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Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2015, Volume 21, Issue 45, pp. 16126 - 16135
A tetranuclear Ce-IV oxo cluster compound containing the Klaui tripodal ligand [Co((5)-C5H5){P(O)(OEt)(2)}(3)](-) (L-OEt(-)) has been synthesized and its reactions with H2O2, CO2, NO, and BrOnsted acids have been studied... 
tetravalent | tripod ligands | cerium | clusters | oxo | TETRAVALENT CERIUM | WATER-GAS SHIFT | MOLECULAR-STRUCTURE | BOND-VALENCE PARAMETERS | CHEMISTRY, MULTIDISCIPLINARY | METAL-LANTHANIDE COMPLEXES | RAY CRYSTAL-STRUCTURE | TEMPLATE SYNTHESIS | CARBON-MONOXIDE | OXIDATION-STATES | PEROXO COMPLEXES
Journal Article
Environmental Science & Technology, ISSN 0013-936X, 05/2013, Volume 47, Issue 10, pp. 5146 - 5153
... to sorption behavior at low, environmentally relevant concentrations. Pu(IV) sorption to montmorillonite was studied at initial concentrations... 
ENVIRONMENTAL SCIENCES | REDUCTION | ENGINEERING, ENVIRONMENTAL | ZN SORPTION | PLUTONIUM | OXIDATION-STATE | NATURAL-WATERS | NA-MONTMORILLONITE | NEVADA TEST-SITE | ADSORPTION | NEPTUNIUM(V) SORPTION | MECHANISTIC DESCRIPTION | Thermodynamics | Plutonium - chemistry | Bentonite - chemistry | Adsorption
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2016, Volume 7, Issue 5, pp. 3286 - 3297
Against expectations the covalency in a cerium( )–carbon multiple bond interaction is essentially as covalent as the uranium( ) analogue. We report comparable... 
GROUND-STATE | OXIDATION-STATE | SMALL-MOLECULE ACTIVATION | X-RAY-ABSORPTION | CRYSTAL-STRUCTURES | BASIS-SETS | DENSITY-FUNCTIONAL THEORY | CARBENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | LIGAND REORGANIZATION | ELECTRONIC-STRUCTURE | Exchange | Covalence | Uranium | Ion exchangers | Computation | Chemical bonds | Trends | Bonding | Chemical Sciences
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 44, pp. 13762 - 13766
... on the redox activity of nickel complexes, and the following discovery of the oxidative activation of C−X and C−C bonds via Ni III and/or Ni IV intermediates, nickel... 
nickel | sulfur ligands | high oxidation states | redox chemistry | NICKEL-COMPLEXES | CATALYSIS | TRANSITION-METAL-COMPLEXES | OXIDATION-STATE | CRYSTAL-STRUCTURE | COMPOUND | HYDROXYLATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | NI(IV) COMPLEXES | LIGANDS | Sulfur compounds | Magnetism | Nickel | X-ray crystallography | Single crystals | Electrochemistry | Oxidation | Crystallography | Magnetic measurement
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 25, pp. 8718 - 8724
A reactive high-valent dinuclear nickel­(IV) oxido bridged complex is reported that can be formed at room temperature by reaction of [(L)2Ni­(II)2(μ-X)3]­X (X = Cl or Br... 
DIOXYGEN ACTIVATION | OXYGEN | ELECTRONIC-STRUCTURES | SERIES | L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE | NONHEME IRON ENZYMES | LIGANDS | OXIDATION-STATE | HYDROXYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H | Nickel compounds | Oxidation-reduction reaction | Chemical reactions | Usage | Chemical properties | Níquel | Reactivity | Chemical tests and reagents | Reactivitat | Nickel | Química | Proves i reactius
Journal Article
Environmental Science & Technology, ISSN 0013-936X, 07/2016, Volume 50, Issue 13, pp. 6948 - 6956
Pu­(IV) and Pu­(V) sorption to goethite was investigated over a concentration range of 10–15–10–5 M at pH 8... 
