Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 6, pp. 2200 - 2203
A range of Rh(III)-catalyzed ortho-C–H functionalizations have been developed; however, extension of this reactivity to remote C–H functionalizations through...
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | PHENOLS | ALKYLATION | ARYLATION | ARENES | BOND ACTIVATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Usage | Rhodium | Analysis | Chemical bonds | Ligands | Catalysis | Chemical properties
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | PHENOLS | ALKYLATION | ARYLATION | ARENES | BOND ACTIVATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Usage | Rhodium | Analysis | Chemical bonds | Ligands | Catalysis | Chemical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 39, pp. 13602 - 13605
Palladium-catalyzed coupling between aryl halides and alkenes (Mizoroki–Heck reaction) is one of the most popular reactions for synthesizing complex organic...
BIDENTATE-CHELATION ASSISTANCE | OXIDATIVE OLEFINATION | ACID-DERIVATIVES | OXIDIZING DIRECTING GROUP | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | CONJUGATED POLYMERS | PD(II)-CATALYZED OLEFINATION | CARBON-HYDROGEN BONDS | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | Palladium | Chemical properties | Hydrogen | Carbon compounds
BIDENTATE-CHELATION ASSISTANCE | OXIDATIVE OLEFINATION | ACID-DERIVATIVES | OXIDIZING DIRECTING GROUP | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | CONJUGATED POLYMERS | PD(II)-CATALYZED OLEFINATION | CARBON-HYDROGEN BONDS | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | Palladium | Chemical properties | Hydrogen | Carbon compounds
Journal Article
Chemical science, ISSN 2041-6520, 02/2018, Volume 9, Issue 5, pp. 1311 - 1316
Although chelation-assisted C-H olefination has been intensely investigated, Pd(ii)-catalyzed C-H olefination reactions are largely restricted to acrylates and...
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2016, Volume 358, Issue 4, pp. 573 - 583
A rhodium(III)‐catalyzed direct ortho CH bond olefination of arenes, including but not limited to benzamides, arylpyridines and indoles, with a variety of...
benzamides | indoles | pyridines | olefination | rhodium | DIRECT ARYLATION | LATE-STAGE DIVERSIFICATION | CHEMISTRY, ORGANIC | AROMATIC-SUBSTITUTION | MIZOROKI-HECK | CATALYZED OXIDATIVE OLEFINATION | ORTHO-ALKENYLATION | COUPLING REACTIONS | REGIOSELECTIVE SYNTHESIS | N BOND FORMATION | CHEMISTRY, APPLIED | DEHYDROGENATIVE HECK REACTION | Stereoselectivity | Silver | Aromatic compounds | Olefins | Catalysis | Bonding | Acetates | Aliphatic compounds
benzamides | indoles | pyridines | olefination | rhodium | DIRECT ARYLATION | LATE-STAGE DIVERSIFICATION | CHEMISTRY, ORGANIC | AROMATIC-SUBSTITUTION | MIZOROKI-HECK | CATALYZED OXIDATIVE OLEFINATION | ORTHO-ALKENYLATION | COUPLING REACTIONS | REGIOSELECTIVE SYNTHESIS | N BOND FORMATION | CHEMISTRY, APPLIED | DEHYDROGENATIVE HECK REACTION | Stereoselectivity | Silver | Aromatic compounds | Olefins | Catalysis | Bonding | Acetates | Aliphatic compounds
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2014, Volume 356, Issue 5, pp. 1038 - 1046
A rhodium(III)‐catalyzed selective olefination of picolinamide derivatives has been developed. The reaction shows high regioselectivity, low catalyst loading...
CH activation | oxidative olefination | pyridines | rhodium | C-H activation | DIRECTING GROUP | DIRECT ARYLATION | PYRIDINE-N-OXIDES | CHEMISTRY, ORGANIC | NICKEL/LEWIS ACID CATALYSIS | SELECTIVE ALKENYLATION | AROMATIC-SUBSTITUTION | C-H ACTIVATION | SCALE SYNTHESIS | CH activation | IMINOPYRIDINIUM YLIDES | BOND ACTIVATION | CHEMISTRY, APPLIED | Rhodium | Pyridine | Synthesis | Catalysts | Strategy | Tolerances | Derivatives | Catalysis | Functional groups
CH activation | oxidative olefination | pyridines | rhodium | C-H activation | DIRECTING GROUP | DIRECT ARYLATION | PYRIDINE-N-OXIDES | CHEMISTRY, ORGANIC | NICKEL/LEWIS ACID CATALYSIS | SELECTIVE ALKENYLATION | AROMATIC-SUBSTITUTION | C-H ACTIVATION | SCALE SYNTHESIS | CH activation | IMINOPYRIDINIUM YLIDES | BOND ACTIVATION | CHEMISTRY, APPLIED | Rhodium | Pyridine | Synthesis | Catalysts | Strategy | Tolerances | Derivatives | Catalysis | Functional groups
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2016, Volume 6, Issue 6, pp. 3708 - 3712
A cooperative photoredox and asymmetric catalysis for the enantioselective aerobic oxidative C(sp3)–H olefination of tetrahydro-β-carbolines (THCs) is...
organocatalysis | photoredox catalysis | β-carbolines | asymmetric cooperative catalysis | aerobic oxidative olefination | ACTIVATION | ACID | HYDROGENATION | ALKYLATION | PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | DUAL-CATALYSIS | C-H BONDS | beta-carbolines | FUNCTIONALIZATION | CYCLIC IMINES
organocatalysis | photoredox catalysis | β-carbolines | asymmetric cooperative catalysis | aerobic oxidative olefination | ACTIVATION | ACID | HYDROGENATION | ALKYLATION | PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | DUAL-CATALYSIS | C-H BONDS | beta-carbolines | FUNCTIONALIZATION | CYCLIC IMINES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2013, Volume 19, Issue 36, pp. 11863 - 11868
Be economic with your atoms! An efficient Rh‐catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported (see...
