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1. Full Text Rh(III)-Catalyzed meta-C–H Olefination Directed by a Nitrile Template
by Xu, Hua-Jin and Lu, Yi and Farmer, Marcus E and Wang, Huai-Wei and Zhao, Dan and Kang, Yan-Shang and Sun, Wei-Yin and Yu, Jin-Quan
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 6, pp. 2200 - 2203
A range of Rh­(III)-catalyzed ortho-C–H functionalizations have been developed; however, extension of this reactivity to remote C–H functionalizations through... 
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ROOM-TEMPERATURE | PHENOLS | ALKYLATION | ARYLATION | ARENES | BOND ACTIVATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Usage | Rhodium | Analysis | Chemical bonds | Ligands | Catalysis | Chemical properties
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2. Full Text Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes
by Deb, Arghya and Bag, Sukdev and Kancherla, Rajesh and Maiti, Debabrata
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 39, pp. 13602 - 13605
Palladium-catalyzed coupling between aryl halides and alkenes (Mizoroki–Heck reaction) is one of the most popular reactions for synthesizing complex organic... 
BIDENTATE-CHELATION ASSISTANCE | OXIDATIVE OLEFINATION | ACID-DERIVATIVES | OXIDIZING DIRECTING GROUP | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | CONJUGATED POLYMERS | PD(II)-CATALYZED OLEFINATION | CARBON-HYDROGEN BONDS | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | Palladium | Chemical properties | Hydrogen | Carbon compounds
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3. Full Text Ligand-enabled: Ortho -C-H olefination of phenylacetic amides with unactivated alkenes
by Lu, Ming-Zhu and Chen, Xing-Rong and Xu, Hui and Dai, Hui-Xiong and Yu, Jin-Quan
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 5, pp. 1311 - 1316
Although chelation-assisted C-H olefination has been intensely investigated, Pd(II)-catalyzed C-H olefination reactions are largely restricted to acrylates and... 
OXIDATIVE OLEFINATION | DIRECTING GROUPS | FUNCTIONALIZATION | SUBSTITUTED ARENES | ACTIVATION | MECHANISM | ALPHA-AMINO-ACIDS | TEMPLATE | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC ALKENES
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4. Full Text Rhodium(III)‐Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins
by Xue, Xiao and Xu, Jianbin and Zhang, Lingjuan and Xu, Conghui and Pan, Yixiao and Xu, Lijin and Li, Huanrong and Zhang, Weidong
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2016, Volume 358, Issue 4, pp. 573 - 583
A rhodium(III)‐catalyzed direct ortho CH bond olefination of arenes, including but not limited to benzamides, arylpyridines and indoles, with a variety of... 
benzamides | indoles | pyridines | olefination | rhodium | DIRECT ARYLATION | LATE-STAGE DIVERSIFICATION | CHEMISTRY, ORGANIC | AROMATIC-SUBSTITUTION | MIZOROKI-HECK | CATALYZED OXIDATIVE OLEFINATION | ORTHO-ALKENYLATION | COUPLING REACTIONS | REGIOSELECTIVE SYNTHESIS | N BOND FORMATION | CHEMISTRY, APPLIED | DEHYDROGENATIVE HECK REACTION | Stereoselectivity | Silver | Aromatic compounds | Olefins | Catalysis | Bonding | Acetates | Aliphatic compounds
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5. Full Text Rhodium(III)‐Catalyzed Oxidative Olefination of Picolinamides: Convenient Synthesis of 3‐Alkenylpicolinamides
by Zhou, Jun and Li, Bo and Qian, Zhen‐Chao and Shi, Bing‐Feng
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2014, Volume 356, Issue 5, pp. 1038 - 1046
A rhodium(III)‐catalyzed selective olefination of picolinamide derivatives has been developed. The reaction shows high regioselectivity, low catalyst loading... 
CH activation | oxidative olefination | pyridines | rhodium | C-H activation | DIRECTING GROUP | DIRECT ARYLATION | PYRIDINE-N-OXIDES | CHEMISTRY, ORGANIC | NICKEL/LEWIS ACID CATALYSIS | SELECTIVE ALKENYLATION | AROMATIC-SUBSTITUTION | C-H ACTIVATION | SCALE SYNTHESIS | CH activation | IMINOPYRIDINIUM YLIDES | BOND ACTIVATION | CHEMISTRY, APPLIED | Rhodium | Pyridine | Synthesis | Catalysts | Strategy | Tolerances | Derivatives | Catalysis | Functional groups
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6. Full Text Enantioselective Aerobic Oxidative C(sp3)–H Olefination of Amines via Cooperative Photoredox and Asymmetric Catalysis
by Wei, Guo and Zhang, Chenhao and Bureš, Filip and Ye, Xinyi and Tan, Choon-Hong and Jiang, Zhiyong
ACS Catalysis, ISSN 2155-5435, 06/2016, Volume 6, Issue 6, pp. 3708 - 3712
A cooperative photoredox and asymmetric catalysis for the enantioselective aerobic oxidative C­(sp3)–H olefination of tetrahydro-β-carbolines (THCs) is... 
