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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2019, Volume 58, Issue 38, pp. 13472 - 13478
Formation of the O-O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High-valent metal complexes with terminal oxo... 
SITE | oxo ligands | OXOIRON(IV) COMPLEXES | MECHANISM | bioinorganic chemistry | REACTIVITY | O-O activation | WATER OXIDATION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | OXYGEN | iron | LIGAND | nitrogen ligands | CATALYSTS | C-H
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 04/2014, Volume 47, Issue 4, pp. 1146 - 1154
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 26, pp. 8939 - 8949
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14312 - 14325
In biology, high valent oxo–iron­(IV) species have been shown to be pivotal intermediates for functionalization of C–H bonds in the catalytic cycles of a range... 
H BOND ACTIVATION | FE-IV=O | PARAMAGNETIC-RESONANCE | ACTIVE-SITE | VALENT IRON(IV)-OXO COMPLEXES | C-TERM SIGNS | TRANSITION-METAL | 2-STATE REACTIVITY | SPIN OXOIRON(IV) COMPLEX | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2009, Volume 48, Issue 23, pp. 11038 - 11047
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14384 - 14388
The sluggish oxidants, [Fe IV (O)(TMC)(CH 3 CN)] 2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) and [Fe IV (O)( d 12 -TMCN)(OTf)] + ( 3d ; d... 
Oxygen Atom Transfer | Hydrogen Atom Transfer | Oxoiron(IV) Complex | Oxygen-Based Ligands | Spin State Effect
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2017, Volume 139, Issue 7, pp. 2757 - 2765
We demonstrate the application of infrared photodissocation spectroscopy for determination of the FeO stretching frequencies of high-valent iron­(IV)–oxo... 
OXYGEN-ATOM EXCHANGE | NONHEME OXOIRON(IV) COMPLEXES | CONSISTENT BASIS-SETS | IRON-OXO COMPLEXES | GAS-PHASE | CORRELATION-ENERGY | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY | 2ND-ORDER PERTURBATION-THEORY | FIELD REFERENCE FUNCTION | C-H BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, pp. 14384 - 14388
The sluggish oxidants [FeIV(O)(TMC)(CH3CN)]2+ (TMC=1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane) and [FeIV(O)(TMCN‐d12)(OTf)]+... 
oxoiron(IV) complexes | hydrogen atom transfer | spin state | O ligands | oxygen atom transfer | O ligands | OXIDATION | MECHANISM | ESCHERICHIA-COLI | OXO | STATE | KETOGLUTARATE DIOXYGENASE | CHEMISTRY, MULTIDISCIPLINARY | NONHEME (FEO)-O-IV COMPLEXES | INTERMEDIATE | TAUD | Enzymes | Hydroxylation | Oxalic acid | Hydrogen | Bonding strength | Ligands | Iron | Oxidants | Oxidizing agents
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 7/2007, Volume 40, Issue 7, pp. 522 - 531
High-valent iron(IV)–oxo species have been implicated as the key reactive intermediates in the catalytic cycles of dioxygen activation by heme and non-heme... 
DIOXYGEN ACTIVATION | OXOIRON(IV) COMPLEXES | CYTOCHROME-P450 MODEL REACTIONS | CATION-RADICAL COMPLEXES | CATALYTIC EPOXIDATION | SPECTROSCOPIC CHARACTERIZATION | ALKYL HYDROPEROXIDES | IRON-PORPHYRIN COMPLEXES | FE-IV=O COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4012 - 4016
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 46, p. n/a
Iron Oxo Complexes In their Communication on page 14384 ff., W. Nam, M. Swart, K. Ray, et al. show that the oxoiron(IV) center in [FeIV(O)(TMCO)(OTf)]+ (bottom... 
oxoiron(IV) complexes | hydrogen atom transfer | spin state | O ligands | oxygen atom transfer | Hydrogen | Coordination compounds | Iron
Journal Article
Polyhedron, ISSN 0277-5387, 09/2019, Volume 169, pp. 169 - 175
Catalytic activity and selectivity of [Fe (N4Py )(CH CN] , where the possible reactive high-valent intermediate (Fe O) is known and spectroscopically well... 
Nonheme oxoiron complex | Kinetics | C[sbnd]H activation | Oxidative N-dealkylation | Bioinspired oxidation | CYTOCHROME P450-CATALYZED HYDROXYLATION | HYDROGEN-ATOM | CRYSTALLOGRAPHY | HORSERADISH-PEROXIDASE | CHEMISTRY, INORGANIC & NUCLEAR | OXYGEN | C-H activation | ELECTRON-TRANSFER | MODEL SYSTEMS | AMINES | N-DEALKYLATION | DEMETHYLATION | MECHANISTIC PROBE
Journal Article
JBIC Journal of Biological Inorganic Chemistry, ISSN 0949-8257, 1/2018, Volume 23, Issue 1, pp. 155 - 165
Journal Article