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Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 46, pp. 16318 - 16320
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 11/2016, Volume 453, pp. 310 - 320
The Cp2M2H2(CO)n (M=Ir, Os, Re; n=3, 2, 1) systems, related to the experimentally known and structurally characterized permethylated derivatives Cp∗2M2H2(CO)2... 
Metal hydrides | Cyclopentadienylmetal carbonyls | Density functional theory | Iridium | Rhenium | Osmium | CYTOCHROME-P450 | ENERGY | BEHAVIOR | COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | DENSITY FUNCTIONALS | TRANSITION | METAL-CARBONYLS | GAS | BASIS-SETS | BOND | Density functionals | Yuan (China)
Journal Article
Organometallics, ISSN 0276-7333, 01/2007, Volume 26, Issue 2, pp. 321 - 331
Reactions of the 30-electron hydride [Mo2Cp2(μ-H)(μ-PCy2)(CO)2] (Cp = η5-C5H5) with the 17-electron-fragment precursors [M2Cp2(CO) n ] (M = Mo, W, n = 6; M =... 
SUBSTITUTION | HETERONUCLEAR CLUSTER | COMPLEXES | SOLID-STATE STRUCTURE | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | DIMOLYBDENUM | X-RAY STRUCTURES | CHAIN CLUSTERS | OSMIUM | STRUCTURAL CHARACTERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 11/2016, Volume 453, p. 310
The Cp2M2H2(CO)n (M = Ir, Os, Re; n = 3, 2, 1) systems, related to the experimentally known and structurally characterized permethylated derivatives... 
Hydrogen-based energy | Hydrogen | Metals | Crystallography | Osmium | Low energy | X rays | Bridging | Hydrogen atoms | Iridium | Rhenium | Atomic structure | Electrons | Carbonyls
Journal Article
Journal of Cluster Science, ISSN 1040-7278, 1/2014, Volume 25, Issue 1, pp. 239 - 252
An overview of the dynamical processes involving the hydrido ligand in triosmium and triruthenium carbonyl clusters is presented. The relationship between the... 
Chemistry | Physical Chemistry | Dynamics | Triruthenium | Triosmium | Hydride | Catalysis | Inorganic Chemistry | Carbonyl | H2OS3(CO)10L | ANION | CRYSTAL-STRUCTURE | COMPLEXES | RUTHENIUM | CHEMISTRY, INORGANIC & NUCLEAR | REARRANGEMENT | CHEMISTRY | LIGAND | Quinoline | Hydrogen | Clusters | Ligands | Hydrides | Terminals | Phosphines | Osmium | Carbonyls
Journal Article
Russian Chemical Bulletin, ISSN 1066-5285, 5/2013, Volume 62, Issue 5, pp. 1191 - 1194
Journal Article
Journal of Catalysis, ISSN 0021-9517, 08/2013, Volume 304, pp. 1 - 6
Hybrid photocatalytic systems by coupling CdS (as photosensitizer) with a series of Ru complexes (as active electro-catalyst) showed activity for hydrogenation... 
Photocatalytic | Visible light | CdS | Ru carbonyl complex | Hydrogenation | Mechanism | OXIDATION | SEMICONDUCTOR | CO2 REDUCTION | CONVERSION | DIOXIDE | PHOTOCATALYTIC PRODUCTION | CHEMISTRY, PHYSICAL | CATALYST | OSMIUM(II) | HYDRIDE | ENGINEERING, CHEMICAL | H-2 EVOLUTION | Composite materials industry | Ruthenium
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 05/2015, Volume 784, pp. 46 - 51
The gold phosphine group in the complex Os3(CO)10(μ-η1-Ph)(μ-AuPPh3), 1 can be replaced by mercury halide groups by reactions with mercury halides. The... 
Cubane | Bridging phenyl | Mercury | Benzyne | Osmium | BEHAVIOR | ARYL LIGANDS | REACTIVITY | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | CLEAVAGE | TRIPHENYLPHOSPHINE | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR | DERIVATIVES | TRANSFORMATIONS | Benzyne No items selected | Carbocyclic compounds | Analysis | Cyclohexane
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 06/2018, Volume 478, p. 25
The reaction of the electron-deficient 6-methoxyquinolinate-substituted triosmium cluster [Os3(CO)9{μ3-η1,κ1-C9H5N(6-OMe)}(μ-H)] (1) with PPh3 proceeds readily... 