CH activation | indoles | oxidative olefination | homogeneous catalysis | rhodium | C-H activation | Economics | Stereoselectivity | Cationic | Pyrroles | Activation | Tolerances | Indoles | Bonding
CH activation | indoles | oxidative olefination | homogeneous catalysis | rhodium | C-H activation | Economics | Stereoselectivity | Cationic | Pyrroles | Activation | Tolerances | Indoles | Bonding
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 08/2019, Volume 10, Issue 31, pp. 7426 - 7432
Rhodium catalysis has been extensively used for ortho-C-H functionalization reactions, and successfully extended to meta-C-H functionalization. Its application...
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ALKYLATION | ARENES | BONDS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | ALKENYLATION
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ALKYLATION | ARENES | BONDS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | ALKENYLATION
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 5, pp. 1311 - 1316
Although chelation-assisted C-H olefination has been intensely investigated, Pd(II)-catalyzed C-H olefination reactions are largely restricted to acrylates and...
OXIDATIVE OLEFINATION | DIRECTING GROUPS | FUNCTIONALIZATION | SUBSTITUTED ARENES | ACTIVATION | MECHANISM | ALPHA-AMINO-ACIDS | TEMPLATE | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC ALKENES | Alkenes | Chemical reactions | Amides | Alkylation | Aliphatic compounds | Acrylates | Hydrogen bonds | Styrenes | Quinoline | Chelation | Ligands | Catalysis | Functional groups
OXIDATIVE OLEFINATION | DIRECTING GROUPS | FUNCTIONALIZATION | SUBSTITUTED ARENES | ACTIVATION | MECHANISM | ALPHA-AMINO-ACIDS | TEMPLATE | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC ALKENES | Alkenes | Chemical reactions | Amides | Alkylation | Aliphatic compounds | Acrylates | Hydrogen bonds | Styrenes | Quinoline | Chelation | Ligands | Catalysis | Functional groups
Journal Article
Chemical Science, ISSN 2041-6520, 03/2015, Volume 6, Issue 3, pp. 1923 - 1927
The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a...
OXIDATIVE OLEFINATION | ELECTRON | PD(II)-CATALYZED OLEFINATION | CATALYZED OXIDATION | COMPLEXES | DEHYDROGENATIVE HECK REACTIONS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | MOLECULAR-OXYGEN
OXIDATIVE OLEFINATION | ELECTRON | PD(II)-CATALYZED OLEFINATION | CATALYZED OXIDATION | COMPLEXES | DEHYDROGENATIVE HECK REACTIONS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | MOLECULAR-OXYGEN
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 5, pp. 985 - 994
Rhodium(III)‐catalyzed chelation‐assisted highly regio‐ and stereoselective direct olefination of imidazoles with olefins has been developed. A broad range of...
pyrimidyl | C−H activation | Rhodium | imidazole | olefination | C-H BOND | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | VINYL CARBOXYLIC-ACIDS | HETEROAROMATIC-COMPOUNDS | ORTHO-ALKENYLATION | OXIDATIVE OLEFINATION | C-H activation | COUPLING REACTIONS | CHEMISTRY, APPLIED | ORGANOMETALLIC CATALYSIS | ARYL CHLORIDES | CATALYZED DIRECT ARYLATION | Chemical tests and reagents | Olefins | Copper compounds | Catalysis | Copper | Acetates | Substitutes | Alkenes | Chelation | Coupling | Substrates | Functional groups
pyrimidyl | C−H activation | Rhodium | imidazole | olefination | C-H BOND | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | VINYL CARBOXYLIC-ACIDS | HETEROAROMATIC-COMPOUNDS | ORTHO-ALKENYLATION | OXIDATIVE OLEFINATION | C-H activation | COUPLING REACTIONS | CHEMISTRY, APPLIED | ORGANOMETALLIC CATALYSIS | ARYL CHLORIDES | CATALYZED DIRECT ARYLATION | Chemical tests and reagents | Olefins | Copper compounds | Catalysis | Copper | Acetates | Substitutes | Alkenes | Chelation | Coupling | Substrates | Functional groups
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2011, Volume 17, Issue 26, pp. 7167 - 7171
Olefin(s) get‐together! A RhIII‐catalyzed oxidative cross‐coupling of different olefins was developed, resulting in the formation of valuable linear butadiene...
butadienes | CH activation | oxidative Heck‐coupling | amino acids | rhodium | C-H activation | oxidative Heck-coupling
butadienes | CH activation | oxidative Heck‐coupling | amino acids | rhodium | C-H activation | oxidative Heck-coupling
Journal Article