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European Journal of Organic Chemistry, ISSN 1434-193X, 12/2019, Volume 2019, Issue 48, pp. 7831 - 7835
Discovered the Ruthenium(II) catalysed highly stereo‐ and regioselective protocol for the oxidative C‐3 alkenylation of indolizines and... 
Directing group | C–H activation | Ruthenium | Indolizine | Alkenylation | ISOINDOLINONES | ACTIVATION | N,N-DIALKYL BENZAMIDES | CHEMISTRY, ORGANIC | INDOLES | FUNCTIONALIZATION | C-H activation | OLEFINATION | C-H ARYLATION | OXIDATIVE ALKENYLATION | CYCLIZATION
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2019, Volume 21, Issue 23, pp. 9545 - 9549
Herein, we report a straightforward, environmentally friendly, and controllable palladium/ligand catalytic system to enable reductive/oxidative Heck reactions... 
FUNCTIONALIZATION | OLEFINATION | ASYMMETRIC CONJUGATE ADDITION | ENANTIOSELECTIVE SYNTHESIS | ARENES | CHEMISTRY, ORGANIC | OXIDATIVE HECK | BOND ACTIVATION | ARYLBORONIC ACIDS | ALKENYLATION | HYDROARYLATION
Journal Article
Chinese Journal of Chemistry, ISSN 1001-604X, 12/2019, Volume 37, Issue 12, pp. 1229 - 1233
Summary of main observation and conclusion Herein, unprecedented rhenium‐catalyzed decarboxylative oxytri‐/difluoromethylation and Heck‐type... 
DIFUNCTIONALIZATION | FUNCTIONALIZATION | ALKENES | BONDS | AMINOACETOXYLATION | OXYTRIFLUOROMETHYLATION | OXIDATIVE TRIFLUOROMETHYLATION | ALKYNES | C-H TRIFLUOROMETHYLATION | PERFLUOROALKYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Zhao, HQ and Xu, X and Luo, ZL and Cao, L and Li, BH and Li, HR and Xu, LJ and Fan, QH and Walsh, PJ
CHEMICAL SCIENCE, ISSN 2041-6520, 11/2019, Volume 10, Issue 43, pp. 10089 - 10096
A versatile Rh(i)-catalyzed C6-selective decarbonylative C-H alkenylation of 2-pyridones with readily available, and inexpensive alkenyl carboxylic acids has... 
OXIDATIVE OLEFINATION | DIRECTING GROUP | CINNAMIC-ACIDS | DIRECT ARYLATION | DECARBOXYLATIVE COUPLING REACTIONS | C3-SELECTIVE DIRECT ALKYLATION | REGIOSELECTIVE SYNTHESIS | BOND ACTIVATION | DECARBONYLATIVE DIRECT OLEFINATION | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2019, Volume 361, Issue 22, pp. 5133 - 5139
In this work, we present an efficient mechanochemical strategy for chemo‐, regio‐ and stereo‐selective oxidative Heck coupling of readily accessible arylboron... 
oxidative arylation | cross-coupling | mechanochemistry | unactivated alkenes | solvent-free reactions | CATALYSIS | PD(II)-CATALYZED OLEFINATION | ARYLATION | ARENES | C-H OLEFINATION | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | N-HYDROXYPHTHALIMIDE | FUJIWARA-MORITANI REACTION | HIGHLY EFFICIENT | INDOLES | CHEMISTRY, APPLIED | Selectivity | Synthesis | Coupling | Alkenes | Substrates | Reagents
Journal Article
by Zheng, LM and Shi, DD and Bao, HY and Liu, YK
CHINESE JOURNAL OF ORGANIC CHEMISTRY, ISSN 0253-2786, 10/2019, Volume 39, Issue 10, pp. 2821 - 2828
A facile and efficient method for the synthesis of 6H-phenanthridines has been successfully developed involving a copper(0)/Selectfluor system-catalyzed tandem... 
annulation reaction | IMINYL-RADICAL FORMATION | PHENANTHRIDINE DERIVATIVES | 6H-phenanthridine | C-H bond amination | VINYL AZIDES | CHEMISTRY, ORGANIC | BOND-CLEAVAGE | copper catalysis | ALKENES | OLEFINATION | Selectfluor | BIOLOGICAL-ACTIVITY | COUPLING REACTION | OXIDATIVE CYCLIZATION | EFFICIENT
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 10/2019, Volume 21, Issue 20, pp. 8219 - 8224
A range of Ru-, Rh-, or Pd-catalyzed vinylic C-H/C-H cross-coupling reactions of olefins have been demonstrated to provide 1,3-dienes, using a quantitative... 
OXIDATIVE OLEFINATION | VINYL | ACTIVATION | H/D EXCHANGE | CHEMISTRY, ORGANIC | SELECTIVE ACCESS | EFFICIENT | C-H BONDS | HYDROARYLATION | ALKENYLATION | ACRYLATES
Journal Article
by Li, TY and Shen, C and Sun, YL and Zhang, J and Xiang, PJ and Lu, XN and Zhong, GF
ORGANIC LETTERS, ISSN 1523-7060, 10/2019, Volume 21, Issue 19, pp. 7772 - 7777
The first cobalt-catalyzed cross-couplings between olefins has been demonstrated to provide C(alkenyl)-H alkenylation and alkylation products, using complex... 
