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Macromolecular Rapid Communications, ISSN 1022-1336, 06/2010, Volume 31, Issue 12, pp. 1083 - 1089
... a chain‐walking Pd‐diimine catalyst, [(ArNC(Me)(Me)CNAr)Pd(CH3)(NCMe)]SbF6 (Ar2,6‐(iPr)2C6H3) (1) is reported. In spite of its high steric bulkiness in the close proximity of the double bond, appreciable DMB incorporations... 
olefin | copolymerization | microstructure | chain topology | Pd‐diimine catalyst | POLAR MONOMERS | ALPHA-OLEFINS | POLYMER SCIENCE | RING INCORPORATION | COCATALYST SYSTEMS | ONE-POT SYNTHESIS | POLYMERIZATION | HYPERBRANCHED POLYETHYLENES | MONOMER REACTIVITIES | NONBRIDGED HALF-TITANOCENES | Pd-diimine catalyst | C-13 NMR | Thermal properties | Copolymers | Catalysts | Ethylene | Chains | Copolymerization | Palladium | Bonding
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2018, Volume 47, Issue 44, pp. 15857 - 15872
New mono(5-aryl-2-( -arylformimino)pyrrolyl) Ni( ) complexes were synthesised and tested as aluminium-free catalysts for the polymerisation of ethylene, yielding hyperbranched oligo-/polyethylenes. A family of mono(2-iminopyrrolyl... 
POLYMERS | METHYL-METHACRYLATE | PD-DIIMINE | CHAIN WALKING POLYMERIZATION | LIGANDS SYNTHESIS | PHOTOPHYSICAL PROPERTIES | IMINOPYRROLYL BORON COMPLEXES | C-13 NMR | ETHYLENE POLYMERIZATION | COPOLYMERIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Macromolecules, ISSN 0024-9297, 01/2013, Volume 46, Issue 1, pp. 72 - 82
...) species as efficient and recyclable catalysts for Heck reaction. This strategy combines remarkably the synthesis of HBPE polymer support and the immobilization of Pd(II... 
CROSS-COUPLING REACTIONS | POLYMER SCIENCE | WALKING ETHYLENE COPOLYMERIZATION | SOLUBLE POLYMER SUPPORTS | CHAIN WALKING | HOMOGENEOUS CATALYSTS | ONE-POT SYNTHESIS | RECOVERABLE CATALYSTS | RADICAL POLYMERIZATION | METAL NANOPARTICLES | PD-DIIMINE CATALYSIS
Journal Article
Macromolecules, ISSN 0024-9297, 06/2011, Volume 44, Issue 11, pp. 4125 - 4139
...” polymerization and atom-transfer radical polymerization (ATRP). Ethylene “living” polymerization was first carried out using a functionalized Pd–diimine catalyst, [(ArNC(Me)–(Me)CNAr)Pd(CH2)3C(O)O(CH2)2OC(O)C(CH3)2Br]+SbF6 – (Ar = 2,6-(iPr)2C6H3) (1... 
ALPHA-OLEFINS | POLYMER SCIENCE | HYPERBRANCHED POLYETHYLENES | RING INCORPORATION | BLOCK-COPOLYMERS | ONE-POT SYNTHESIS | CHAIN WALKING COPOLYMERIZATION | SHAPED POLYMERS | PD-DIIMINE CATALYST | CATIONIC-POLYMERIZATION | BRANCHED POLYETHYLENES
Journal Article
by Xiang, P and Ye, ZB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 12/2015, Volume 798, pp. 429 - 436
Four Pdediimine catalysts with varying ligand sterics {[RC6H3N=C(R')-C(R') = NC6H3R] Pd(CH3) (N CMe)}SbF6 [1, R = 2,6-(iPr)(2), R' = CH3; 2, R = CH3, R' = H; 3... 
CHAIN-WALKING | MOLECULAR-WEIGHT | RING INCORPORATION | ONE-POT SYNTHESIS | PD-DIIMINE | Polymerization | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | WALKING ETHYLENE COPOLYMERIZATION | HYPERBRANCHED POLYETHYLENES | ALPHA-DIIMINE CATALYSTS | ADDITION POLYMERIZATION | Norbornene | Catalysis | PALLADIUM CATALYSTS
Journal Article
Chemistry, an Asian journal, ISSN 1861-4728, 2010, Volume 5, Issue 5, pp. 1058 - 1070
Journal Article
Polymer, ISSN 0032-3861, 2010, Volume 51, Issue 3, pp. 597 - 605
...) using a Pd-diimine catalyst, [(ArN C(Me)–(Me)C NAr)Pd(CH 3)(N CMe)] +SbF 6 − (Ar = 2,6–( iPr) 2C 6H 3). The polymers were characterized extensively using 13C nuclear magnetic resonance... 
Polyethylene | Chain walking polymerization | Chain topology | MONOMERS | POLYMER SCIENCE | PD-DIIMINE | OLEFIN POLYMERIZATION | MOLECULAR-WEIGHT POLYETHYLENES | PROPYLENE | CATALYSTS | MICROSTRUCTURE
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 12/2009, Volume 210, Issue 24, pp. 2194 - 2202
Journal Article
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