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palladium-mediated polymerization (36) 36
polymer science (17) 17
copolymerization (14) 14
polymers (14) 14
diazocarbonyl compounds (12) 12
carbenes (11) 11
chemistry, multidisciplinary (11) 11
polymerization (10) 10
alkyl diazoacetates (9) 9
carbene polymerization (7) 7
diazo compounds (7) 7
diazoketones (7) 7
chain (6) 6
alpha-diazocarbonyl compounds (5) 5
catalysis (5) 5
catalysts (5) 5
chemistry, organic (5) 5
complexes (5) 5
copolymers (5) 5
dimethylsulfoxonium methylide (5) 5
monomers (5) 5
palladium (5) 5
chemistry, inorganic & nuclear (4) 4
diazo-compounds (4) 4
ethyl diazoacetate (4) 4
living polymethylene synthesis (4) 4
poly (4) 4
polyhomologation (4) 4
polymer (4) 4
rhodium (4) 4
block-copolymers (3) 3
carbon (3) 3
chemistry (3) 3
chemistry, physical (3) 3
containing diazoacetates (3) 3
copolymerisation (3) 3
ethylene (3) 3
index medicus (3) 3
inkorporierung (3) 3
isomerization radical polymerization (3) 3
living polymerization (3) 3
methyl-methacrylate (3) 3
migratory insertion (3) 3
olefins (3) 3
oligomers (3) 3
radical polymerization (3) 3
stereospecific carbene polymerization (3) 3
tert-butyl maleate (3) 3
thermotropic behavior (3) 3
transition-metal-complexes (3) 3
activation (2) 2
alkynes (2) 2
architectures (2) 2
azo (2) 2
c-h insertion (2) 2
carben (2) 2
carbene (2) 2
carbon-carbon composites (2) 2
chain-transfer (2) 2
chains (2) 2
chemical synthesis (2) 2
cross-coupling (2) 2
cross-coupling reactions (2) 2
diazo compound (2) 2
diazocarbonyl compound (2) 2
diazoketone (2) 2
diazomethane (2) 2
diazoverbindung (2) 2
efficient synthesis (2) 2
esters (2) 2
ethyl-acetate (2) 2
ethylacetat (2) 2
incorporation (2) 2
kinetics (2) 2
kohlenstoff (2) 2
main-chain (2) 2
mechanism (2) 2
methane - analogs & derivatives (2) 2
methane - chemistry (2) 2
molecular structure (2) 2
molecular-mass (2) 2
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oligomer (2) 2
oligomerisation (2) 2
oligomerization (2) 2
organic chemistry (2) 2
palladium complex (2) 2
pd-initiated polymerization (2) 2
polymer sciences (2) 2
polymerisation (2) 2
precursors (2) 2
rhodium - chemistry (2) 2
side-chains (2) 2
soft and granular matter, complex fluids and microfluidics (2) 2
surface-catalyzed growth (2) 2
syndiotactic polymethylenes (2) 2
thermal properties (2) 2
through-space (2) 2
transfer radical polymerization (2) 2
1,2-disubstituted ethylenic monomers (1) 1
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Chemical Society reviews, ISSN 0306-0012, 2010, Volume 39, Issue 5, pp. 1706 - 1723
In this critical review we summarise the currently available ‘C1 polymerisation’ techniques as valuable alternatives for ‘C2 polymerisation’ in the preparation... 
ALPHA-DIAZOCARBONYL COMPOUNDS | TRANSITION-METAL-COMPLEXES | CATALYZED INSERTION | FISCHER CARBENE | MIGRATORY INSERTION | DIMETHYLSULFOXONIUM METHYLIDE | DIAZO-COMPOUNDS | PALLADIUM-MEDIATED POLYMERIZATION | LIVING POLYMETHYLENE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | ETHYL DIAZOACETATE
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 11/2018, Volume 374, pp. 261 - 278
Journal Article
ACS Catalysis, ISSN 2155-5435, 2014, Volume 4, Issue 5, pp. 1376 - 1389
This paper discloses the DFT-computed pathways for chain propagation, chain transfer, and chain termination during carbene polymerization catalyzed by cationic... 
DFT | carbene polymerization | diazo compounds | computational studies | rhodium | POLYMERS | ACTIVATION | CHEMISTRY, PHYSICAL | COPOLYMERS | DIAZOCARBONYL COMPOUNDS | ATOMS LI | TRANSITION METAL | ZETA VALENCE QUALITY | PALLADIUM-MEDIATED POLYMERIZATION | GAUSSIAN-BASIS SETS
Journal Article
Chemical Society reviews, ISSN 0306-0012, 2013, Volume 42, Issue 13, pp. 5809 - 5832
Journal Article
Angewandte Chemie, International Edition, ISSN 1433-7851, 2012, Volume 51, Issue 21, pp. 5157 - 5161
Journal Article
Macromolecules, ISSN 0024-9297, 01/2018, Volume 51, Issue 2, pp. 328 - 335
Pd-initiated polymerization of fluorine (F) containing alkyl and phenyl diazoacetates is described. Polymerization of 2,2,2-trifluoroethyl diazoacetate... 
CARBENE POLYMERIZATION | SIDE-CHAINS | POLYMERS | POLYMER SCIENCE | THERMOTROPIC BEHAVIOR | BLOCK-COPOLYMERS | CONSTRUCTION | SYNDIOTACTIC POLYMETHYLENES | PALLADIUM-MEDIATED POLYMERIZATION | HOMOPOLYMERS | ARCHITECTURES
Journal Article
Macromolecules, ISSN 0024-9297, 2012, Volume 45, Issue 9, pp. 3711 - 3721
We present our results obtained in the Rh-catalyzed carbene copolymerization of diazomethane and diazoesters as a new approach to functional polymer synthesis.... 
