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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2010, Volume 49, Issue 23, pp. 3947 - 3951
CF bond borylation: A 16‐electron rhodium(I)–boryl complex was synthesized by borylation of a rhodium(I)–fluorine complex. The former reacts with benzene or... 
CH activation | CF activation | boryl ligands | borylation | rhodium | Boryl ligands | C-H activation | Rhodium | C-F activation | Borylation | TRANSITION-METAL-COMPLEXES | P-C | DEHYDROGENATIVE BORYLATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | CARBON-FLUORINE BONDS | COUPLING REACTIONS | DIBORON REAGENTS | B-H | N-HETEROCYCLES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 13, pp. 3174 - 3177
Herein the first P−C(sp3) bond cleavage and radical alkynylation of α‐phosphorus alcohols to construct phosphonoalkynes is reported. The phosphorus radical is... 
P−C(sp3) bond cleavage | radicals | alkynylation | photochemistry | phosphorus | P−C(sp | bond cleavage | ACIDS | C-P | ELIMINATION | IODINE(III) REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | DECARBOXYLATIVE ALKYNYLATION | CENTERED RADICALS | LASER FLASH-PHOTOLYSIS | ESTERS | GENERATION | P-C(sp) bond cleavage | OXIDES | Reagents | Phosphorus | Alcohol | Cleavage | Catalysis | Iodine | Alcohols
Journal Article
Journal of Physics and Chemistry of Solids, ISSN 0022-3697, 07/2019, Volume 130, pp. 250 - 255
Crystallized black phosphorus-graphite (BP-G) composites with tunable phosphorus carbon (P–C) bonds have been prepared by a facile high pressure and high... 
Electrochemical performance | P–C bonds | Crystallized phosphorus/carbon composites | High pressure | CAPACITY | PHYSICS, CONDENSED MATTER | TRANSPORT-PROPERTIES | GRAPHENE | NANOSHEETS | POROUS CARBON | CHEMISTRY, MULTIDISCIPLINARY | PHOTOCATALYST | LITHIUM-ION | HIGH-PERFORMANCE ANODE | BLACK PHOSPHORUS | P-C bonds | G-C3N4 | Boron nitride | Electrochemistry | Graphene | Bonds | Graphite
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2014, Volume 50, Issue 2, pp. 162 - 164
Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre... 
Journal Article
Organometallics, ISSN 0276-7333, 10/2018, Volume 37, Issue 20, pp. 3425 - 3436
The ability of the title anion to act as an acceptor of simple donors and to participate in E–H bond activation processes (E = p-block element) was analyzed by... 
DIMOLYBDENUM COMPLEXES | TOTAL ENERGIES | MOLYBDENUM | AB-INITIO | P-C | SET MODEL CHEMISTRY | C-C | REACTIVITY | CHEMISTRY, ORGANIC | RHENIUM | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 51, pp. 18594 - 18597
The reactivity of phosphenium dication [(Ph3P)2C‐P‐NiPr2]2+, 12+, towards pyridine N‐oxide (O‐py) has been investigated. The resulting oxophosphonium dication... 
P−C bond oxidation | Baeyer–Villiger oxidation | Criegee intermediate | main-group chemistry | phosphenium dication | Baeyer-Villiger oxidation | P-C bond oxidation | REAGENT | INSERTION | ACTIVATION | HYDROGENATION | CONVERSION | IRON | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | H BONDS | PRECURSORS | CATALYSTS | Insertion | Pyridines | Oxygen | Oxidation | Ligands | Analogue | Bonding
Journal Article
Organic Letters, ISSN 1523-7060, 06/2019, Volume 21, Issue 11, pp. 4177 - 4181
The nickel-catalyzed cyclization of bisphosphine derivatives to form various phosphacycles is reported. The reaction proceeds via the cleavage of two... 
P,N LIGANDS | PALLADIUM | PHOSPHINE | HECK | ARYL HALIDES | P-C | CHEMISTRY, ORGANIC | TRIPHENYLPHOSPHINE | SALTS | TRIARYLPHOSPHINES | METATHESIS
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2014, Volume 50, Issue 2, pp. 162 - 164
Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre... 
N-HETEROCYCLIC CARBENE | ACTIVATION | CONJUGATED POLYMERS | LIGANDS | COMPLEXES | REACTIVITY | POLYMERIZATION | WHITE PHOSPHORUS | P=C BOND | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2018, Volume 2018, Issue 33, pp. 3778 - 3784
It is demonstrated that backbone chloro(phenyl)phosphanyl‐substituted imidazole‐2‐thiones 3 (N‐R = Me, Et, nBu) can be easily synthesized which allow for a... 
Heterocycles | Phosphorus | P–C bond cleavage | Cyclization | ALKALI | IHR REAKTIVES VERHALTEN | NUCLEOPHILIC-SUBSTITUTION | IMIDAZOLE-2-THIONES | MIT DIPHENYLPHOSPHIN-NATRIUM | P-C bond cleavage | CHEMISTRY, INORGANIC & NUCLEAR | Substitution reactions | Derivatives | Isomers | Imidazole
Journal Article
Organometallics, ISSN 0276-7333, 04/2010, Volume 29, Issue 7, pp. 1824 - 1831
Density functional theory is used to explore the origins of the chemoselectivity and regioselectivity of activation of C−F bonds in pentafluoropyridine with... 
CARBON-FLUORINE BONDS | DIRECT ARYLATION | CATALYTIC HYDRODEFLUORINATION | COUPLING REACTIONS | P-C | CORRELATION-ENERGY | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | RHODIUM COMPLEXES | GRIGNARD-REAGENTS | H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Current Organic Synthesis, ISSN 1570-1794, 2014, Volume 11, Issue 3, pp. 429 - 453
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 05/2016, Volume 11, Issue 9, pp. 1353 - 1356
A novel catalytic asymmetric P−C bond formation between phosphinates/phosphine oxide and allylic carbonates was developed. This methodology could not only... 
organocatalysis | kinetic resolution | P−C bond formation | 1,3-bisphosphinylpropanes | P-stereogenic compounds | P-C bond formation | HYDROPHOSPHINATION | SUBSTITUTION | HYDROGENATION | ALPHA,BETA-UNSATURATED ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOPHILES | KETONES | ESTERS | CONSTRUCTION | BAYLIS-HILLMAN CARBONATES | PHOSPHINE OXIDES | Catalysis
Journal Article
Dalton Transactions, ISSN 1477-9226, 06/2014, Volume 43, Issue 24, pp. 9038 - 9044
Thioether-phosphines, 1 and 2, were applied for the stabilisation of palladium nanoparticles (PdNPs) synthesised by a bottom-up methodology, using... 
P-C BOND | HYDRODESULFURIZATION REACTION | HYDROGENATION | RUTHENIUM NANOPARTICLES | CARBONYL CLUSTERS | COMPLEXES | REACTIVITY | OXIDATIVE ADDITION | IONIC LIQUIDS | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR | Nanoparticles | Synthesis | Surface chemistry | Ligands | Activation | Palladium | X-ray photoelectron spectroscopy | Activation analysis
Journal Article