Substitutes | Toluene | Isomerization | Clusters | Ligands | Hydrides | Nitrogen | Crystallography | Isomers | Osmium | Electrons | Carbonyls
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 21, pp. 3436 - 3439
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2016, Volume 55, Issue 44, pp. 13749 - 13753
The aromatic osmacyclopropenefuran bicycles [OsTp{κ3‐C1,C2,O‐(C1H2C2CHC(OEt)O)}(PiPr3)]BF4 (Tp=hydridotris(1‐pyrazolyl)borate) and... 
allenes | metallaheterobicycles | osmium | hydration | aromaticity | OSMACYCLES | DIHYDROGEN COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | H BOND ACTIVATION | SIGMA-AROMATICITY | KETONES | RING | CARBONYL CLUSTERS | DERIVATIVES | Analysis | Bicycles | Hydration | Aromaticity | Allene | Metals | Intermediates
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2015, Volume 44, Issue 11, pp. 5160 - 5169
The 62-electron oxo-capped tetrairon butterfly cluster, Fe-4(CO)(10)(kappa(2)-dppn)(mu(4)-O) (1) {dppn = 1,8-bis-(diphenylphosphino)naphthalene}, undergoes... 
ELECTRON-TRANSFER | FE-ONLY HYDROGENASE | MOLECULAR-STRUCTURE | ACTIVE-SITE | CRYSTAL-STRUCTURE | STRUCTURAL-CHARACTERIZATION | IRON | METAL-CLUSTERS | OSMIUM CARBONYL HYDRIDES | BUTTERFLY CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2005, Volume 690, Issue 2, pp. 371 - 382
The reactivity of phosphine substituted ruthenium carbonyl carboxylates Ru(CO) 2(MeCOO) 2(PBu 3) 2, Ru 2(CO) 4(μ-MeCOO) 2(PBu 3) 2, Ru 4(CO) 8(μ-MeCOO) 4(PBu... 
Ruthenium | Carbonyl carboxylates | Acetic acid | Hydrogenation | PLATINUM METALS | HYDRIDES | CHEMISTRY, ORGANIC | hydrogenation | CHEMISTRY, INORGANIC & NUCLEAR | ruthenium | REDUCTION | MONOXIDE | acetic acid | RUTHENIUM COMPLEXES | CHEMISTRY | OSMIUM | carbonyl carboxylates | CARBOXYLIC-ACIDS
Journal Article
Organometallics, ISSN 0276-7333, 02/2004, Volume 23, Issue 3, pp. 441 - 445
Absolute rate constants for hydrogen atom abstraction by benzyl radical from Os3(μ-H)2(CO)9PPh3 (1), Os3(μ-H)(H)(CO)10PPh3 (2), Os3(μ-H)(CO9)(μ3-η2-C9H6N) (3),... 
TRANSITION-METAL HYDRIDES | CARBONYL SUBSTITUTION | MECHANISM | CRYSTAL-STRUCTURE | COMPLEXES | CHEMISTRY, ORGANIC | BOND | SPECTRA | OSMIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 09/2003, Volume 22, Issue 20, pp. 4084 - 4089
The rate constants for hydride transfer from CpRu(P−P)H (P−P = bis(diphenylphosphino)methane (dppm), bis(diphenylphosphino)ethane (dppe),... 
TRANSITION-METAL HYDRIDES | KINETIC HYDRICITY | HALIDE ION | BOND-DISSOCIATION ENERGIES | TRITYL CATION | CARBONYL HYDRIDES | COMPLEXES | CHEMISTRY, ORGANIC | X-RAY STRUCTURE | ASYMMETRIC HYDROGENATION | CYCLOPENTADIENYL-OSMIUM CHEMISTRY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 05/2017, Volume 836-837, pp. 68 - 80
Heating a benzene solution of the unsaturated cluster Os3(CO)8(μ-dppm)(μ-H)2 (1) [dppm = bis(diphenylphosphino)methane] with MeO2CCCCO2Me (DMAD) or... 
Diphosphines | DFT | Unsaturated osmium clusters | Reversible C-H bond activation | C-C bond scission | Activated alkynes
Journal Article
JOURNAL OF MOLECULAR STRUCTURE, ISSN 0022-2860, 10/2015, Volume 1097, pp. 157 - 160
X-ray and spectroscopic data for the new complex (mu-H)(mu-OCH3)Os-3(CO)(9){:C(CD3)NC2H8O) (2) obtained in the reaction of the... 
TRANSFORMATION | Ligand substitution | Fisher type carbenes | CH-acidity | TRIOSMIUM CLUSTERS | CHEMISTRY, PHYSICAL | CRYSTAL | Cluster carbenes | LIGAND | Osmium clusters | OSMIUM CARBONYL HYDRIDES
Journal Article
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