organocatalysis | photoredox catalysis | β-carbolines | asymmetric cooperative catalysis | aerobic oxidative olefination | ACTIVATION | ACID | HYDROGENATION | ALKYLATION | PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | DUAL-CATALYSIS | C-H BONDS | beta-carbolines | FUNCTIONALIZATION | CYCLIC IMINES
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7. Full Text Rhodium catalyzed template-assisted distal para-C-H olefination
by Dutta, U and Maiti, S and Pimparkar, S and Gahan, LR and Krenske, EH and Lupton, DW and Maiti, D
CHEMICAL SCIENCE, ISSN 2041-6520, 08/2019, Volume 10, Issue 31, pp. 7426 - 7432
Rhodium catalysis has been extensively used for ortho-C-H functionalization reactions, and successfully extended to meta-C-H functionalization. Its application... 
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ALKYLATION | ARENES | BONDS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | ALKENYLATION
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8. Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes
by Ming-Zhu Lu and Xing-Rong Chen and Hui Xu and Hui-Xiong Dai and Jin-Quan Yu
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 5, pp. 1311 - 1316
Although chelation-assisted C–H olefination has been intensely investigated, Pd(ii)-catalyzed C–H olefination reactions are largely restricted to acrylates and... 
Alkenes | Chemical reactions | Amides | Alkylation | Aliphatic compounds | Acrylates | Hydrogen bonds | Styrenes | Quinoline | Chelation | Ligands | Catalysis | Functional groups
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9. Full Text Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)‐Catalyzed CH Bond Activation
by Li, Bin and Ma, Jianfeng and Xie, Weijia and Song, Haibin and Xu, Shansheng and Wang, Baiquan
Chemistry – A European Journal, ISSN 0947-6539, 09/2013, Volume 19, Issue 36, pp. 11863 - 11868
Be economic with your atoms! An efficient Rh‐catalyzed oxidative olefination of indoles and pyrroles with broad substrate scope and tolerance is reported (see... 
CH activation | indoles | oxidative olefination | homogeneous catalysis | rhodium | C-H activation | Economics | Stereoselectivity | Cationic | Pyrroles | Activation | Tolerances | Indoles | Bonding
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10. Full Text Rh(III)-catalyzed C-H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant
by Lu, Yi and Wang, Huai-Wei and Spangler, Jillian E and Chen, Kai and Cui, Pei-Pei and Zhao, Yue and Sun, Wei-Yin and Yu, Jin-Quan
Chemical Science, ISSN 2041-6520, 03/2015, Volume 6, Issue 3, pp. 1923 - 1927
The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved via a... 
OXIDATIVE OLEFINATION | ELECTRON | PD(II)-CATALYZED OLEFINATION | CATALYZED OXIDATION | COMPLEXES | DEHYDROGENATIVE HECK REACTIONS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | MOLECULAR-OXYGEN
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11. Full Text Rhodium(III)‐Catalyzed Selective Direct Olefination of Imidazoles
by Zhao, Haoqiang and Xu, Jianbin and Chen, Changjun and Xu, Xin and Pan, Yixiao and Zhang, Zongyao and Li, Huanrong and Xu, Lijin
Advanced Synthesis & Catalysis, ISSN 1615-4150, 03/2018, Volume 360, Issue 5, pp. 985 - 994
Rhodium(III)‐catalyzed chelation‐assisted highly regio‐ and stereoselective direct olefination of imidazoles with olefins has been developed. A broad range of... 
pyrimidyl | C−H activation | Rhodium | imidazole | olefination | C-H BOND | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | VINYL CARBOXYLIC-ACIDS | HETEROAROMATIC-COMPOUNDS | ORTHO-ALKENYLATION | OXIDATIVE OLEFINATION | C-H activation | COUPLING REACTIONS | CHEMISTRY, APPLIED | ORGANOMETALLIC CATALYSIS | ARYL CHLORIDES | CATALYZED DIRECT ARYLATION | Chemical tests and reagents | Olefins | Copper compounds | Catalysis | Copper | Acetates | Substitutes | Alkenes | Chelation | Coupling | Substrates | Functional groups
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12. Full Text RhIII‐Catalyzed Oxidative Olefination of Vinylic CH Bonds: Efficient and Selective Access to Di‐unsaturated α‐Amino Acid Derivatives and Other Linear 1,3‐Butadienes
by Besset, Tatiana and Kuhl, Nadine and Patureau, Frederic W and Glorius, Frank
Chemistry – A European Journal, ISSN 0947-6539, 06/2011, Volume 17, Issue 26, pp. 7167 - 7171
Olefin(s) get‐together! A RhIII‐catalyzed oxidative cross‐coupling of different olefins was developed, resulting in the formation of valuable linear butadiene... 
butadienes | CH activation | oxidative Heck‐coupling | amino acids | rhodium | C-H activation | oxidative Heck-coupling
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