) 19
chemistry (19) 19
organic chemistry (19) 19
palladium catalysis (19) 19
amination (18) 18
bond functionalization (18) 18
carbon - chemistry (18) 18
stereoisomerism (18) 18
aryl hydrogen phosphates (17) 17
bonding (17) 17
c-h bond activation (17) 17
cleavage (17) 17
cross-coupling (17) 17
indoles (17) 17
organometallic compounds - chemistry (17) 17
research (17) 17
unactivated arenes (17) 17
amides (16) 16
c-h (16) 16
chemical reactions (16) 16
homogeneous catalysis (16) 16
olefins (16) 16
oxidation-reduction (16) 16
regioselectivity (16) 16
efficient synthesis (15) 15
hydrogen - chemistry (15) 15
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15509 - 15512
Oxidative coupling between C((sp2)))-H bonds and C((sp3)))-H bonds is achieved by the Ni(II)-catalyzed reaction of benzamides containing an 8-aminoquinoline... 
H BOND ACTIVATION | FUNCTIONALIZATION | CATALYZED ORTHO-ARYLATION | FLUOROALKYLATION | C-C | PERFLUOROALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ALKYL-HALIDES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 8/2012, Volume 41, Issue 17, pp. 5588 - 5598
In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed oxidative coupling via C-H functionalization of aromatic, benzylic... 
H BOND ACTIVATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | COUPLING REACTIONS | CARBON-CARBON BONDS | ORTHO-ARYLATION | UNACTIVATED ARENES | GRIGNARD-REAGENT | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ARYLBORONIC ACIDS
Journal Article
by Wang, DH and Wasa, M and Giri, R and Yu, JQ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2008, Volume 130, Issue 23, pp. 7190 - 7190
O-Methyl hydroxamic acids, readily available from carboxylic acids, are found to be extremely reactive for P-C-H activation by Pd(OAC)(2). This reactivity is... 
SCOPE | MECHANISTIC INSIGHTS | ORTHO-ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | ARYLBORONIC ACIDS | PALLADIUM-CATALYZED ALKYLATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 07/2016, Volume 49, Issue 7, pp. 1389 - 1400
CONSPECTUS: Direct C-H bond activation is an important reaction in synthetic organic chemistry. This methodology has the potential to simplify reactions by... 
CATELLANI ORTHO-ARYLATION | PALLADIUM/NORBORNENE CATALYSIS | REACTION SEQUENCE | NORBORNENE | PALLADIUM-CATALYZED SYNTHESIS | ALKYLATION | COUPLING REACTION | TOSYLHYDRAZONE INSERTION REACTION | ARYL IODIDES | 6H-DIBENZOPYRAN DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 08/2005, Volume 7, Issue 17, pp. 3657 - 3659
[GRAPHICS] A method for the palladium-catalyzed arylation of pyridines and pyrazoles has been developed. Both aliphatic and aromatic CA bonds may be... 
FUNCTIONALIZATION | ACTIVATION | ALKYL | COMPLEXES | 2-ARYLPYRIDINES | DIRECT ORTHO ARYLATION | CHEMISTRY, ORGANIC
Journal Article
Organic Letters, ISSN 1523-7060, 02/2011, Volume 13, Issue 4, pp. 706 - 708
The ruthenium-catalyzed oxidative vinylation of thiophene-2-carboxylic acids with alkenes efficiently proceeds through directed C-H bond cleavage to give the... 
DIRECT ORTHO-ARYLATION | FUNCTIONALIZATION | PALLADIUM | CINNAMIC-ACIDS | CARBON | CROSS-COUPLING REACTION | AROMATIC KETONES | CHEMISTRY, ORGANIC | ARYL | ALKENYLATION | BENZOIC-ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 50, pp. 15636 - 15639
The first methodology for Au(I/III)-catalyzed oxidative cross-coupling of arenes via double C-H activation has been developed. The reaction is fully selective... 
ORGANIC GOLD COMPOUNDS | FUNCTIONALIZATION | POLYFLUOROARENES | ARYL HALIDES | CHEMISTRY | BOND ACTIVATION | ORTHO-ARYLATION | OXIDATIVE ADDITION | DIRECT ALKYNYLATION | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 41, pp. 14349 - 14352
We report here that an iron-catalyzed directed CH functionalization reaction allows the coupling of a variety of aromatic, heteroaromatic, and olefinic... 
BORONIC ACIDS | ACTIVATION | ALKYL | IMINES | ARYL | CARBOXAMIDES | ORTHO-ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ALKENYLATION | METATHESIS
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8977 - 9015
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 5/2016, Volume 45, Issue 1, pp. 29 - 2936
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 09/2010, Volume 12, Issue 17, pp. 3926 - 3929
A Pd-catalyzed protocol for direct C-H bond acylation by cross coupling of aryl ketone oximes and aldehydes using fert-butyl hydroperoxide (TBHP) as oxidant... 
ORGANIC-SYNTHESIS | IODIDES | ACIDS | ACYL RADICALS | COMPLEXES | CHEMISTRY, ORGANIC | ORTHO-ARYLATION | DIRECT ACCESS | H BOND FUNCTIONALIZATION | BROMIDES
Journal Article
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2013, Volume 42, Issue 13, pp. 5744 - 5767
The metal-catalysed successive activation and functionalisation of sp(2) C-H bonds is the at heart of synthetic innovations for the development of C-C bond... 
DIRECTING GROUP | ROOM-TEMPERATURE | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | ANILIDE ORTHO-ARYLATION | HYDROGEN/DEUTERIUM EXCHANGE-REACTIONS | RUTHENIUM-HYDRIDE COMPLEX | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | HYDROGEN-DEUTERIUM EXCHANGE | CONJUGATE ADDITION
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 09/2015, Volume 2, Issue 9, pp. 1107 - 1295
Transition metal-catalyzed direct functionalization of C-H bonds is one of the key emerging strategies that is currently attracting tremendous attention with... 
DIRECT ORTHO-ARYLATION | BIDENTATE-CHELATION ASSISTANCE | QUINOLINE N-OXIDES | UNACTIVATED C(SP)-H BONDS | ONE-POT SYNTHESIS | AROMATIC AZO-COMPOUNDS | PD(II)-CATALYZED ORTHO-TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | ALPHA-OXOCARBOXYLIC ACIDS | DECARBOXYLATIVE ORTHO-ACYLATION | CARBON-HYDROGEN BONDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 49, pp. 16474 - 16475
The oxidative synthesis of highly functionalized indoles from simple anilines and internal alkynes mediated by a rhodium(III) catalyst is described. Good... 
PALLADIUM | KETONES | ORTHO-ARYLATION | 2,3-DISUBSTITUTED INDOLES | BOND-CLEAVAGE | ANILIDES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ANNULATION | CYCLIZATION | O-HALOANILINES | Rhodium | Aniline | Ionization | Indole | Analysis | Chemical properties | Catalysis
Journal Article
Organometallics, ISSN 0276-7333, 11/2014, Volume 33, Issue 22, pp. 6704 - 6707
Palladium-catalyzed regioselective homocoupling of arylpyridines under anodic oxidation conditions was achieved in the presence of I-2. The dimerization of... 
ACTIVATION | COUPLING REACTIONS | CHEMISTRY, ORGANIC | IODINATION | ORTHO-ARYLATION | C-H FUNCTIONALIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2006, Volume 128, Issue 39, pp. 12634 - 12635
Journal Article