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Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1501 - 1508
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 69, pp. 10533 - 10536
A cobalt-catalyzed C-H olefination of aromatic and heteroaromatic amides with unactivated alkenes, allyl acetates and allyl alcohols is described. This method... 
OXIDATIVE OLEFINATION | ORGANIC-SYNTHESIS | ROOM-TEMPERATURE | TRADITIONAL LEAVING GROUP | DIRECTED FUNCTIONALIZATION | TERMINAL ALKYNES | CARBON-HYDROGEN BONDS | HIGHLY SELECTIVE ARYLATION | ALLYL ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ORTHO-ALKENYLATION | Amides | Synthesis | Alkenes | Benzamide | Acetates | Alcohols
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 36, pp. 6232 - 6239
Hypervalent iodine‐mediated oxidative olefination of amines with an active methylene compound provides a rapid gateway towards the formation of electrophilic... 
Oxidative olefination | Synthetic methods | Amines | Hypervalent iodine | CATALYZED KNOEVENAGEL CONDENSATION | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | METAL-ORGANIC FRAMEWORK | IONIC LIQUID | HYDRATION | CHEMOSELECTIVE REDUCTION | GREEN PROCEDURE | FACILE SYNTHESIS | NITRILES | EFFICIENT
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 6, pp. 1426 - 1429
An unprecedented approach for the synthesis of imine derivatives was achieved via a Pd­(II)-catalyzed dearomatization reaction of N-aryl ureas with internal... 
NAPHTHOLS | ASYMMETRIC DEAROMATIZATION | OLEFINATION | OXIDATIVE DEAROMATIZATION | ANNULATION | ANILINES | ARYLATION | CONSTRUCTION | CHEMISTRY, ORGANIC | INTERNAL ALKYNES | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2012, Volume 14, Issue 16, pp. 4166 - 4169
NH and N-protected isoquinolones undergo Rh(III)-catalyzed oxidative olefination at the 8-position. Complementary redox-neutral olefination of such... 
COPPER-CATALYZED ARYLATION | FUNCTIONALIZATION | 3+2 ANNULATION | AROMATIC KETIMINES | ACTIVATION | DIRECTED ALKENYLATION | CHEMISTRY, ORGANIC | ALKYNES | C-H BONDS | OXIDATIVE ALKENYLATION | HYDROARYLATION
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2016, Volume 72, Issue 22, pp. 2756 - 2762
A practical C–H olefination of phenyl acetic acid derivatives was achieved with a 1,2,3-triazole auxiliary directing group. Good to excellent yields were... 
Directing group | Oxidative heck | C–H activation | 1,2,3-Triazole | Aerobic olefination | C-H activation | ACTIVATION | SILANOL | ARYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | FUNCTIONALIZATION | ETHER | BIDENTATE | HECK REACTION | ALKENYLATION | Amines | Acetic acid | Triazoles | Organic acids | Phenyls | Tetrahedrons | Activation | Terminals | Derivatives
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2014, Volume 50, Issue 90, pp. 13914 - 13916
The room-temperature oxidative C-H/C-H cross-couplings between (hetero)arenes and alkenes, coumarins or quinones have been reported by using a highly... 
Alkenes - chemistry | Temperature | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Alkenes - chemical synthesis | Palladium - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 8/2017, Volume 53, Issue 64, pp. 8931 - 8947
The transition-metal-catalyzed chelation-assisted alkenylation at the inert C-H bond of aromatics with alkenes is one of the efficient methods to synthesize... 
DIRECT ORTHO-ALKENYLATION | DIRECTING GROUP | ASYMMETRIC 1,4-ADDITION | RUTHENIUM-CATALYZED CYCLIZATION | COUPLING REACTION | BOND ACTIVATION | ARYL KETONES | INTERNAL ALKYNES | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | OXIDATIVE ALKENYLATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 02/2014, Volume 356, Issue 2‐3, pp. 609 - 615
Oxidative C‐2 olefination of indoles/pyrrole via rhodium(III)‐catalyzed direct CH bond activation is reported. Phenolic OH and aniline NH2 units were revealed... 
indoles | hydroxy group | directing groups | olefination | rhodium | Hydroxy group | Indoles | Rhodium | Olefination | Directing groups | OPEN ATMOSPHERE | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | H BOND ACTIVATION | OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ALKENES | C-C | CHEMISTRY, APPLIED | DERIVATIVES | ALKENYLATION | BENZOIC-ACIDS | Aniline | Fine chemicals
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2013, Volume 2013, Issue 10, pp. 1950 - 1962
Two pathways that can be used to access ortho‐olefinated phenol carbamate, including a ruthenium(II)‐catalyzed oxidative olefination of phenol carbamate with... 
