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1. Full Text Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis
by Ghaffari, Behnaz and Preshlock, Sean M and Plattner, Donald L and Staples, Richard J and Maligres, Peter E and Krska, Shane W and Maleczka, Robert E and Smith, Milton R
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 41, pp. 14345 - 14348
Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The... 
IRIDIUM | COMPLEXES | DIRECTED ORTHO BORYLATION | C-H ACTIVATION | FUNCTIONALIZED ARENES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Boron Compounds - chemistry | Organophosphorus Compounds - chemical synthesis | Organosilicon Compounds - chemical synthesis | Chelating Agents - chemistry | Organophosphorus Compounds - chemistry | Coordination Complexes - chemistry | Boron Compounds - chemical synthesis | Nitrogen - chemistry | Organosilicon Compounds - chemistry | Molecular Structure | Catalysis | Chelating Agents - chemical synthesis | Iridium - chemistry | Phosphorus compounds | Chemical properties | Iridium | Nitrogen | Synthesis | Catalysts | Phosphorus | Ligands | Modular | Chelates | Communication
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2. Full Text Non‐Basic High‐Performance Molecules for Solution‐Processed Organic Solar Cells
by van der Poll, Thomas S and Love, John A and Nguyen, Thuc‐Quyen and Bazan, Guillermo C and Energy Frontier Research Centers (EFRC) (United States). Center for Energy Efficient Materials (CEEM)
Advanced Materials, ISSN 0935-9648, 07/2012, Volume 24, Issue 27, pp. 3646 - 3649
A new small molecule, p‐DTS(FBTTh2)2, is designed for incorporation into solution‐fabricated high‐efficiency organic solar cells. Of primary importance is the... 
organic solar cells | bulk heterojunction | electron poor heterocycles | solution‐processed | small molecules | solution-processed | POLYMERS | PHYSICS, CONDENSED MATTER | DESIGN | PHYSICS, APPLIED | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | PYRIDINES | CHEMISTRY, MULTIDISCIPLINARY | EFFICIENCY | DERIVATIVES | COUPLING APPROACH | Electrodes | Protons | Organosilicon Compounds - chemical synthesis | Solar Energy | Thiadiazoles - chemical synthesis | Heterocyclic Compounds - chemistry | Organosilicon Compounds - chemistry | Semiconductors | Thiadiazoles - chemistry | Thiophenes - chemistry | Polystyrenes - chemistry | Solutions - chemistry | Solar cells | Solar energy industry | Solar batteries | solar (photovoltaic), solid state lighting, phonons, thermoelectric, bio-inspired, energy storage (including batteries and capacitors), electrodes - solar, defects, charge transport, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)
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3. Full Text A Facile Multi-interface Transformation Approach to Monodisperse Multiple-Shelled Periodic Mesoporous Organosilica Hollow Spheres
by Teng, Zhaogang and Su, Xiaodan and Zheng, Yuanyi and Zhang, Junjie and Liu, Ying and Wang, Shouju and Wu, Jiang and Chen, Guotao and Wang, Jiandong and Zhao, Dongyuan and Lu, Guangming
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 24, pp. 7935 - 7944
The synthesis of well-defined and complex hollow structures via a simple method is still a major challenge. In this work, a facile and controllable... 
NANOSPHERES | NANOPARTICLES | ROUTE | MICROSPHERES | CHEMISTRY, MULTIDISCIPLINARY | MESOCHANNELS | Nanostructures - ultrastructure | Antibiotics, Antineoplastic - pharmacology | Nanotechnology - methods | Humans | Silicon Dioxide - chemistry | Phase Transition | Drug Carriers - chemistry | Neoplasms - drug therapy | Antibiotics, Antineoplastic - administration & dosage | Organosilicon Compounds - chemistry | Surface Properties | HEK293 Cells | Cell Line, Tumor | Nanostructures - chemistry | Surface-Active Agents - chemistry | Cetrimonium Compounds - chemistry | Porosity | Doxorubicin - pharmacology | Doxorubicin - administration & dosage | Care and treatment | Organosilicon compounds | Chemical properties | Doxorubicin | Cancer
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4. Full Text Bu4N+ Alkoxide-Initiated/Autocatalytic Addition Reactions with Organotrimethylsilanes
by Das, Manas and O’Shea, Donal F
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2014, Volume 79, Issue 12, pp. 5595 - 5607
The use of Me3SiO–/Bu4N+ as a general activator of organotrimethylsilanes for addition reactions has been established. The broad scope of the method offers... 
