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chemistry, multidisciplinary (133) 133
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Chemical Science, ISSN 2041-6520, 2014, Volume 5, Issue 8, pp. 3221 - 3225
The sterically encumbered dimer [(CpFe)-Fe-BIG(CO)(2)(]2) (1) (Cp-BIG C-5(4-nBuC(6)H(4))(5)) is able to activate small tetrahedral molecules like P-4 and As-4... 
P4S3 | LIGANDS | PHOSPHORUS BOND-CLEAVAGE | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | COMPLEXES | P-4 ACTIVATION | CARBON-DISULFIDE | WHITE PHOSPHORUS | CHEMISTRY, MULTIDISCIPLINARY | Cage compounds | Cage | Forming | Cleavage | Activation | Dimers | Bonding | Radicals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7882 - 7885
Journal Article
Organometallics, ISSN 0276-7333, 01/2017, Volume 36, Issue 1, pp. 89 - 96
C–F bond activation is a challenging reaction with increasing importance in synthesis. The strength of the C–F bond and the shielding effect of the fluorine... 
URANIUM | HETEROCYCLES | FLUORINE EXCHANGE | P-4 ACTIVATION | FLUOROCARBONS | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | COORDINATION | LANTHANIDE | HYDRODEFLUORINATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chem. Sci, ISSN 2041-6520, 2014, Volume 5, Issue 8, pp. 3221 - 3225
The sterically encumbered dimer [CpBIGFe(CO)2]2 (1) (CpBIG = C5(4-nBuC6H4)5) is able to activate small tetrahedral molecules like P4 and As4 as well as the... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 49, pp. 9444 - 9447
Carbenes more than measure up: Singlet stable carbenes compete with transition metals in the activation of enthalpically strong bonds, as shown by the cleavage... 
boranes | bond activation | carbenes | silanes | phosphanes | TRANSITION-METAL-COMPLEXES | AMMONIA | LEWIS PAIR | DIHYDROGEN ACTIVATION | P-4 ACTIVATION | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | IMIDAZOLE DERIVATIVES | MEDIATED ACTIVATION | ALKYL AMINO CARBENES | WHITE PHOSPHORUS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2016, Volume 22, Issue 37, pp. 13032 - 13036
We report the reactions of catecholborane (HBcat; 1) with unsaturated and saturated NHCs as well as CAACMe. Mono‐NHC adducts of the type HBcat⋅NHC (NHC=nPr2Im,... 
N-heterocyclic carbene | B–H bond activation | ring expansion reaction | catecholborane | C–N bond cleavage | MECHANISM | COMPLEXES | SECONDARY | N-HETEROCYCLIC CARBENES | BOND-CLEAVAGE | BORANE | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | C-N bond cleavage | P-4 | PHOSPHINES | CHEMISTRY | B-H bond activation | Bonds | Expansion | Backbone | Chemical bonds | Forming | Activation | Carbenes | Bonding | Dipping | Adducts
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2014, Volume 2014, Issue 10, pp. 1652 - 1659
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2018, Volume 57, Issue 28, pp. 8760 - 8764
In a systematic study of the activation of As-4, three [LCo(tol)] (L=beta-diiminato) complexes have revealed different steric and electronic influences.... 
PHOSPHORUS | beta-diiminato ligand | MAIN-GROUP | COMPOUND | REACTIVITY | ELECTRON-DIFFRACTION | POLYARSENIDES | CHEMISTRY, MULTIDISCIPLINARY | small-molecule activation | yellow arsenic | ELEMENTS | P-4 TRANSFORMATIONS | REDUCTION | paramagnetic compounds | substituent effects | ANTIMONY
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2016, Volume 55, Issue 47, pp. 14798 - 14801
Bismuth diphenylphosphanides Bi(NONR)(PPh2) (NONR=[O(SiMe2NR)(2)], R=tBu, 2,6-iPr(2)C(6)H(3), Aryl) undergo facile decomposition via single-electron processes... 
bond homolysis | ELEMENTS | PHOSPHORUS | P-4 activation | phosphanides | COMPLEX | SINGLE | main-group radicals | CRYSTAL-STRUCTURE | PHOSPHIDE | CHEMISTRY, MULTIDISCIPLINARY | bismuth
Journal Article
by Lu, W and Xu, K and Li, YX and Hirao, H and Kinjo, R
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2018, Volume 57, Issue 48, pp. 15691 - 15695
Metal-free activation of homoatomic E-E sigma bonds (E = P, B) in white phosphorus (P-4) and bis(catecholato)diboron (B(2)cat(2)) with a 1,2-diboraallene 1 is... 
OXIDATION | catenation | INSERTION | BORON | REACTIVITY | STRUCTURAL-CHARACTERIZATION | diboration | diborene | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE | white phosphorus | NEUTRAL DIBORENE | sigma-bond activation | B-B | P-4 TETRAHEDRON | MULTIPLE BONDS
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2012, Volume 48, Issue 16, pp. 2169 - 2179
The activation of phosphorus remains a popular and competitive area of research driven by the dual goals of finding ways to avoid the environmentally... 
