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palladium/norbornene catalysis (17) 17
aryl iodides (15) 15
c-h functionalization (13) 13
chemistry, organic (12) 12
norbornene (12) 12
palladium (11) 11
chemistry, multidisciplinary (10) 10
catalysis (8) 8
catellani reaction (7) 7
functionalization (7) 7
tetrasubstituted helical alkenes (7) 7
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domino reaction (6) 6
iodides (6) 6
regiospecific synthesis (6) 6
alkylation (5) 5
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arylation (5) 5
bond activation (5) 5
palladium/norbornene (5) 5
6h-dibenzopyran derivatives (4) 4
chemical reactions (4) 4
chemical synthesis (4) 4
cooperative catalysis (4) 4
efficient synthesis (4) 4
norbornen (4) 4
palladium-catalyzed synthesis (4) 4
transformation (4) 4
activation (3) 3
amination (3) 3
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c−h activation (3) 3
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enantioselective synthesis (3) 3
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organic chemistry (3) 3
oxidative addition (3) 3
palladium catalysis (3) 3
palladium/norbornene cooperative catalysis (3) 3
reagents (3) 3
sequential reactions (3) 3
substituted aryl iodides (3) 3
acids (2) 2
acylation (2) 2
alkenes (2) 2
bromides (2) 2
c-h arylation (2) 2
c-h bond activation (2) 2
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chemistry, inorganic & nuclear (2) 2
chemistry, physical (2) 2
clavine alkaloids (2) 2
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natural-products (2) 2
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organic compounds (2) 2
ortho-acylation (2) 2
palladium-catalyzed alkylation (2) 2
pd/norbornene (2) 2
polymers (2) 2
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tosylhydrazone insertion reaction (2) 2
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2-alkylation (1) 1
6h-dibenzopyran (1) 1
7-membered ring (1) 1
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Accounts of Chemical Research, ISSN 0001-4842, 07/2016, Volume 49, Issue 7, pp. 1389 - 1400
Direct C–H bond activation is an important reaction in synthetic organic chemistry. This methodology has the potential to simplify reactions by avoiding the... 
CATELLANI ORTHO-ARYLATION | PALLADIUM/NORBORNENE CATALYSIS | REACTION SEQUENCE | NORBORNENE | PALLADIUM-CATALYZED SYNTHESIS | ALKYLATION | COUPLING REACTION | TOSYLHYDRAZONE INSERTION REACTION | ARYL IODIDES | 6H-DIBENZOPYRAN DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Nature Chemistry, ISSN 1755-4330, 10/2015, Volume 7, Issue 11, pp. 863 - 870
The Catellani reaction - a palladium-catalysed C-H functionalization reaction mediated by norbornene - was first reported in 1997. The capacity to... 
DOMINO REACTION | U-SHAPED TEMPLATE | EXPEDITIOUS SYNTHESIS | PALLADIUM/NORBORNENE | ARYLATION | ARYL IODIDES | BOND ACTIVATION | CATELLANI REACTION | TETRASUBSTITUTED HELICAL ALKENES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3323 - 3327
Reported is the borono-Catellani arylation process for unsymmetrical biaryls synthesis, utilizing the readily available pinacol ester of arylboronic acids,... 
6H-DIBENZOPYRAN | ENANTIOSELECTIVE SYNTHESIS | PALLADIUM/NORBORNENE | PALLADIUM-CATALYZED SYNTHESIS | CHEMISTRY, ORGANIC | EXTENSION | SUBSTITUTED ARYL IODIDES | ACCESS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 30, pp. 5376 - 5385
The Catellani reaction enables an ortho-C-H activation based on oxidative addition of Pd(0) and an intermediary carbopalladation of norbornene. Among its... 
CLAVINE ALKALOIDS | DOMINO REACTION | FUNCTIONALIZATION | PALLADIUM/NORBORNENE CATALYSIS | ACTIVATION | NATURAL-PRODUCTS | ARYLATION | CHEMISTRY, ORGANIC | ARYL IODIDES | LIGAND | ORTHO-ACYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 17, pp. 4166 - 4169
A palladium-catalyzed, norbornene-mediated tandem amination/cyanation reaction via Catellani-type C–H functionalization was developed using N-benzoyloxyamines... 