ALCOHOLS | KETONES | CATALYZED ADDITION | ENANTIOSELECTIVE SYNTHESIS | ALLYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | CLEAVAGE | BASE | FLUORIDE | Organosilicon Compounds - chemical synthesis | Cations - chemistry | Quaternary Ammonium Compounds - chemistry | Trimethylsilyl Compounds - chemistry | Trimethylsilyl Compounds - chemical synthesis | Organosilicon Compounds - chemistry | Organometallic Compounds - chemical synthesis | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Quaternary Ammonium Compounds - chemical synthesis | Sulfur Compounds - chemistry | Quinolizines - chemistry
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5. Full Text Hybrid nanoparticles for combination therapy of cancer
by He, Chunbai and Lu, Jianqin and Lin, Wenbin
Journal of Controlled Release, ISSN 0168-3659, 12/2015, Volume 219, pp. 224 - 236
Nanoparticle anticancer drug delivery enhances therapeutic efficacies and reduces side effects by improving pharmacokinetics and biodistributions of the drug... 
Combination therapy of cancer | Co-delivery | Synergistic effect | Hybrid nanoparticle | IRON-OXIDE NANOPARTICLES | GOLD NANOPARTICLES | PHOTODYNAMIC THERAPY | CONTRAST AGENTS | MESOPOROUS SILICA NANOPARTICLES | NANOSCALE COORDINATION POLYMERS | MAGNETIC NANOPARTICLES | CHEMISTRY, MULTIDISCIPLINARY | OVERCOME DRUG-RESISTANCE | BREAST-CANCER | METAL-ORGANIC FRAMEWORKS | PHARMACOLOGY & PHARMACY | Polymers - administration & dosage | Gold - administration & dosage | Nanoparticles - chemistry | Humans | Ferric Compounds - administration & dosage | Ferric Compounds - chemistry | Antineoplastic Agents - therapeutic use | Antineoplastic Agents - administration & dosage | Drug Delivery Systems | Organosilicon Compounds - administration & dosage | Polymers - therapeutic use | Organosilicon Compounds - therapeutic use | Nanoparticles - therapeutic use | Organometallic Compounds - therapeutic use | Gold - chemistry | Antineoplastic Agents - chemistry | Neoplasms - drug therapy | Animals | Organosilicon Compounds - chemistry | Ferric Compounds - therapeutic use | Gold - therapeutic use | Organometallic Compounds - chemistry | Polymers - chemistry | Nanoparticles - administration & dosage | Drug Combinations | Organometallic Compounds - administration & dosage | Nanoparticles | Drugs | Drug delivery systems | Chemotherapy | Analysis | Permeability | Health aspects | Cancer | Vehicles | Drug resistance | Photochemotherapy | co-delivery | combination therapy of cancer | synergistic effect
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6. Full Text Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes
by Lee, Kang-sang and Hoveyda, Amir H
Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 9, pp. 2898 - 2900
An efficient Cu-catalyzed protocol for enantioselective addition of a dimethylphenylsilanyl group to a wide range of cyclic and acyclic unsaturated ketones,... 
