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chemistry, multidisciplinary (53) 53
phosphorus (38) 38
white phosphorus (38) 38
p-4 activation (35) 35
chemistry (28) 28
p-4 (26) 26
activation (21) 21
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arsenic (9) 9
carbenes (9) 9
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lewis-acid (8) 8
nmr spectroscopy (8) 8
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oxidation (8) 8
p5x2+ x (8) 8
catalysis (7) 7
chemistry, organic (7) 7
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iron (5) 5
mathematical analysis (5) 5
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silicon (5) 5
silylene (5) 5
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aggregation (4) 4
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as-4 (4) 4
butan (4) 4
butane (4) 4
butterflies (4) 4
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carben (4) 4
chemical industry (4) 4
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formations (4) 4
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mediated activation (4) 4
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p4 activation (4) 4
phosphines (4) 4
phosphorus - chemistry (4) 4
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acid derivatives (3) 3
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Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 39, pp. 6601 - 6604
A new reaction mode for bicyclo[1.1.0]tetraphosphabutanes is reported. The C=S and C=N bonds of phenyl isothiocyanate reversibly insert into a P-P bond of... 
TRANSFORMATION | LEWIS-ACID | TETRAHEDRON | P-4 ACTIVATION | CHEMISTRY | REACTIVITY | METAL | WHITE PHOSPHORUS | FUNCTIONALIZED LIGANDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 41, pp. 14592 - 14604
The reaction of LGa (L = Dipp­(4-(Dipp-imino)­pent-2-en-2-yl)­amide; Dipp: 2,6-diisopropylphenyl) and white phosphorus was revisited. A plethora of... 
CARBENE ANALOG | STRUCTURAL CHEMISTRY | TETRAHEDRON | CRYSTAL-STRUCTURE | COVALENT RADII | COMPLEXES | P-4 ACTIVATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | TRANSFORMATIONS | P-P BONDS | Chemical reactions | Usage | Phosphorus compounds | Chemical properties
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 8/2014, Volume 43, Issue 18, pp. 6639 - 6657
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their... 
ACTIVATION | PHOSPHENIUM IONS | CRYSTAL-STRUCTURE | P5X2+ X | NUCLEAR-MAGNETIC-RESONANCE | P-4 TETRAHEDRON | P-P BOND | WHITE PHOSPHORUS | CHEMISTRY, MULTIDISCIPLINARY | P-31 | Chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2013, Volume 52, Issue 42, pp. 11078 - 11082
The cage compound [DippP5Cl][GaCl4] (Dipp=2,6‐diisopropylphenyl) reacts with an NHC (N‐heterocyclic carbene) by an unprecedented [3+2] fragmentation of the P5+... 
carbenes | phosphorus cations | structure elucidation | triphosphaallyl anion | DFT calculations | OXIDATION | PHOSPHORUS | INSERTION | ACTIVATION | ANION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | P-P BONDS | P5X2+ X | CHEMISTRY | P-4 TETRAHEDRON | Pyridine
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2015, Volume 21, Issue 1, pp. 191 - 198
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2017, Volume 56, Issue 23, pp. 6655 - 6659
The activation of yellow arsenic is possible with the silylene [ePhC(NtBu)(2)SiN(SiMe3)(2)] (1) and the disilene... 
TRANSFORMATION | COMPLEXES | P-4 ACTIVATION | arsenic | CHEMISTRY, MULTIDISCIPLINARY | small-molecule activation | silylene | density functional calculations | ELEMENTS | silicon | TETRAHEDRON | CAGE COMPOUNDS | DINITROGEN | WHITE PHOSPHORUS | BOND | AGGREGATION
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2016, Volume 52, Issue 39, pp. 6601 - 6604
A new reaction mode for bicyclo[1.1.0]tetraphosphabutanes is reported. The C&z.dbd; S and C&z.dbd; N bonds of phenyl isothiocyanate reversibly insert into a... 
Phenyls | X-rays | Insertion | Inserts | Nickel | NMR spectroscopy | Bonding | Isomers
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 11, pp. 1342 - 1359
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2016, Volume 45, Issue 5, pp. 1953 - 1961
On account of our interest in P-4 activation by phosphenium ion insertion into P-P bonds we have developed synthetic routes to bicyclic N-P-Si-heterocycle 7... 
ACTIVATION | INSERTION | COMPLEXES | N BOND | COORDINATION | P-4 TETRAHEDRON | PHOSPHAZENES | P-P BOND | WHITE PHOSPHORUS | MAIN-GROUP ELEMENTS | CHEMISTRY, INORGANIC & NUCLEAR | Cations | Gallium - chemistry | Heterocyclic Compounds - chemistry | Silicon - chemistry | Phosphorus Compounds - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 27, pp. 7858 - 7862
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2010, Volume 49, Issue 38, pp. 6860 - 6864
Under control: Controlled self‐aggregation of P4 to extended neutral polyphosphorus cages was achieved in the presence of cobalt complex fragments. X‐ray... 
allotropes | cobalt | cage compounds | phosphorus | TRANSITION-METAL-COMPLEXES | COORDINATION SPHERE | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON LOCALIZATION | COBALT COMPLEXES | LASER-ABLATION | CHEMISTRY | P-4 TETRAHEDRON | LIGAND | WHITE PHOSPHORUS | 1ST SALTS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2013, Volume 19, Issue 30, pp. 9895 - 9907
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 06/2012, Volume 638, Issue 7‐8, pp. 1103 - 1108
The reaction of several amino‐substituted mono‐ and dichlorophosphanes (R2N)nPCl3–n (n = 2, R = i‐Pr; n = 1, R = i‐Pr, Cy) with GaCl3 to form phosphenium... 
Main group elements | Phosphorus | P4 activation | Cations | Structure elucidation | INSERTION | PHOSPHENIUM IONS | CAGE | CHEMISTRY, INORGANIC & NUCLEAR | PHOSPHORUS CATIONS | P5X2+ X | CHEMISTRY | STRUCTURAL ALTERNATIVES | P-4 TETRAHEDRON | WHITE PHOSPHORUS | BOND
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 01/2020, Volume 142, Issue 3, pp. 1190 - 1195
Selective substitution and insertion reactions of silylenes into the cyclo-P, ring of [Cp*Fe(eta(5)-P-5)] are reported. The selective substitution of one P... 
TRANSFORMATION | OXIDATION | PHOSPHORUS | ELEMENTS | ACTIVATION | PENTAPHOSPHAFERROCENE | COMPLEXES | CHEMISTRY | P-4 TETRAHEDRON | CP-ASTERISK-FE(ETA-P-5) | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Structural Chemistry, ISSN 1040-0400, 12/2015, Volume 26, Issue 5, pp. 1335 - 1342
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2009, Volume 11, Issue 26, pp. 5273 - 5280
White phosphorus (P-4) is prone to undergo degradation by nucleophiles and is reluctant to do so with electrophiles. Silylenes possess a strong singlet... 
STABLE SILYLENES | CARBENES | BONDS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY | REACTIVITY | CHEMISTRY, PHYSICAL | ORBITALS | P-4 TETRAHEDRON | TRIALKYL PHOSPHITES | SINGLET | Thermodynamics | Automation | Silanes - chemistry | Phosphorus - chemistry | Molecular Structure | Catalysis | Ethylenes - chemistry
Journal Article