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Journal of Organometallic Chemistry, ISSN 0022-328X, 2010, Volume 695, Issue 10, pp. 1435 - 1440
The activated alkyne, RC CR (R = CO 2Me), readily inserts into the hydride of unsaturated [Os 3(CO) 9(μ 3-C 7H 4NS)(μ-H)] to give a series of isomeric alkenyl... 
Carbon–carbon bond formation | Carbonyl | Alkenyl isomerism | Osmium | X-ray structures | Carbon-carbon bond formation | TRIOSMIUM CLUSTER | DIAZOMETHANE | CRYSTAL-STRUCTURE | HYDRIDES | ISOMERIZATION | H2OS3(CO)10 | CHEMISTRY, ORGANIC | ALKYNES | CHEMISTRY, INORGANIC & NUCLEAR | HYDROGEN | REDUCTION | CHEMISTRY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2016, Volume 22, Issue 19, pp. 6501 - 6504
The reaction of Os3(CO)10(NCMe)2 with closo‐o‐C2B10H10 has yielded two interconvertible isomers Os3(CO)9(μ3‐4,5,9‐C2B10H8)(μ‐H)2 (1 a) and... 
crystal structure | osmium | carborane | cage-opening | clusters | Metals | Triangles | Clusters | Ligands | Carborane | Yield | Cages | Coordination compounds | Bonding | Isomers | Cobalt | Osmium | Cage | Metal clusters
Journal Article
Organometallics, ISSN 0276-7333, 04/2012, Volume 31, Issue 7, pp. 2582 - 2588
Reactions of the tetrahedral clusters Mo2Ir2(μ-CO)3(CO)7(η5-L)2 (L = C5H5, C5HMe4) with the molybdenum alkylidyne complex Mo(CC6H4OMe-4)(CO)2{(N2C3H3)3BH-κ3... 
TUNGSTEN-IRIDIUM CLUSTERS | MOLECULAR-STRUCTURE | MOLYBDENUM | CARBYNE LIGANDS | RAY CRYSTAL-STRUCTURES | OXO | REACTIVITY | CHEMISTRY, ORGANIC | MULTIPLE BONDS | OSMIUM CARBONYL HYDRIDES | BRIDGING CARBENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2019, Volume 880, pp. 223 - 231
Journal Article
Modern Physics Letters A, ISSN 0217-7323, 03/2016, Volume 31, Issue 7, p. 1650045
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 06/2016, Volume 812, pp. 108 - 114
The compounds Os5(CO)15(μ3-AuPPh3)2, 2 and Os5(CO)14[μ4-Au3(PPh3)3](μ3-AuPPh3), 3 were obtained from the reaction of [PPN]2[Os5(CO)15] using [Au(PPh3)][NO3].... 
Gold | Cluster | Methyl ligand | Osmium | Crystal structure | SELECTIVE OXIDATION | CATALYZED ORGANIC-REACTIONS | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | PALLADIUM NANOPARTICLES | CHEMISTRY, INORGANIC & NUCLEAR | RAY CRYSTAL-STRUCTURES | MOLECULAR-STRUCTURES | SOLVENT-FREE OXIDATION | FISCHER-TROPSCH SYNTHESIS | Structure | Crystals | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2013, Volume 52, Issue 46, pp. 12110 - 12113
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 05/2015, Volume 783, pp. 46 - 48
The room temperature reaction of Os3(CO)11(NCCH3) with BiPh3 afforded the substituted derivative Os3(CO)11(BiPh3) which decomposed rapidly. The X-ray... 
Carbonyl cluster | Bismuth | Osmium
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 05/2007, Volume 46, Issue 11, pp. 4605 - 4611
The reactions of the osmium−tin cluster complexes Os3(CO)12(μ3-SnPh)Ph, 9, and Os4(CO)16(μ4-Sn), 10, with Pt(PBut 3)2 have been investigated. Two products,... 
DYNAMICAL ACTIVITY | PALLADIUM | OS-3(CO) | PLATINUM | CATALYST | LIGAND | CHEMISTRY, INORGANIC & NUCLEAR | Tin compounds | Diffraction | Analysis | X-rays | Chemical bonds | Chemical properties | Structure | Clusters (Chemistry) | Platinum compounds | Osmium
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 18, pp. 2935 - 2942
Reaction of [Mn 2(CO) 9(NCMe)] with tetrahydropyrimidine-2-thione (thpymSH) at 25 °C furnishes the mono- and dinuclear complexes [Mn(CO) 4(κ 1:η 1-SCNHC 3H... 