CHAIN | ALTERNATING COPOLYMERIZATION | POLYMER SCIENCE | ETHYLENE | METHYL-METHACRYLATE | CARBON-MONOXIDE | COMPLEXES | EFFICIENT SYNTHESIS | PALLADIUM-MEDIATED POLYMERIZATION | ISOSPECIFIC POLYMERIZATION | CATALYSTS
Journal Article
Macromolecules, ISSN 0024-9297, 09/2018, Volume 51, Issue 18, pp. 7248 - 7256
Herein we describe the Rh-catalyzed Cl polymerization of silyl-protected diazoacetates of the general formula HC(=N-2)C(=O)O(CH2)(x)OSiR3, where x = 2-5. After... 
CARBENE POLYMERIZATION | N-ISOPROPYLACRYLAMIDE | POLY(SUBSTITUTED METHYLENE)S | POLYMER SCIENCE | THERMOTROPIC BEHAVIOR | LIVING CATIONIC-POLYMERIZATION | RADICAL POLYMERIZATION | PALLADIUM-MEDIATED POLYMERIZATION | CRITICAL SOLUTION TEMPERATURE | STIMULI-RESPONSIVE POLYMERS | CONTAINING DIAZOACETATES
Journal Article
Macromolecules, ISSN 0024-9297, 11/2009, Volume 42, Issue 22, pp. 8608 - 8610
Journal Article
Macromolecules, ISSN 0024-9297, 2014, Volume 47, Issue 16, pp. 5484 - 5491
The living Cl polymerization of sulfoxide ylides initiated by organoborane is one of the few methods for controlling the molecular weight, polydispersity, and... 
SULFUR YLIDES | POLYMERS | POLYMER SCIENCE | DIMETHYLSULFOXONIUM METHYLIDE | LIVING POLYMERIZATION | COPOLYMERS | PALLADIUM-MEDIATED POLYMERIZATION | POLYHOMOLOGATION | ORGANOBORANES
Journal Article
by Xiao, LQ and Chen, C and Chen, FJ and Liu, LJ
PROGRESS IN CHEMISTRY, ISSN 1005-281X, 09/2014, Volume 26, Issue 9, pp. 1506 - 1515
Carbene polymerization of alpha-diazocarbonyl compounds is a new type reaction which has been developed in recent years for the synthesis of functional... 
ALKENE POLYMERIZATION | POLYMERS | diazo compound | STEREOSELECTIVE POLYMERIZATION | CHAIN-TRANSFER | TRANSFER RADICAL POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | DIAZOCARBONYL COMPOUNDS | palladium | DIAZOKETONES | PALLADIUM-MEDIATED POLYMERIZATION | carbene polymerization | COPOLYMERIZATION | METAL-COMPLEXES | rhodium
Journal Article
Organometallics, ISSN 0276-7333, 2010, Volume 29, Issue 12, pp. 2823 - 2826
Stereoselective polymerization of "carbenes" from diazo esters mediated by [(L-prolinate)RhI(Me2cod)] allows the formation of highly syndiotactic, fully... 
COMPLEXES | CHEMISTRY, ORGANIC | DIAZOKETONES | DIAZO-COMPOUNDS | PALLADIUM-MEDIATED POLYMERIZATION | COPOLYMERIZATION | DIAZOCARBONYL COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
KOBUNSHI RONBUNSHU, ISSN 0386-2186, 2015, Volume 72, Issue 7, pp. 375 - 384
We describe the polymerization of a variety of diazocarbonyl compounds initiated with Pd complexes. Relatively low molecular weight polymers (M-n = ca. 2000)... 
Palladium Complex | CARBENE POLYMERIZATION | CHAIN | Polymerization Mechanism | POLYMER SCIENCE | Poly(substituted methylene) | Diazocarbonyl Compound | Chain Transfer | Hydroxy-Containing Polymer | PALLADIUM-MEDIATED POLYMERIZATION | ALKYL DIAZOACETATES
Journal Article
Dalton Transactions, ISSN 1477-9226, 2009, Issue 41, pp. 8970 - 8976
New Rh-I(cod) complexes of N-heterocyclic carbene ligands containing a pending pyridyl moiety for subsequent binding of Zn-II-templates were designed for... 
PREPARE BIDENTATE LIGANDS | BUILDING-BLOCKS | BASE-PAIR MODEL | PALLADIUM-MEDIATED POLYMERIZATION | ASYMMETRIC HYDROGENATION | TRANSITION-METAL CATALYSTS | C-H FUNCTIONALIZATION | REDUCTIVE ELIMINATION | COMBINATORIAL HOMOGENEOUS CATALYSIS | REGIOSELECTIVE HYDROFORMYLATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Polymer Bulletin, ISSN 0170-0839, 1/2011, Volume 66, Issue 1, pp. 3 - 15
Thermally induced polymerization of diazoketones, (E)-1-diazo-3-nonen-2-one 1 and (E)-1-diazo-4-phenyl-3-buten-2-one 2, is described. Heating 1 and 2 in a... 
Polymer Sciences | Diazoketone | Chemistry | Soft and Granular Matter, Complex Fluids and Microfluidics | Physical Chemistry | Radical polymerization | Styrene | Characterization and Evaluation of Materials | Copolymerization | POLYMER SCIENCE | CARBENES | PALLADIUM-MEDIATED POLYMERIZATION | Polymerization | Quinone
Journal Article