BORATION | ASYMMETRIC-SYNTHESIS | ALPHA,BETA-UNSATURATED KETONES | SILICON | ESTERS | ENONES | BOND FORMATION | 1,4-ADDITION | BETA-HYDROXY KETONES | CHEMISTRY, MULTIDISCIPLINARY | ORGANOSILICON COMPOUNDS | Silanes - chemistry | Copper - chemistry | Heterocyclic Compounds - chemistry | Methane - analogs & derivatives | Stereoisomerism | Ketones - chemistry | Methane - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Silanes - chemical synthesis | Analysis | Alkadienes | Organometallic compounds | Chemical properties | Structure | Copper
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7. Full Text Bulk Heterojunction Solar Cells Using Thieno[3,4-c]pyrrole-4,6-dione and Dithieno[3,2-b:2′,3′-d]silole Copolymer with a Power Conversion Efficiency of 7.3
by Chu, Ta-Ya and Lu, Jianping and Beaupré, Serge and Zhang, Yanguang and Pouliot, Jean-Rémi and Wakim, Salem and Zhou, Jiayun and Leclerc, Mario and Li, Zhao and Ding, Jianfu and Tao, Ye
Journal of the American Chemical Society, ISSN 0002-7863, 03/2011, Volume 133, Issue 12, pp. 4250 - 4253
A new alternating copolymer of dithienosilole and thienopyrrole-4,6-dione (PDTSTPD) possesses both a low optical bandgap (1.73 eV) and a deep highest occupied... 
TRANSISTORS | PERFORMANCE | PHOTOVOLTAIC PROPERTIES | ADDITIVES | LOW-BANDGAP POLYMER | BLENDS | CHEMISTRY, MULTIDISCIPLINARY | MORPHOLOGY | Pyrroles - chemistry | Polymers - chemistry | Molecular Structure | Organosilicon Compounds - chemistry | Solar cells | Design and construction | Research | Solar batteries
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8. Full Text Click Assembly of 1,2,3‐Triazole‐Linked Dendrimers, Including Ferrocenyl Dendrimers, Which Sense Both Oxo Anions and Metal Cations
by Ornelas, Cátia and Ruiz Aranzaes, Jaime and Cloutet, Eric and Alves, Sandra and Astruc, Didier
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2007, Volume 46, Issue 6, pp. 872 - 877
Clickety click: Click dendrimers, including the first click metallodendrimers, are synthesized in the presence of a stoichiometric amount of copper(I). The... 
ferrocenes | cations | dendrimers | anions | redox chemistry | Anions | Dendrimers | Cations | Redox chemistry | Ferrocenes | AZIDES | RECOGNITION | COMPLEXES | LIGATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | CHEMISTRY | ELECTRODE SURFACES | RECEPTORS | TRIAZOLE DENDRIMERS | Cations - chemistry | Oxidation-Reduction | Triazoles - chemistry | Ferrous Compounds - chemical synthesis | Metals - analysis | Cations - analysis | Dendrimers - chemical synthesis | Anions - chemistry | Metals - chemistry | Organosilicon Compounds - chemistry | Anions - analysis | Dendrimers - chemistry | Triazoles - chemical synthesis | Ferrous Compounds - chemistry | Molecular Structure | Polymers | Chemical Sciences
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9. Full Text Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications
by Zou, Hua and Wu, Shishan and Shen, Jian
Chemical Reviews, ISSN 0009-2665, 09/2008, Volume 108, Issue 9, pp. 3893 - 3957
ORGANIC-INORGANIC HYBRID | NITROXIDE-MEDIATED POLYMERIZATION | NANO-SIZED SILICA | SILICA COLLOIDAL NANOCOMPOSITES | SURFACE-INITIATED POLYMERIZATION | NONLINEAR VISCOELASTIC BEHAVIOR | IN-SITU POLYMERIZATION | SOL-GEL PROCESS | TRANSFER RADICAL POLYMERIZATION | POLY(METHYL METHACRYLATE)/SILICA NANOCOMPOSITES | CHEMISTRY, MULTIDISCIPLINARY | Particle Size | Colloids - chemistry | Organosilicon Compounds - chemical synthesis | Nanocomposites - chemistry | Organosilicon Compounds - chemistry | Silicon Dioxide - chemistry | Surface Properties | Models, Molecular | Polymers - chemistry | Molecular Structure | Colloids - chemical synthesis | Nanoparticles | Polymerization | Chemical properties | Structure | Silica | Analysis
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10. Full Text Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex
by Morgan, Erin and MacLean, Darren F and McDonald, Robert and Turculet, Laura
Journal of the American Chemical Society, ISSN 0002-7863, 10/2009, Volume 131, Issue 40, pp. 14234 - 14236
Ir silyl pincer complexes insert into the N−H bonds of anilines and ammonia under mild conditions to form isolable [Cy-PSiP]Ir(H)(NHR) complexes that are... 
