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Journal of the American Chemical Society, ISSN 0002-7863, 12/2016, Volume 138, Issue 49, pp. 16120 - 16129
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 36, pp. 11920 - 11929
This Article reports the first comprehensive study of β-hydride elimination at gold­(III). The stability/fate of gold­(III) alkyl species have been... 
ORGANIC-SYNTHESIS | GOLD CATALYSIS | POLYMERIZATION CATALYSTS | CARBON-CARBON BOND | SYN-INSERTION | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | ALKYL COMPLEXES | LIGAND DESIGN | Density functionals | Usage | Gold compounds | Chemical properties | Chemical synthesis | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 7, pp. 1820 - 1824
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 23, pp. 6870 - 6873
Five‐membered metallacycles are typically reluctant to undergo endocyclic β‐hydrogen elimination. The rhodium‐catalyzed isomerization of 4‐pentenals into... 
CH activation | β‐H elimination | isomerization | metallacycles | rhodium | β-H elimination | C-H activation | Rhodium | Metallacycles | Isomerization | Olefins | Cleavage | Activation | Selectivity | Bonding | Lead (metal) | Communications | C–H activation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2012, Volume 18, Issue 15, pp. 4714 - 4722
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 27, pp. 9401 - 9407
The reaction of C6F5H and H2CCHSiMe3 with catalytic [ i Pr2Im]­Ni­(η2-H2CCHSiMe3)2 (1b) exclusively forms the C–H silylation product C6F5SiMe3 with ethylene... 
BIDENTATE-CHELATION ASSISTANCE | TRANSITION-METAL CATALYSIS | ROOM-TEMPERATURE | CARBON-HYDROGEN-BOND | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | F BOND | OLEFIN METATHESIS | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Chemical reactions | Analysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 05/2016, Volume 52, Issue 41, pp. 6817 - 6820
An efficient transition metal-free approach for the generation of acceptor/acceptor-carbene followed by trapping with alkenes to provide fluoroacetyl... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 41, pp. 6817 - 6820
An efficient transition metal-free approach for the generation of acceptor/acceptor-carbene followed by trapping with alkenes to provide fluoroacetyl... 
PHASE-TRANSFER-CATALYSIS | FLUORINE | OLEFINS | DICHLOROCARBENE | PYRROLES | CONTAINING NATURAL-PRODUCTS | CHEMISTRY, MULTIDISCIPLINARY | TRANSFORMATIONS | Trapping | Synthesis | Alkenes | Fluorometers | Organic compounds
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2017, Volume 58, Issue 19, pp. 1842 - 1845
[Display omitted] •A selective substitution reaction of (Z)-1,2-dibromoalkenes is demonstrated.•A side-reaction of halogen elimination from vicinal... 
Dihaloalkenylsilanes | Alkene geometry | Halogen elimination | Regio-selectivity | Acrylonitriles | CARBON | CHEMISTRY, ORGANIC | ALKYNES | TETRASUBSTITUTED OLEFINS | CROSS-COUPLINGS | ARYL | STEREOSELECTIVE-SYNTHESIS | VINYL HALIDES | EXCHANGE | EFFICIENT | Silane
Journal Article
Organometallics, ISSN 0276-7333, 09/2013, Volume 32, Issue 17, pp. 4741 - 4751
It is surprising that rapid β-hydride elimination (βHE) can take place in some high-spin iron(II)– and cobalt(II)–alkyl complexes despite the absence of empty... 
TRANSITION-METAL-COMPLEXES | LOW-COORDINATE IRON(II) | 2-STATE REACTIVITY | OLEFIN POLYMERIZATION | CHEMISTRY, ORGANIC | DENSITY-FUNCTIONAL THEORY | C-H ACTIVATION | OPEN-SHELL ORGANOMETALLICS | ALKYL COMPLEXES | NONHEME FE-IV=O | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2009, Volume 15, Issue 15, pp. 3823 - 3829
Dramatic rate enhancement of reductive elimination of [Ar‐Pd‐C sp 3] was observed in the presence of a phosphine/electron‐deficient olefin ligand. Through... 
palladium | reductive elimination | cross‐coupling | kinetics | olefins | Palladium | Cross-coupling | Kinetics | Reductive elimination | Olefins | MECHANISTIC ASPECTS | ROOM-TEMPERATURE | ELECTRONIC-PROPERTIES | HINDERED ARYL CHLORIDES | ALKYLZINC REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | GENERAL-METHOD | CROSS-COUPLING REACTIONS | cross-coupling | ACTIVE CATALYST | HECK REACTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 331 - 335
Reported herein is the first enantioselective β‐elimination reaction catalyzed by a chiral cation‐binding polyether. By using this catalytic protocol, a wide... 
organocatalysis | kinetic resolution | asymmetric catalysis | sulfones | ion pairs | INTRAMOLECULAR CYCLOPROPANATION | GAMMA-SECRETASE INHIBITOR | ASYMMETRIC-SYNTHESIS | VINYL SULFONES | OLEFIN SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CHIRAL BUILDING-BLOCKS | ALLYLIC ALCOHOLS | 1,3-DIPOLAR CYCLOADDITION | HYDROXY-SULFONES | DIMETHYL-SULFOXIDE
Journal Article
Organometallics, ISSN 0276-7333, 07/2018, Volume 37, Issue 14, pp. 2335 - 2341
Quinolinone derivatives were synthesized by exchanging the ethyl group of 1-(quinolin-8-yl)­propan-1-one with substituted styrenes via group-directed... 
BENZOCYCLOBUTENONES | ACTIVATION | INSERTION | CYCLOADDITIONS | C-C BOND | ESTERIFICATION | CHEMISTRY, ORGANIC | OLEFINS | ARYL KETONES | RH-CATALYZED CARBOACYLATION | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 05/2019, Volume 84, Issue 9, pp. 5732 - 5746
N-Arylitaconimides, accessible from maleic anhydride, anilines, and paraformaldehyde, react with arene diazonium salts in Pd-catalyzed Matsuda-Heck arylation... 
CYCLOADDITION | ARENEDIAZONIUM SALTS | MECHANISM | MALEIMIDES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | OLEFINS | INHIBITORS | TRANSITION-METALS | MIZOROKI-HECK | DERIVATIVES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2016, Volume 138, Issue 36, pp. 11513 - 11516
Electron-rich and -poor BN-heterocycles with benzyl-pyridyl backbones and two bulky aryls on the boron (Ar = tipp, BN-1, Ar = MesF, BN-2) have been found to... 
ORGANOBORON COMPOUNDS | BORON | TRANSITION-METAL-COMPLEXES | N,C-CHELATE | CHEMISTRY | CONICAL INTERSECTION | OLEFIN METATHESIS | PHOTOELIMINATION | LEWIS ACIDITY | STABLE METHYLENEBORANES | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Usage | Chemical properties | Elimination reactions | Isomerization
Journal Article