Iron | Ruthenium | Tetrahydropyrimidine-2-thione | Osmium | Manganese | Carbonyls | ANIONS | CARBONYL-COMPLEXES | POLAR METAL | CRYSTAL-STRUCTURE | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | Military leaders
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2013, Volume 744, pp. 24 - 34
The reaction of 2-[(diphenylphosphino)methyl]-6-methylpyridine (PN) with Os3(CO)12−n(MeCN)n [where n = 0 (1), 1 (2), 2 (3)] has been investigated. Os3(CO)12... 
X-ray crystallography | Phosphinopyridine ligand | P–C and C–H bond activation | DFT | Osmium clusters | PeC and CeH bond activation
Journal Article
Computational and Theoretical Chemistry, ISSN 2210-271X, 02/2017, Volume 1101, pp. 127 - 131
[Display omitted] •The Os3N3+ (D3h, 7A1′) cation and Os3N3− (D3h, 5A1′) anion possess triple (σ-, π- and δ-) aromaticity.•Five types of σt-, σr-, πt-, πr-, and... 
DFT calculation | Osmium low-nitride clusters | Triple (σ-π- and δ-) aromaticity | THIN-FILMS | Triple (sigma-pi- and delta-) aromaticity | STABILITY | AB-INITIO | COMPLEXES | CHEMISTRY, PHYSICAL | TRANSITION-METAL NITRIDES | 1ST PRINCIPLES | OXIDE CLUSTERS | ALKALI-METAL | ELECTRONIC-STRUCTURE | PHOTOELECTRON-SPECTROSCOPY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2019, Volume 2019, Issue 14, pp. 1966 - 1969
The room temperature reaction of [Os3(CO)12] (1) with three molar equivalents of [PtCl(allyl)(NHC)] (2) in the presence of KOtBu afforded the heterometallic... 
Carbene ligands | Carbonyl ligands | Platinum | Osmium | Heterometallic complexes | NANOCATALYSTS | COMPLEXES | RUTHENIUM | CHEMISTRY, INORGANIC & NUCLEAR | Heterocyclic compounds | Clusters
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 01/2014, Volume 53, Issue 2, pp. 1210 - 1216
The reaction of Ru3(CO)12 with Pt(IMes)2 in benzene solvent at room temperature afforded the monoplatinum–triruthenium cluster complex Ru3Pt(IMes)2(CO)11, 1,... 
NANOPARTICLE CATALYSTS | ROOM-TEMPERATURE | OLEFIN METATHESIS CATALYSTS | BUCHWALD-HARTWIG | HYDROGENATION CATALYSTS | HYDROSILYLATION | SINGLE-STEP | OSMIUM | PALLADIUM/IMIDAZOLIUM SALT SYSTEMS | SUZUKI-MIYAURA | CHEMISTRY, INORGANIC & NUCLEAR | Ruthenium | Platinum | Analysis | Chemical properties | Chemical synthesis | Structure | Carbenes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2005, Volume 127, Issue 8, pp. 2380 - 2381
A self-assembled monolayer (SAM) of a C60−triosmium cluster complex Os3(CO)7(CNR)(CNR‘)(μ 3-η 2:η 2:η 2-C60) (ZnP − C 60 ; R = (CH2)3Si(OEt)3, R‘ = ZnP) on an... 
ENERGY | SELF-ASSEMBLED MONOLAYERS | FILMS | FULLERENE DYADS | ARTIFICIAL PHOTOSYNTHESIS | COMPLEXES | DEVICES | C-60 | CHEMISTRY, MULTIDISCIPLINARY | COMMUNICATION | SURFACES | Research | Electron transport | Carbon | Electric properties | Porphyrins
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 08/2017, Volume 1141, pp. 115 - 118
Dichloroacetonitrile undergoes hydrogenation by triosmium dihydride cluster under mild conditions. The reaction of cluster complex (μ-H)2Os3(CO)10 (1) with... 
Osmium clusters | Hydrogenation | Transition metal cluster hydrides
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 09/2016, Volume 642, Issue 19, pp. 1104 - 1111
Journal Article
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