ENVIRONMENTAL SCIENCES | REDUCTION | HEMATITE | ENGINEERING, ENVIRONMENTAL | OXIDATION-STATE | SPECIATION | PU(V) | NEPTUNIUM | FAR-FIELD | ADSORPTION | MINERAL SURFACES | GROUNDWATER | Adsorption | Oxidation-Reduction | Plutonium - chemistry | GEOSCIENCES
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 1, pp. 164 - 167
The Pt-IV prodrug strategy has emerged as an excellent alternative to tackle the problems associated with conventional Pt-II drug therapy... 
platinum | cisplatin | prodrugs | glutathione | fluorescent probes | CANCER-CELLS | ACTIVATION | DESIGN | OXIDATION-STATE | CHEMISTRY, MULTIDISCIPLINARY | SATRAPLATIN | PEPTIDE | CONSTRUCTION | CYTOTOXICITY | CHEMODOSIMETER | Chemotherapy | Reduction | Platinum | Toxicity | Cytotoxicity | Fluorescent indicators | Intracellular | Cisplatin | Glutathione
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 2014, Volume 5, Issue 6, pp. 2489 - 2497
We report on the role of 5f-orbital participation in the unexpected inversion of the sigma-bond metathesis reactivity trend of triamidoamine thorium(IV) and uranium(IV) alkyls... 
OXIDATION-STATE | SMALL-MOLECULE ACTIVATION | TRANSITION-METAL | PYRIDINE N-OXIDE | INTRAMOLECULAR HYDROAMINATION | CHEMISTRY | C-H ACTIVATION | PHOSPHINE COMPLEXES | ACTINIDE | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE | Uranium | Computation | Decomposition reactions | Metathesis | Inversions | Trends | Bonding | Thorium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2016, Volume 138, Issue 18, pp. 6049 - 6060
This report describes a combined experimental and computational investigation of the mechanism of C­(sp3)–N bond-forming reductive elimination from... 
N-FLUOROBENZENESULFONIMIDE | MOLECULAR CALCULATIONS | HIGH-OXIDATION-STATE | EFFECTIVE CORE POTENTIALS | INTRAMOLECULAR AMINATION | BIOCHEMICAL PATHWAYS | GROWING STRING METHOD | CATALYZED DIAMINATION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 2012, Volume 389, pp. 77 - 84
Journal Article
Polyhedron, ISSN 0277-5387, 2017, Volume 133, pp. 393 - 397
The cerium(IV)-diolate complex with an 18 N-phenylaminediethanolate shell and a 13-nuclear cerium(IV... 
Cerium | Polymerization | ε-Caprolactone | Tetravalent | Crystal structure | TETRAVALENT CERIUM | AMMONIUM-NITRATE | OXIDE | OXIDATION-STATE | DIOLATE | CRYSTALLOGRAPHY | CHEMISTRY, INORGANIC & NUCLEAR | OXYGEN | NANOPARTICLES | CHEMISTRY | LACTIDE | epsilon-Caprolactone | WATER
Journal Article
Chemical Society reviews, ISSN 0306-0012, 11/2017, Volume 46, Issue 22, pp. 6697 - 6709
...(iv) compounds include organic synthesis, bioinorganic chemistry, materials science, and industrial catalysis... 
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 11/2017, Volume 46, Issue 22, pp. 6697 - 6709
...(IV) compounds include organic synthesis, bioinorganic chemistry, materials science, and industrial catalysis... 
TETRAVALENT CERIUM | GROUND-STATE | OXIDATION-STATE | COMPLEXES | CHEMISTRY | CEROCENE | LANTHANIDE | TRANSITION-METAL COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
Radiochimica Acta, ISSN 0033-8230, 04/2017, Volume 105, Issue 4, pp. 295 - 302
...-hydroxyisobutyric acid (HIBA). The three oxidation states of Pu viz. Pu(III), Pu(IV) and Pu(VI) were separated under optimised conditions... 
reversed Phase | liquid chromatography | Plutonium | α-hydroxyisobutyric acid | speciation | PLUTONIUM OXIDATION-STATES | alpha-hydroxyisobutyric acid | OXIDE | NUCLEAR SCIENCE & TECHNOLOGY | STABILITY | COMPLEXES | EXCHANGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article