CARBONYL-COMPLEXES | CROSS-COUPLING REACTIONS | CRYSTALLINE CARBENE | TRANSITION-METAL-COMPLEXES | N-HETEROCYCLIC-CARBENE | P-4 ACTIVATION | BASE-STABILIZED DICHLOROSILYLENE | WHITE PHOSPHORUS | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | DOUBLE-BOND | Valence | Analogue | Chemists | Phosphorus | Activation | Derivatives | Carbenes | Alkynes
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 04/2019, Volume 38, Issue 7, pp. 1436 - 1444
Tetraisocyanide complex Co(CNArmes2)(4) (Ar-Mes2 = 2,6-(2,4,6-Me3C6H2)(2)C6H3) serves as a crystallographically characterized, thermally stable isocyano... 
NHC LIGATION SYNTHESIS | CARBON-MONOXIDE SUBSTITUTION | NUCLEOPHILIC-SUBSTITUTION | MIT VERSCHIEDENARTIGEN BASEN | P-4 ACTIVATION | DINUCLEAR | CHEMISTRY, ORGANIC | BOND ACTIVATION | METAL | ZUR KENNTNIS | RADICAL REACTIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 07/2019, Volume 10, Issue 26, pp. 6476 - 6481
The facile synthesis of a rare two-coordinate acyclic silylene (R2Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly... 
FUNCTIONALIZATION | PHOSPHORUS | STABLE SILYLENE | P-4 | SILICON | 2-COORDINATE | E-H BONDS | MAIN-GROUP ELEMENTS | N-HETEROCYCLIC OLEFINS | COMPLEXATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 07/2019, Volume 10, Issue 26, pp. 6476 - 6481
The facile synthesis of a rare two-coordinate acyclic silylene (R2Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly... 
FUNCTIONALIZATION | PHOSPHORUS | STABLE SILYLENE | P-4 | SILICON | 2-COORDINATE | E-H BONDS | MAIN-GROUP ELEMENTS | N-HETEROCYCLIC OLEFINS | COMPLEXATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 50, pp. 17652 - 17661
We report the synthesis and comprehensive study of the electronic structure of a unique series of dinuclear group 5 cyclo-tetraphosphide inverted sandwich... 
NIOBIUM(III) IMIDO COMPLEX | FUNCTIONALIZATION | TRIPLE-BOND | TRANSITION-METAL-COMPLEXES | LIGANDS | CAGE COMPOUNDS | POLYPHOSPHIDES | P-4 ACTIVATION | CLEAVAGE | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 04/2013, Volume 2013, Issue 12, pp. 2051 - 2058
The reaction of [Ni2(iPr2Im)4(cod)] (1) with white phosphorus led to dinuclear [{Ni(iPr2Im)2}2(μ,η2:2‐P2)] (2) in excellent yield. This reaction represents the... 
Phosphorus | Nickel | Density functional calculations | NHC ligands | Platinum | AB-INITIO BENCHMARK | TRANSITION-METAL-COMPLEXES | TRIPLE BONDS | P-4 ACTIVATION | C-F ACTIVATION | PHOSPHIDO COMPLEXES | OXIDATIVE ADDITION | DIHYDROGEN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | IMIDAZOL-2-YLIDENE LIGANDS | WHITE PHOSPHORUS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2013, Volume 19, Issue 28, pp. 9114 - 9117
Mo and Si in concert: Fragmentation and simultaneous activation of white phosphorus was achieved by a complex featuring reactive main‐group‐element and... 
metallocenophanes | P4 activation | silicon | metallocenes | molybdenum | phosphorus | activation | OXIDATION | TRANSITION-METAL-COMPLEXES | P-4 ACTIVATION | REACTIVITY | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTS | MEDIATED ACTIVATION | CHEMISTRY | BOND | SI-P | Molybdenum | Organophosphorus compounds | Metallocenes | Electronic structure | Computation | Concerts | Phosphorus | Activation | Silicon | Fragmentation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2012, Volume 51, Issue 34, pp. 8628 - 8631
Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2... 
ruthenium | iodine | polyphosphanes | hydrolysis | phosphorus | CAGE | STABILIZATION | COMPLEXES | P-4 ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | SILYLENE | CHEMISTRY | GENERATION | AGGREGATION | Hydrolysis | Organophosphorus compounds | Ruthenium | Stabilization | Phosphorus | Activation | Formations | Transformations | Iodine
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 12/2011, Volume 50, Issue 24, pp. 12349 - 12358
The Nb–P triple bond in [PNb(N[Np]Ar)3]− (Np = CH2 t Bu; Ar = 3,5-Me2C6H3) has produced the first case of P4 activation by a metal–ligand multiple bond.... 
TRANSFORMATION | ELECTRON-GAS | TERMINAL PHOSPHIDE | LIGANDS | APPROXIMATION | CORRELATION-ENERGY | P-4 ACTIVATION | COORDINATION | MOLECULES | COBALT | CHEMISTRY, INORGANIC & NUCLEAR | Usage | Phosphorus compounds | Analysis | Organometallic compounds | Chemical bonds | Nuclear magnetic resonance spectroscopy | Chemical properties | Niobium
Journal Article