OXIDATIVE OLEFINATION | ACTIVATION | ALPHA,BETA-UNSATURATED IMINES | CROSS-COUPLING REACTION | COBALT(III)-CATALYZED SYNTHESIS | BONDS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | SELECTIVE ACCESS | ELECTRON-DEFICIENT ALKENES | CARBOXYLIC-ACIDS
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 10/2019, Volume 84, Issue 19, pp. 12553 - 12561
Organic molecules bearing acetoxy moieties are important functionalities in natural products, drugs, and agricultural chemicals. Synthesis of such molecules... 
9-MESITYL-10-METHYLACRIDINIUM ION | OXIDATIVE DECARBOXYLATION | OLEFINATION | ALKYL RADICALS | AMINO-ACIDS | ARYLATION | LIGHT PHOTOREDOX CATALYSIS | CHEMISTRY, ORGANIC | ESLICARBAZEPINE ACETATE | BENZOIC-ACIDS | 4-ACETOXY-2-AZETIDINONES
Journal Article
European Journal of Medicinal Chemistry, ISSN 0223-5234, 10/2019, Volume 179, pp. 753 - 764
Over the latest years phytochemical consumption has been associated to a decreased risk of both the onset and the development of a number of pathological... 
Indicaxanthin | Antiproliferative | Antitumoral | Molecular modelling | Multi-target compound | Poly-pharmacology | Neuromodulator | Antiinflammatory | Antioxidant | CELLS | OXIDATIVE STRESS | CHEMISTRY, MEDICINAL | ANTIOXIDANT BETALAINS | CONVERSION | PIGMENTS | AMANITA-MUSCARIA | INFLAMMATION | BIOSYNTHESIS | INCREASED RESISTANCE | BETANIN | Antioxidants | Analysis | Models
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 36, pp. 6232 - 6239
Hypervalent iodine‐mediated oxidative olefination of amines with an active methylene compound provides a rapid gateway towards the formation of electrophilic... 
Oxidative olefination | Synthetic methods | Amines | Hypervalent iodine | CATALYZED KNOEVENAGEL CONDENSATION | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | METAL-ORGANIC FRAMEWORK | IONIC LIQUID | HYDRATION | CHEMOSELECTIVE REDUCTION | GREEN PROCEDURE | FACILE SYNTHESIS | NITRILES | EFFICIENT
Journal Article
Polymer, ISSN 0032-3861, 09/2019, Volume 179, p. 121607
Poly( -phenylenevinylene) derivative was ladderized in a stepwise manner by the intramolecular oxidative cyclization using 2,3-dichloro-5,6-dicyano-... 
Polycyclic aromatic hydrocarbon | Oxidative cyclization | Poly(p-phenylenevinylene) | CHAIN | LADDER POLYMER | POLYMER SCIENCE | EFFICIENT | BOTTOM-UP SYNTHESIS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2019, Volume 361, Issue 18, pp. 4393 - 4398
We developed herein an iridium‐catalyzed direct C−H activation/ C−N bond formation reaction of benzenesulfonamides with sulfonyl azides. The amidation reaction... 
iridium | 2-aminobenzesulfonamides | sulfonamides | C−H amidation | sulfonyl azides | BOND AMIDATION | CHEMISTRY, ORGANIC | 1,1-DIOXIDES | MILD | OLEFINATION | HETEROCYCLES | ARYL SULFONAMIDES | OXIDATIVE SYNTHESIS | CHEMISTRY, APPLIED | DERIVATIVES | ACCESS | C-H amidation | BENZOIC-ACIDS | Nitrogen | Sulfonamides | Iridium | Functional groups | Substrates
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 34, pp. 5974 - 5977
A novel cascade reaction has been described for the synthesis of Carbolines via palladium‐catalyzed successive C–C/C–N formation from O‐methylketoximes and... 
Carbolines | Palladium | Dual C–C/C–N formation | Styrenes | Annulation | DIRECT ARYLATION | Dual C-C | GAMMA-CARBOLINES | CHEMISTRY, ORGANIC | C-N formation | OXIMES | OLEFINATION | ETHER | ESTERS | OXIDANT | DERIVATIVES | OXIDATIVE ALKENYLATION | ACCESS | Styrene
Journal Article
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 08/2019, Volume 10, Issue 31, pp. 7426 - 7432
Rhodium catalysis has been extensively used for ortho-C-H functionalization reactions, and successfully extended to meta-C-H functionalization. Its application... 
OXIDATIVE OLEFINATION | FUNCTIONALIZATION | ACTIVATION | DIRECT ARYLATION | ALKYLATION | ARENES | BONDS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | ALKENYLATION
Journal Article