C‐H activation | Ruthenium | Rhodium | Olefination | Protecting groups | C-H activation | ROOM-TEMPERATURE | ACTIVATION | ARENES | CHEMISTRY, ORGANIC | CIS-ADDITION | SELECTIVE ALKENYLATION | ALKYNES | ALKENES | CATALYZED ALKENYLATION | DERIVATIVES | OXIDATIVE ALKENYLATION | Carbamates | Phenols | Acrylates
Journal Article
Organic Letters, ISSN 1523-7060, 01/2012, Volume 14, Issue 1, pp. 74 - 77
An efficient Pd(II)-catalyzed direct olefination of perfluoroarenes with allyl esters is demonstrated. Under the typical conditions, the coupling reaction of... 
FUNCTIONALIZATION | OXIDATIVE HECK REACTIONS | ARENES | CHEMISTRY, ORGANIC | FLUORINE | BOND ACTIVATION | HIGHLY SELECTIVE ARYLATION | ALKYLATIONS | ARYLBORONIC ACIDS | ALKENYLATION | PROTON-ABSTRACTION MECHANISM | Alkenes - chemistry | Esters - chemistry | Allyl Compounds - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Fluorine - chemistry
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 18, pp. 4582 - 4585
A Ru-catalyzed direct olefination of electron-deficient alkenes with allyl acetate via C–H bond activation is disclosed. By using N,N-disubstituted... 
ORGANIC-SYNTHESIS | CROSS-COUPLING REACTION | C-H ALLYLATION | OXIDATIVE HECK REACTIONS | CHEMISTRY, ORGANIC | BOND ACTIVATION | SELECTIVE SYNTHESIS | LINEAR 1,3-BUTADIENES | ALKENYLATION | DEAROMATIZATION REACTION | ACRYLATES
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2015, Volume 51, Issue 25, pp. 5375 - 5378
Journal Article
Chemical Science, ISSN 2041-6520, 02/2015, Volume 6, Issue 3, pp. 1923 - 1927
The oxidative olefination of a broad array of arenes and heteroarenes with a variety of activated and unactivated olefins has be achieved viaa... 
Sole | Oxidants | Aromatic compounds | Olefins | Oxidizing agents | Activation | Arrays | Benzamide
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2016, Volume 81, Issue 22, pp. 11353 - 11359
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 05/2011, Volume 133, Issue 17, pp. 6541 - 6544
This communication describes a new method for the Pd/polrxometalate-catalyzed aerobic olefination of unactivated sp(3)C H bonds. Nitrogen heterocycles serve as... 
OXIDATIVE FUNCTIONALIZATION | COUPLING REACTION | ARYLATION | CARBON-HYDROGEN BONDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
Chemical Communications, ISSN 1359-7345, 09/2011, Volume 47, Issue 34, pp. 9660 - 9662
The Co/Mn-mediated oxidative cross-coupling of indoles with beta-keto esters via dioxygen activation under mild conditions leads to ketonization-olefination of... 
FUNCTIONALIZATION | PALLADIUM | DIELS-ALDER | OXIDASE | ACIDS | TERMINAL ALKYNES | N-HYDROXYPHTHALIMIDE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SOLVENT | MOLECULAR-OXYGEN | Alkenes - chemistry | Ketones - chemistry | Oxidative Coupling | Oxygen - chemistry | Esters | Manganese - chemistry | Indoles - chemistry | Cobalt - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2007, Volume 129, Issue 24, pp. 7666 - 7673
Highly regioselective olefination of substituted N,N-dimethylbenzylamines was developed by tuning the acidity of reaction conditions based on analysis of their... 
CATALYTIC FUNCTIONALIZATION | MILD CONDITIONS | FRIEDEL-CRAFTS BENZYLATION | PALLADIUM COMPLEXES | OXIDATIVE FUNCTIONALIZATION | COUPLING REACTIONS | AROMATIC SUBSTITUTION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | METAL-COMPLEXES | Monoamine oxidase | Toluene | Olefins | Electric properties
Journal Article
by Wang, L and Guo, W and Zhang, XX and Xia, XD and Xiao, WJ
ORGANIC LETTERS, ISSN 1523-7060, 02/2012, Volume 14, Issue 3, pp. 740 - 743
A highly efficient approach to indolo [1,2-a]quinoxaline derivatives through a Pd-catalyzed regioselective C-H olefination/cyclization sequence has been... 
CATALYTIC FUNCTIONALIZATION | OXIDATIVE OLEFINATION | SULFUR YLIDES | PALLADIUM | DIRECT ARYLATION | BIOLOGICAL EVALUATION | CHEMISTRY, ORGANIC | BOND FORMATION | CASCADE | AROMATIC-SUBSTITUTION | BENZOIC-ACIDS
Journal Article
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