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Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 7, pp. 2757 - 2765
We demonstrate the application of infrared photodissocation spectroscopy for determination of the FeO stretching frequencies of high-valent iron­(IV)–oxo... 
OXYGEN-ATOM EXCHANGE | NONHEME OXOIRON(IV) COMPLEXES | CONSISTENT BASIS-SETS | IRON-OXO COMPLEXES | GAS-PHASE | CORRELATION-ENERGY | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY | 2ND-ORDER PERTURBATION-THEORY | FIELD REFERENCE FUNCTION | C-H BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 28, pp. 8027 - 8031
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 04/2014, Volume 47, Issue 4, pp. 1146 - 1154
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 11, pp. 3709 - 3713
Reactions of N,N‐dimethylaniline (DMA) with nonheme iron(IV)‐oxo and iron(IV)‐tosylimido complexes occur via different mechanisms, such as an N‐demethylation... 
N-demethylation | electron transfer | iron(IV)-imido complexes | mechanisms | bioinorganic chemistry | IMIDO COMPLEXES | METAL-OXO | OXOIRON(IV) COMPLEXES | HYDROGEN-ATOM TRANSFER | IRON | CHEMISTRY, MULTIDISCIPLINARY | VALENT | NITRIDO COMPLEXES | LIGATION SYNTHESIS | C-H | Iron | Demethylation | Fish oils | Energy | Analogue | Electron transfer | Coordination compounds | Dimerization | Electrode potentials
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 7/2007, Volume 40, Issue 7, pp. 522 - 531
High-valent iron(IV)–oxo species have been implicated as the key reactive intermediates in the catalytic cycles of dioxygen activation by heme and non-heme... 
DIOXYGEN ACTIVATION | OXOIRON(IV) COMPLEXES | CYTOCHROME-P450 MODEL REACTIONS | CATION-RADICAL COMPLEXES | CATALYTIC EPOXIDATION | SPECTROSCOPIC CHARACTERIZATION | ALKYL HYDROPEROXIDES | IRON-PORPHYRIN COMPLEXES | FE-IV=O COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 07/2019, Volume 25, Issue 41, pp. 9608 - 9613
The [Fe-IV(O)(Me3NTB)](2+) (Me3NTB=tris[(1-methyl-benzimidazol-2-yl)methyl]amine) complex 1 has been shown by Mossbauer spectroscopy to have an S=1 ground... 
nonheme iron | OXIDATION | IRON(IV)-OXO COMPLEXES | ACTIVATION | HYDROGEN-ATOM TRANSFER | IRON-OXO COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | DFT calculations | C-H BONDS | oxoiron(IV) complexes | ELECTRON-TRANSFER | RATE CONSTANTS | SPIN-STATE | NMR spectroscopy | (FEO)-O-IV COMPLEXES | two-state reactivity
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 37, pp. 11129 - 11133
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14312 - 14325
In biology, high valent oxo–iron­(IV) species have been shown to be pivotal intermediates for functionalization of C–H bonds in the catalytic cycles of a range... 
H BOND ACTIVATION | FE-IV=O | PARAMAGNETIC-RESONANCE | ACTIVE-SITE | VALENT IRON(IV)-OXO COMPLEXES | C-TERM SIGNS | TRANSITION-METAL | 2-STATE REACTIVITY | SPIN OXOIRON(IV) COMPLEX | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article