ROOM-TEMPERATURE | HYDROGEN | HYDRIDE COMPLEX | CATALYTIC HYDROAMINATION | ANILINES | REACTIVITY | OXIDATIVE ADDITION | CLEAVAGE | EXCHANGE | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Magnetic Resonance Spectroscopy - methods | Organosilicon Compounds - chemistry | Amides - chemistry | Crystallography, X-Ray | Organometallic Compounds - chemistry | Ammonia - chemistry | Aniline Compounds - chemistry | Iridium - chemistry | Rhodium - chemistry | Aniline | Rhodium | Analysis | Chemical properties | Iridium | Organosilicon compounds | Structure | Elimination reactions
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11. Full Text Multifunctional gold nanostar-based nanocomposite: Synthesis and application for noninvasive MR-SERS imaging-guided photothermal ablation
by Gao, Yongping and Li, Yongsheng and Chen, Jianzhuang and Zhu, Shaojia and Liu, Xiaohang and Zhou, Liangping and Shi, Ping and Niu, Dechao and Gu, Jinlou and Shi, Jianlin
Biomaterials, ISSN 0142-9612, 2015, Volume 60, pp. 31 - 41
Abstract We report here the design and facile synthesis of multifunctional gold nanostars based nanocomposites (MGSNs) through direct organosilica coating onto... 
Advanced Basic Science | Dentistry | Photothermal therapy | Gold | Nanocomposite | MRI | SERS | HIGH-PERFORMANCE | MATERIALS SCIENCE, BIOMATERIALS | NANOPROBES | PHOTODYNAMIC THERAPY | CONTRAST AGENTS | ENGINEERING, BIOMEDICAL | NANORODS | LIVING MICE | CANCER-DETECTION | NANOSHELLS | IN-VIVO | RAMAN NANOPARTICLE | Gold - chemistry | Nanocomposites - therapeutic use | Nanocomposites - chemistry | Humans | Chelating Agents - chemistry | Magnetic Resonance Imaging - methods | Polyethylene Glycols - chemistry | Spectrum Analysis, Raman - methods | Polyethylene Glycols - therapeutic use | Neoplasms - therapy | Phototherapy - methods | Animals | Heterocyclic Compounds - chemistry | Organosilicon Compounds - chemistry | Organosilicon Compounds - therapeutic use | Cell Line, Tumor | Gold - therapeutic use | Organometallic Compounds - therapeutic use | Nanocomposites - ultrastructure | Organometallic Compounds - chemistry | Mice, Inbred BALB C | Heterocyclic Compounds - therapeutic use | Neoplasms - pathology | Chelating Agents - therapeutic use | Magnetic resonance imaging | Anisotropy | Chelates | Surgical implants | Biomedical materials | Synthesis | Imaging | Nanostructure | Ablation | Tumors
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12. Full Text Anisotropic Growth-Induced Synthesis of Dual-Compartment Janus Mesoporous Silica Nanoparticles for Bimodal Triggered Drugs Delivery
by Li, Xiaomin and Zhou, Lei and Wei, Yong and El-Toni, Ahmed Mohamed and Zhang, Fan and Zhao, Dongyuan
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 42, pp. 15086 - 15092
Multifunctional dual-compartment Janus mesoporous silica nanocomposites of UCNP@SiO2@mSiO2&PMO (UCNP = upconversion nanoparticle, PMO = periodic mesoporous... 