DOMINO REACTION | AROMATIC FUNCTIONALIZATION | PALLADIUM/NORBORNENE CATALYSIS | N-DEBENZYLATION | REGIOSPECIFIC SYNTHESIS | CHEMISTRY, ORGANIC | ARYL IODIDES | CATELLANI REACTION | ORTHO-ARYLATION | C-H FUNCTIONALIZATION | TETRASUBSTITUTED HELICAL ALKENES
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2018, Volume 8, Issue 5, pp. 3775 - 3779
The Catellani reaction provides a facile and efficient method for the synthesis of multifunctionalized arenes. However, the use of Pd(0) catalysts restricts... 
palladium catalysis | arylboronic acid | C-H activation | Catellani reaction | arene | PALLADIUM/NORBORNENE CATALYSIS | ACTIVATION | REGIOSPECIFIC SYNTHESIS | CHEMISTRY, PHYSICAL | FUNCTIONALIZATION | KETONES | AMINATION | NORBORNENE | C-H ARYLATION | ANILINES | ARYL IODIDES
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 8/2018, Volume 16, Issue 3, pp. 5376 - 5385
The Catellani reaction enables an ortho -C-H activation based on oxidative addition of Pd(0) and an intermediary carbopalladation of norbornene. Among its... 
Transformation | Palladium | Indoles | Chemical synthesis | Alkylation
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 15, pp. 3782 - 3785
A catalytically asymmetric palladium/norbornene-catalyzed reaction is reported, where α-aryl tetrahydroquinoline derived phosphoramidite L15 is found to be the... 
PALLADIUM/NORBORNENE CATALYSIS | CONCOMITANT ORTHO-ALKYLATION | BOND FUNCTIONALIZATION | EFFICIENT SYNTHESIS | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | ARYL IODIDES | C-H FUNCTIONALIZATION | TETRASUBSTITUTED HELICAL ALKENES | CONCISE SYNTHESIS
Journal Article
Organic Letters, ISSN 1523-7060, 09/2016, Volume 18, Issue 17, pp. 4162 - 4165
Efficient tandem ortho-C–H-amination/ipso-cyanation of iodoarenes was accomplished under a norbornene-mediated Pd-catalyzed process. A series of functionalized... 
DOMINO REACTION | FUNCTIONALIZATION | PALLADIUM/NORBORNENE CATALYSIS | FACILE SYNTHESIS | ACYLATION | CHEMISTRY, ORGANIC | BOND ACTIVATION | CATELLANI REACTION | SUBSTITUTED ARYL IODIDES | DERIVATIVES | PD/NORBORNENE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2018, Volume 83, Issue 20, pp. 12683 - 12693
A palladium-catalyzed three-component reaction of aryl iodides, norbornenes, and hexamethyldisilane/hexamethyldigermane has been developed for the assembly of... 
HALIDES | FUNCTIONALIZATION | PALLADIUM/NORBORNENE COOPERATIVE CATALYSIS | INTERMOLECULAR SILYLATION | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | ALKYL ELECTROPHILES | TERMINAL ALKYNES | BOND ACTIVATION | STEREOSELECTIVE-SYNTHESIS | C-H ACTIVATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 13, pp. 3444 - 3448
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 28, pp. 8592 - 8596
Herein, we report a cooperatively palladium/norbornene‐catalyzed polymerization, which simplifies the synthesis of functional aromatic polymers, including... 
palladium catalysis | multicomponent polymerization | C−H activation | palladium/norbornene catalysis | polymers | Polymerization | Palladium | Amines | Catalysis | Amination | Polymers | Chemical synthesis | Monomers
Journal Article
Organic Letters, ISSN 1523-7060, 12/2016, Volume 18, Issue 23, pp. 6120 - 6123
Palladium-catalyzed α-arylation reactions of ketones with simultaneous ortho alkylation offer 1,2,3-substituted arenes. The reactions of 1,ω-dihaloalkanes also... 
PALLADIUM/NORBORNENE CATALYSIS | IODIDES | MONO-ALPHA-ARYLATION | FACILE SYNTHESIS | CONCOMITANT ORTHO-ALKYLATION | REGIOSPECIFIC SYNTHESIS | CHEMISTRY, ORGANIC | BIOLOGICAL-ACTIVITIES | CATELLANI REACTION | C-H FUNCTIONALIZATION | GENERAL-METHOD
Journal Article
Tetrahedron, ISSN 0040-4020, 03/2019, Volume 75, Issue 12, pp. 1774 - 1780
Mediators play a central role in Catellani-type reactions. Herein we reported the discovery of inexpensive 5-norbornene-2-carboxylic acid (N4) as a general... 
Redox-relay Heck | Quaternary center | Catellani reaction | Tetrahydronaphthalene | Indane | Cooperative catalysis | Mediator | CARBON CENTERS | ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | PALLADIUM/NORBORNENE | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | C-H FUNCTIONALIZATION | HECK ARYLATIONS | ARYL IODIDES | TETRASUBSTITUTED HELICAL ALKENES | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 24, pp. 7161 - 7165
Journal Article