UP-CONVERSION LUMINESCENT | OPTICAL-PROPERTIES | CONTROLLED-RELEASE | NANOSPHERES | BIOMEDICAL APPLICATIONS | NANOSTRUCTURES | CHEMISTRY, MULTIDISCIPLINARY | Nanocomposites - chemistry | Nanoparticles - chemistry | Nanotechnology - methods | Humans | Silicon Dioxide - chemistry | Doxorubicin - chemistry | Drug Carriers - chemical synthesis | Drug Carriers - chemistry | Organosilicon Compounds - chemistry | Anisotropy | Hydrophobic and Hydrophilic Interactions | HeLa Cells | Porosity | Doxorubicin - pharmacology | Chemical properties | Chemical synthesis | Silica | Analysis
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13. Full Text SuFEx‐Based Polysulfonate Formation from Ethenesulfonyl Fluoride–Amine Adducts
by Wang, Hua and Zhou, Feng and Ren, Gerui and Zheng, Qinheng and Chen, Hongli and Gao, Bing and Klivansky, Liana and Liu, Yi and Wu, Bin and Xu, Qingfeng and Lu, Jianmei and Sharpless, K. Barry and Wu, Peng and Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 37, pp. 11203 - 11208
The SuFEx‐based polycondensation between bisalkylsulfonyl fluorides (AA monomers) and bisphenol bis(t‐butyldimethylsilyl) ethers (BB monomers) using... 
click chemistry | ethenesulfonyl fluoride | SuFEx reaction | polysulfonate formation | bifluoride salt | SULFONYL FLUORIDES | 1,3-DIPOLAR CYCLOADDITIONS | BLOCK-COPOLYMERS | TERMINAL ALKYNES | EXPONENTIAL-GROWTH | SILYL ETHERS | CHEMISTRY, MULTIDISCIPLINARY | POSTPOLYMERIZATION MODIFICATION | POLYMER | SURFACE | Amines - chemistry | Sulfonic Acids - chemistry | Fluorides - chemistry | Organosilicon Compounds - chemistry | Click Chemistry | Polymerization | Phenols - chemistry | Aniline Compounds - chemistry | Ethylenes - chemistry | Benzhydryl Compounds - chemistry | Amines | Fluorides | Fluoride | Chloride | Catalysts | Bisphenols | Phenols | Ethers | Monomers | Adducts | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY | MATERIALS SCIENCE
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14. Full Text Highly Fluorescent Solid-State Asymmetric Spirosilabifluorene Derivatives
by Lee, Sang Ho and Jang, Bo-Bin and Kafafi, Zakya H
Journal of the American Chemical Society, ISSN 0002-7863, 06/2005, Volume 127, Issue 25, pp. 9071 - 9078
A series of four asymmetrically aryl-substituted 9,9‘-spiro-9-silabifluorene (SSF) derivatives, 2,2‘-di-tert-butyl-7,7‘-diphenyl-9,9‘-spiro-9-silabifluorene... 
LIGHT-EMITTING-DIODES | SILOLE DERIVATIVES | ORGANIC ELECTROLUMINESCENT DEVICES | ACIDS | STABILITY | ELECTRON-TRANSPORTING MATERIALS | EMISSION | CHEMISTRY, MULTIDISCIPLINARY | GLASSES | Chlorides - chemical synthesis | Organosilicon Compounds - chemical synthesis | Temperature | Luminescence | Silicon Compounds - chemical synthesis | Silicon Compounds - chemistry | Chlorides - chemistry | Quantum Theory | Fluorenes - chemistry | Cyclization | Organosilicon Compounds - chemistry | Biphenyl Compounds - chemical synthesis | Spiro Compounds - chemical synthesis | Electrochemistry | Molecular Structure | Biphenyl Compounds - chemistry | Spiro Compounds - chemistry | Thermal properties | Silicon diodes | Ring formation (Chemistry) | Analysis | Electric properties
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